The 2023 MDPI Annual Report has
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15 pages, 275 KiB  
Article
Tourism Development and Urban Landscape Conservation in Rural Areas: Opportunities and Ambivalences in Local Regulations—The Case of Spain
by José David Albarrán
Sustainability 2024, 16(10), 3973; https://doi.org/10.3390/su16103973 - 9 May 2024
Abstract
This article analyzes local-level normative regulations aimed at directly or indirectly conserving the urban landscape in rural areas. Using a discursive analysis methodology on regulatory documents being enforced in a series of localities assigned to a tourism promotion program, the evidence suggests that [...] Read more.
This article analyzes local-level normative regulations aimed at directly or indirectly conserving the urban landscape in rural areas. Using a discursive analysis methodology on regulatory documents being enforced in a series of localities assigned to a tourism promotion program, the evidence suggests that promotional activity retroactively influences the phraseology of these municipal regulations. The results obtained point to the existence of perpetuating historicist approaches within the current regulations, which appear to largely derive from the search for success in the tourism market and the resulting benefits to the local economy. Full article
(This article belongs to the Special Issue Heritage Preservation and Tourism Development)
19 pages, 560 KiB  
Article
Does Farmers’ Cognition Enhance Their Enthusiasm for Adopting Sustainable Digital Agricultural Extension Services? Evidence from Rural China
by Tianzhi Gao, Qian Lu, Yiping Zhang and Hui Feng
Sustainability 2024, 16(10), 3972; https://doi.org/10.3390/su16103972 - 9 May 2024
Abstract
The service model of digital agricultural technology extension, as a novel and sustainable approach, plays a pivotal role in facilitating the digital transformation of farmers’ agricultural practices. Leveraging survey data from 1475 farmers in China, the study employed a multivariate ordered logit model [...] Read more.
The service model of digital agricultural technology extension, as a novel and sustainable approach, plays a pivotal role in facilitating the digital transformation of farmers’ agricultural practices. Leveraging survey data from 1475 farmers in China, the study employed a multivariate ordered logit model to investigate the relationship between farmers’ cognition and enthusiasm to adopt digital agricultural extension services. The findings revealed that subjective and objective cognitions positively influence farmers’ enthusiasm for adopting digital agricultural extension services. Furthermore, policy incentives, as a significant regulatory factor, effectively influence farmers’ cognition levels and enthusiasm to adopt digital agricultural extension services. Additionally, female respondents, farmers with higher educational levels, and membership in agricultural cooperatives all facilitate the adoption of these services. This study not only enriches the theoretical framework for agricultural technology promotion, aiding in the understanding of farmers’ decision-making processes when adopting digital agricultural extension services, but also provides a deeper insight into the role of digital agricultural technologies in promoting sustainable agricultural development, offering scientific evidence for relevant policy formulation and implementation. Full article
(This article belongs to the Special Issue Digital Economy and Sustainable Development)
25 pages, 5609 KiB  
Article
Optimal Wind Farm Siting Using a Fuzzy Analytic Hierarchy Process: Evaluating the Island of Andros, Greece
by Dimitris Ioannidis and Dimitra G. Vagiona
Sustainability 2024, 16(10), 3971; https://doi.org/10.3390/su16103971 - 9 May 2024
Abstract
In recent decades, fuzzy logic and fuzzy multi-criteria decision-making systems have been applied in several fields. This paper aims to determine the optimal wind farm siting solution in a fuzzy environment. Therefore, the main research question of the present paper is whether and [...] Read more.
In recent decades, fuzzy logic and fuzzy multi-criteria decision-making systems have been applied in several fields. This paper aims to determine the optimal wind farm siting solution in a fuzzy environment. Therefore, the main research question of the present paper is whether and to what extent the uncertainty in the researcher’s judgments affects the ranking of wind farm siting solutions. The fuzzy analytical hierarchy method is applied to an existing case study of wind farm siting on the island of Andros, examining the stability of the final priorities of the alternatives under a regime of gradual increases in ambiguity, as well as whether the introduced ambiguity in the model corresponds to any uncertainty the researcher has during the process of scoring the criteria and alternatives. Five assessment criteria (wind potential, ground slope, distance from road network, distance from high-voltage network, and social acceptance of local population) and eight eligible suitable alternatives (A1–A8) for wind farm siting are considered in the computations. The methodology includes the fuzzification of initial decision-maker judgments, the calculation of fuzzy intermediate priorities (weights), the defuzzification of fuzzy intermediate priorities (weights), and the synthesis of intermediate priorities into final priorities of alternatives, according to the procedures of the crisp AHP (CAHP). Under the assumptions of the initial case study, the results show that the final priorities are quite robust when faced with increased ambiguity. In almost all the examined cases, the alternative initially chosen as the best, A1, is dominant, followed by A3. In addition, in all cases, social acceptance favors alternative A1, and wind velocity favors alternative A8. Therefore, fuzzy multi-criteria methods can be applied to determine an optimal wind farm siting solution when criteria with qualitative characteristics are used and the manifestation of preferences involves strong elements of subjectivity. Full article
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20 pages, 270 KiB  
Article
Study on the Impact of Delayed Retirement on the Sustainability of the Basic Pension Insurance Fund for Urban Employees in China
by Guiling Zhao, Deyu Zhou and Yunpeng Fu
Sustainability 2024, 16(10), 3969; https://doi.org/10.3390/su16103969 - 9 May 2024
Abstract
With the aging of China’s population, the problem of pension security has become more and more prominent, and whether delayed retirement can effectively alleviate the pension fund gap and ensure the sustainability of the pension fund has become the focus of social concern. [...] Read more.
With the aging of China’s population, the problem of pension security has become more and more prominent, and whether delayed retirement can effectively alleviate the pension fund gap and ensure the sustainability of the pension fund has become the focus of social concern. This study predicts the income and expenditure of urban workers’ basic pension insurance fund from 2021 to 2050 by constructing an actuarial model of pension insurance fund income and expenditure, and simulates the effect of delayed retirement policy. The prediction results show that under the existing system, the basic pension insurance fund for urban workers will have a shortfall for the first time in 2027, and the shortfall will expand year by year. Compared with the non-implementation of delayed retirement policy, the simulation of the implementation of a delayed retirement program delayed the emergence of the fund gap until 2029, and the forecast period of the pension fund gap significantly narrowed, indicating that delayed retirement policy has a certain positive impact on alleviating the pressure of pension payments, but delayed retirement cannot completely eliminate the pension fund gap. In view of this, this paper suggests that a progressive and flexible delayed retirement policy should be introduced as soon as possible to better adapt to the needs of different groups. At the same time, differentiated policies should be formulated for different groups of people and a pension incentive mechanism for delayed retirement should be set up to improve public acceptance of delayed retirement policy. In addition, delayed retirement policy should be combined with other measures, such as lowering the corporate contribution rate and enhancing the value-added capacity of the pension fund, so as to ensure the sustainability of the pension fund. Full article
19 pages, 1672 KiB  
Article
European Citizens’ Evaluation of the Common Agricultural Policy
by Fernando Mata and Maria J. P. L. Dos-Santos
Sustainability 2024, 16(10), 3970; https://doi.org/10.3390/su16103970 - 9 May 2024
Abstract
The Common Agricultural Policy (CAP) is crucial in ensuring food safety and security in Europe. Providing a stable and diverse food supply also supports rural economies and promotes social, environmental and economic sustainability. However, as CAP consumes approximately 30% of the EU budget, [...] Read more.
The Common Agricultural Policy (CAP) is crucial in ensuring food safety and security in Europe. Providing a stable and diverse food supply also supports rural economies and promotes social, environmental and economic sustainability. However, as CAP consumes approximately 30% of the EU budget, debates regarding its pertinence have arisen. This paper aimed to understand European citizens’ perceptions of CAP, its associated benefits and their level of agreement regarding the allocation of the EU budget. Ultimately, the goal was to gain insights into EU citizens’ attitudes and perceptions towards the CAP. Information and data come from the European Survey Eurobarometer. The methods include statistical inferential techniques adjusted to the nature of the variables and goals. The findings confirm that European citizens generally perceive the CAP positively and have positive attitudes about the CAP. While some differences among various social groups may exist, the results did not identify any specific group strongly opposing the CAP. Overall, European citizens hold a favorable attitude towards the CAP, its associated benefits and budget allocation. This paper brings new insights into new European CAP measures and programs to promote food security and the sustainability of agriculture among European countries and citizens. These insights may be useful for public decision-makers to define better policies and measures adjusted to European citizens and to promote food security and sustainability. Full article
(This article belongs to the Section Sustainable Agriculture)
16 pages, 873 KiB  
Article
Evaluating the Sustainable Development Performance of China’s International Commercial Ports Based on Environmental, Social and Governance Elements
by Yan Zhang, Zihan Xin and Guoya Gan
Sustainability 2024, 16(10), 3968; https://doi.org/10.3390/su16103968 - 9 May 2024
Abstract
An environmental, social and governance (ESG) evaluation system can focus on the value of enterprises more comprehensively and better scrutinize the development premise of enterprise. As a novel investment concept, both domestic and foreign investors widely acknowledge the significance of ESG. With the [...] Read more.
An environmental, social and governance (ESG) evaluation system can focus on the value of enterprises more comprehensively and better scrutinize the development premise of enterprise. As a novel investment concept, both domestic and foreign investors widely acknowledge the significance of ESG. With the implementation of “carbon peak”, “carbon neutral” and other national strategies, an increasing number of transportation enterprises in China’s international commercial ports have started to focus on the role of ESG evaluation. This not only facilitates self-examination and correction within enterprises but also helps in adjusting the strategic direction toward sustainable development. This shift toward ESG evaluation is crucial for promoting environmental sustainability and corporate social responsibility within the transportation industry. In this regard, this study aims to evaluate the sustainable development performance of China’s international commercial ports based on ESG elements. A data envelopment analysis (DEA) is considered to be a non-parametric performance evaluation method that can effectively solve for multi-criteria decision-making units, so this study mainly selects the DEA model for the performance evaluation. This study conducted research to select eight benchmarking companies within the industry and found that efficient units excelled in their ability to complete capacity levels with high quality and quantity at ports. In contrast, less efficient units scored lower in the domain of social responsibility. Full article
(This article belongs to the Special Issue Green Shipping and Sustainable Maritime Transport)
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23 pages, 12372 KiB  
Article
Blast-Resistant Performance of Steel Petrochemical Control Room with 3D-Kagome Sandwich Wall
by Zhijun Li, Xinlong Dong, Dou Chen, Yan Jiang and Xuehua Li
Sustainability 2024, 16(10), 3967; https://doi.org/10.3390/su16103967 - 9 May 2024
Abstract
As the control brain of the petrochemical plant, blast-resistant performance requirements are important for the sustainability of the petrochemical control room and should be guaranteed when the vapor cloud explosion occurs in the petrochemical production process. The 3D-Kagome truss core sandwich structure is [...] Read more.
As the control brain of the petrochemical plant, blast-resistant performance requirements are important for the sustainability of the petrochemical control room and should be guaranteed when the vapor cloud explosion occurs in the petrochemical production process. The 3D-Kagome truss core sandwich structure is a kind of blast-resistant material with high energy absorption and recycling. Considering the influential factors of the radius of the truss core rod and thickness of the upper and lower panels, in this paper, the blast-resistant performance of a real steel petrochemical control room with a 3D-Kagome truss core sandwich wall was analyzed. With the optimization goal of plastic deformation energy and panel displacement, the optimal wall thickness and radius of the truss core rod were obtained. The optimized blast-resistant walls were assembled, and the dynamic response of the steel petrochemical control room with the 3D-Kagome truss core sandwich blast-resistant wall was analyzed. The simulation results indicate that the truss core layer is ineffective in dissipating blast energy when the radius ratio of the truss core rod exceeds 2.7% of the total wall thickness. Moreover, as the thickness of the upper and lower panels increases from 0.5 cm to 3 cm, the proportion of plastic deformation energy in the truss core layer gradually rises from 55% to 95%, stabilizing at around 90%. The optimal configuration for blast resistance is achieved when the panel thickness ratio is 6.7% of the total wall thickness; the truss core rod radius ratio is 2.7% of the total thickness. This study establishes the effectiveness of the optimized 3D-Kagome sandwich wall as a blast-resistant solution for steel petrochemical control rooms. Full article
(This article belongs to the Section Green Building)
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16 pages, 861 KiB  
Article
The Impact of Sugarcane By-Product Exports on Income Inequality: How Sustainable Is This Relationship?
by Thiago Vizine Da Cruz and Ricardo Luiz Machado
Sustainability 2024, 16(10), 3966; https://doi.org/10.3390/su16103966 - 9 May 2024
Abstract
The reduction in income inequality and its convergence between localities is one of the aims of the United Nations Sustainable Development Goals. This work aims to contribute to the theme, researching the relationship among international trade, the export of sugarcane by-products, and income [...] Read more.
The reduction in income inequality and its convergence between localities is one of the aims of the United Nations Sustainable Development Goals. This work aims to contribute to the theme, researching the relationship among international trade, the export of sugarcane by-products, and income inequality. A panel data regression was performed for a group of 98 cities from the state of Goiás-Brazil. Results indicate that international trade has a minimal, though positive effect, reducing income inequality. Nevertheless, the export of sugarcane by-product results indicates a harmful effect on workers’ income in the poorest cities who work in the agricultural sector. The results indicate that international trade contributes to sustainable development by generating wealth, contributing to UN SDG number 1, and reducing income inequality, helping to achieve UN SDG number 10. Full article
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16 pages, 7363 KiB  
Article
Sustainable Application of Pyrolytic Oxygen Furnace Slag in Cement-Stabilized Macadam: Volume Stability, Mechanical Properties, and Environmental Impact
by Dezhi Kong, Jiahui Zou, Meizhu Chen, Jun Xie and Xuanwen Gou
Sustainability 2024, 16(10), 3965; https://doi.org/10.3390/su16103965 - 9 May 2024
Abstract
As an industrial waste, basic oxygen furnace (BOF) slag is an ideal substitute for natural rubble and sand. However, its potential instability of volume restricts the application of the BOF slag in engineering. This study aims at investigating the volume stability and mechanical [...] Read more.
As an industrial waste, basic oxygen furnace (BOF) slag is an ideal substitute for natural rubble and sand. However, its potential instability of volume restricts the application of the BOF slag in engineering. This study aims at investigating the volume stability and mechanical properties of BOF slag and its application as an aggregate in cement-stabilized macadam. As part of this research, the physicochemical properties, especially the volume stability, of two types of BOF slags and andesite were first studied. Then, mechanical properties, volume stability, and an environment analysis are used to evaluate the application of pyrolytic BOF slag in cement-stabilized macadam. The experimental results show that different types of BOF slags have similar thermal expansion coefficients, which are higher than andesite. The free CaO content of pyrolytic BOF slag is much lower than that of ordinary BOF slag and the volume expansion of pyrolytic BOF slag is less than 0.5%. The unconfined compressive strength (UCS) of cement-stabilized macadam using pyrolytic BOF slag is about 30% higher than that of andesite. Although the water loss rate is higher than a natural aggregate, dry shrinkage of pyrolytic BOF slag cement-stabilized macadam is about 30–50% less than that of a natural aggregate. Meanwhile, its shrinking speed is also slower than that of a natural aggregate. The micro-expansion properties of pyrolytic BOF slag could effectively partially offset the shrinkage characteristics of cement-stabilized macadam. Finally, the Toxicity Characteristic Leaching Procedure (TCLP) test results indicated that the metal leaching concentration meets the Chinese environmental standards. This study provides a direction for the large-scale and effective sustainable application of pyrolytic BOF slag. Full article
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12 pages, 260 KiB  
Perspective
Empowering Sustainable Healthcare: The Role of Health Literacy
by Patrizio Zanobini, Marco Del Riccio, Chiara Lorini and Guglielmo Bonaccorsi
Sustainability 2024, 16(10), 3964; https://doi.org/10.3390/su16103964 - 9 May 2024
Abstract
The imperative of sustainability in healthcare is becoming more pressing due to global health crises, climate change, and the rising burden of chronic diseases. Sustainability in healthcare involves social, economic, and environmental dimensions, each important for equitable and robust healthcare delivery. Health literacy [...] Read more.
The imperative of sustainability in healthcare is becoming more pressing due to global health crises, climate change, and the rising burden of chronic diseases. Sustainability in healthcare involves social, economic, and environmental dimensions, each important for equitable and robust healthcare delivery. Health literacy may play a central role in embracing all three dimensions, bridging the gap between complex health information and individuals’ capability to understand and use it effectively: In fact, as a factor influencing the link between adverse social and economic conditions and subsequent health issues, health literacy could represent a practical target for mitigating health disparities within various demographic groups, thereby enhancing social sustainability. Furthermore, when people possess a solid understanding of their health conditions and the necessary steps for health management, they can contribute to a reduction in generated healthcare costs. Finally, health literacy and environmental health literacy equips individuals and communities with the knowledge and skills to understand how environmental factors affect health and empowers them to take proactive measures to protect the environment, potentially reducing the environmental impact of healthcare services. Therefore, integrating health literacy into education curricula and healthcare professional training is crucial for promoting sustainability. Despite some known barriers to the advancement and improvement of health literacy, such as limited awareness of its importance, the collaboration between academia, healthcare institutions, and community organizations is a path to follow to overcome these challenges. Full article
29 pages, 391 KiB  
Article
Perceptions and Attitudes of SMEs and MNCs Managers Regarding CSR Implementation: Insights from Companies Operating in the Retail Sector
by Andra Modreanu, Sorin-George Toma, Marin Burcea and Cătălin Grădinaru
Sustainability 2024, 16(10), 3963; https://doi.org/10.3390/su16103963 - 9 May 2024
Abstract
To establish a responsible business environment, it is important to analyze the way corporate social responsibility (CSR) is implemented within the business world. In this respect, managers play a crucial role in designing and applying the CSR concept and practices. Therefore, this paper [...] Read more.
To establish a responsible business environment, it is important to analyze the way corporate social responsibility (CSR) is implemented within the business world. In this respect, managers play a crucial role in designing and applying the CSR concept and practices. Therefore, this paper aims to identify and analyze the perceptions and attitudes of medium-sized enterprises (SMEs) and multinational companies (MNCs) managers in the Romanian retail sector related to CSR implementation. A documentary research approach and a qualitative research methodology through the use of four focus groups were utilized to fulfill the above-mentioned purpose. Additionally, the authors employed content analysis and Nvivo 14 software to process the collected data. The findings indicate that the size of firms represents a key element of managers’ perceptions and attitudes regarding CSR. Particularly, SME managers have a lower level of familiarity with the concept and the potential advantages for business compared to MNC managers. Furthermore, when it comes to CSR practices, MNCs use a comprehensive approach to meeting the demands of their stakeholders, whereas SMEs prioritize the requirements of their employees. One major obstacle in implementing the CSR concept continues to be the high expenses involved in the businesses. Full article
17 pages, 5943 KiB  
Article
The Future Probability of Winter Wheat and Maize Yield Failure in Hungary Based on Long-Term Temporal Patterns
by László Huzsvai, Csaba Juhász, Loujaine Seddik, Györgyi Kovács and József Zsembeli
Sustainability 2024, 16(10), 3962; https://doi.org/10.3390/su16103962 - 9 May 2024
Abstract
The level of yield variation of primary crops has a considerable effect on the vulnerability of agriculture. The main factor that makes the agriculture of Hungary so vulnerable is climate change, and technological development cannot compensate for its unfavourable effects. We examined the [...] Read more.
The level of yield variation of primary crops has a considerable effect on the vulnerability of agriculture. The main factor that makes the agriculture of Hungary so vulnerable is climate change, and technological development cannot compensate for its unfavourable effects. We examined the yield failures of the two major field crops grown in Hungary that occurred during the last 100 years. The goals of our study were to determine how often yield losses at 15% and 30% occur, what their probability is and whether the probability has changed in recent decades. The Wald–Wolfowitz runs test was used to determine the randomness of yield failures. A series of yield failures for maize and winter wheat were found to be random. Based on the data for 1985–2023, failure by 15% and 30% can be expected approximately every 8th and 19th year for winter wheat and 3rd and 5th year for maize. Winter wheat yield failure at 15% shows a decreasing trend in occurrence, while at 30% it increases. On the other hand, the frequency of maize yield failure increased at both levels. The consideration of historical yield data can help to determine the extent of crop loss to be expected in the long term to maintain sustainable winter wheat and maize production in our changing climate. Full article
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19 pages, 1040 KiB  
Article
Variations in Gender Perceptions of Summer Comfort and Adaptation in Colonial Revival-Style Homes
by Timothy O. Adekunle
Sustainability 2024, 16(10), 3961; https://doi.org/10.3390/su16103961 - 9 May 2024
Abstract
Past investigations have assessed gender variations in thermal comfort and adaptation in different buildings. However, no reported study has evaluated differences in gender perceptions of the thermal environment in US Colonial Revival-style homes. As a result, this study aims to provide an understanding [...] Read more.
Past investigations have assessed gender variations in thermal comfort and adaptation in different buildings. However, no reported study has evaluated differences in gender perceptions of the thermal environment in US Colonial Revival-style homes. As a result, this study aims to provide an understanding of variations in gender perceptions of summer comfort and adaptation in the buildings. The study evaluated data collected during the field studies of thermal comfort (FSTC), including physical measurements of environmental variables and subjects’ votes. In this study, 67% females and 33% males participated in the field surveys in summertime. The mean neutral temperature of 25.5 °C and preferred temperature of 24.9 °C were noted for females. For males, the mean neutral and preferred temperatures of 25.8 °C and 25.6 °C were observed. Females feel neutral and prefer “no change” to the thermal environment at lower temperatures than males. A difference of 0.3 °C was noted between the average heat indices for females and males. Male respondents who feel warm perceive less air quality more than females. Females and males who perceive being thermally comfortable also perceive good air quality. Females and males who are thermally comfortable rated air humidity to be acceptable. There are similarities and differences between gender perceptions of the thermal environment. The investigation suggests interventions that can help users regulate their skin temperatures and use control measures that are sensitive to clothing insulation. The research also calls for policies that can promote building users’ pivotal adaptive measures to improve their indoor thermal environment. The study enhances our understanding of sustainable indoor environments and how to improve living conditions and adaptive modifications among different groups of occupants in buildings. Full article
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16 pages, 17924 KiB  
Article
Revealing the Effect of α’ Decomposition on Microstructure Evolution and Mechanical Properties in Ti80 Alloy
by Chunhong Xiao, Bin Hu, Jinyang Ge, Bin Kong, Deng Luo, Xiaoyong Zhang and Kechao Zhou
Materials 2024, 17(10), 2238; https://doi.org/10.3390/ma17102238 - 9 May 2024
Abstract
Three types of solution treatment and aging were designed to reveal the α’ decomposition and its effect on the mechanical properties of near-α Ti-80 alloy, as follows: solution at 970 °C then quenching (ST), ST + aging at 600 °C for 5 h [...] Read more.
Three types of solution treatment and aging were designed to reveal the α’ decomposition and its effect on the mechanical properties of near-α Ti-80 alloy, as follows: solution at 970 °C then quenching (ST), ST + aging at 600 °C for 5 h (STA-1), and ST + aging 600 °C for 24 h (STA-2). The results show that the microstructures of the ST samples were mainly composed of equiaxed αp and acicular α’, with a large number of dislocations confirmed by the KAM results. After subsequent aging for 5 h, α’ decomposed into acicular fine αs and nano-β (intergranular β, intragranular β) in the STA-1 specimen, which obstructed dislocation motion during deformation, resulting in the STA-1 specimen exhibiting the most excellent yield strength (1012 MPa) and maintaining sufficient elongation (8.1%) compared with the ST (898 MPa) and STA-2 (871 MPa) samples. By further extending the aging time to 24 h, the size of acicular αs and nano-β gradually increased while the density of dislocations decreased, which resulted in a decrease in strength and an increase in plasticity. Based on this, a microstructures–properties correlation model was proposed. This study provides a new method for strength–plasticity matching of near-α titanium alloys through α’ decomposition to acicular αs+nano-β. Full article
(This article belongs to the Special Issue Review and Feature Papers in "Metals and Alloys" Section)
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11 pages, 9743 KiB  
Article
Effect of Compressive Stress on Copper Bonding Quality and Bonding Mechanisms in Advanced Packaging
by Tsan-Feng Lu, Ping-Yang Lee and YewChung Sermon Wu
Materials 2024, 17(10), 2236; https://doi.org/10.3390/ma17102236 - 9 May 2024
Abstract
The thermal expansion behavior of Cu plays a critical role in the bonding mechanism of Cu/SiO2 hybrid joints. In this study, artificial voids, which were observed to evolve using a focused ion beam, were introduced at the bonded interfaces to investigate the [...] Read more.
The thermal expansion behavior of Cu plays a critical role in the bonding mechanism of Cu/SiO2 hybrid joints. In this study, artificial voids, which were observed to evolve using a focused ion beam, were introduced at the bonded interfaces to investigate the influence of compressive stress on bonding quality and mechanisms at elevated temperatures of 250 °C and 300 °C. The evolution of interfacial voids serves as a key indicator for assessing bonding quality. We quantified the bonding fraction and void fraction to characterize the bonding interface and found a notable increase in the bonding fraction and a corresponding decrease in the void fraction with increasing compressive stress levels. This is primarily attributed to the Cu film exhibiting greater creep/elastic deformation under higher compressive stress conditions. Furthermore, these experimental findings are supported by the surface diffusion creep model. Therefore, our study confirms that compressive stress affects the Cu–Cu bonding interface, emphasizing the need to consider the depth of Cu joints during process design. Full article
(This article belongs to the Special Issue Welding, Joining, and Additive Manufacturing of Metals and Alloys)
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19 pages, 591 KiB  
Article
Physical Analysis and Mathematical Modeling of the Hydrogen Storage Process in the MmNi4.2Mn0.8 Compound
by Sihem Belkhiria, Abdulrahman Alsawi, Chaker Briki, Saleh M. Altarifi, Mohamed Houcine Dhaou and Abdelmajid Jemni
Materials 2024, 17(10), 2237; https://doi.org/10.3390/ma17102237 - 9 May 2024
Abstract
The results of an experimental and mathematical study into the MmNi4.2Mn0.8 compound’s hydrogen storage properties are presented in the present research. Plotting and discussion of the experimental isotherms (P-C-T) for different starting temperatures (288 K, 298 K, 308 K, and [...] Read more.
The results of an experimental and mathematical study into the MmNi4.2Mn0.8 compound’s hydrogen storage properties are presented in the present research. Plotting and discussion of the experimental isotherms (P-C-T) for different starting temperatures (288 K, 298 K, 308 K, and 318 K) were carried out first. Then, the enthalpy and entropy of formation (ΔH0, ΔS0) were deduced from the plot of van’t Hoff. Following that, the P-C-T were contrasted with a mathematical model developed via statistical physics modeling. The steric and energetic parameters, such as the number of the receiving sites (n1, n2), their densities (Nm1, Nm2), and the energy parameters (P1, P2) of the system, were calculated thanks to the excellent agreement between the numerical and experimental results. Therefore, plotting and discussing these parameters in relation to temperature preceded their application in determining the amount of hydrogen in each type of site per unit of metal ([H/M]1, [H/M]2) as well as for the entire system [H/M] versus temperature and pressure besides the absorption energies associated with each kind of site (ΔE1, ΔE2) and the thermodynamic functions (free energy, Gibbs energy, and entropy) that control the absorption reaction. Full article
(This article belongs to the Special Issue Research on Metallic Hydrogen Storage Materials)
12 pages, 6850 KiB  
Article
Predictive Modeling of Vickers Hardness Using Machine Learning Techniques on D2 Steel with Various Treatments
by Claudia Lorena Mambuscay, Carolina Ortega-Portilla, Jeferson Fernando Piamba and Manuel Guillermo Forero
Materials 2024, 17(10), 2235; https://doi.org/10.3390/ma17102235 - 9 May 2024
Abstract
Hardness is one of the most crucial mechanical properties, serving as a key indicator of a material’s suitability for specific applications and its resistance to fracturing or deformation under operational conditions. Machine learning techniques have emerged as valuable tools for swiftly and accurately [...] Read more.
Hardness is one of the most crucial mechanical properties, serving as a key indicator of a material’s suitability for specific applications and its resistance to fracturing or deformation under operational conditions. Machine learning techniques have emerged as valuable tools for swiftly and accurately predicting material behavior. In this study, regression methods including decision trees, adaptive boosting, extreme gradient boosting, and random forest were employed to forecast Vickers hardness values based solely on scanned monochromatic images of indentation imprints, eliminating the need for diagonal measurements. The dataset comprised 54 images of D2 steel in various states, including commercial, quenched, tempered, and coated with Titanium Niobium Nitride (TiNbN). Due to the limited number of images, non-deep machine learning techniques were utilized. The Random Forest technique exhibited superior performance, achieving a Root Mean Square Error (RMSE) of 0.95, Mean Absolute Error (MAE) of 0.12, and Coefficient of Determination (R2) ≈ 1, surpassing the other methods considered in this study. These results suggest that employing machine learning algorithms for predicting Vickers hardness from scanned images offers a promising avenue for rapid and accurate material assessment, potentially streamlining quality control processes in industrial settings. Full article
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13 pages, 6859 KiB  
Article
Effect of Sb Content on the Microstructure and Mechanical Properties of Eutectic SnPb Solder
by Xiuchen Zhao, Jiahui Chang, Xuefeng Wu, Zi-Ting Ye, Weiwei Chen and Xiaochen Xie
Materials 2024, 17(10), 2233; https://doi.org/10.3390/ma17102233 - 9 May 2024
Abstract
SnPb solder was widely used in electronic packaging for aerospace devices due to its high reliability. However, its creep resistance is poor and can be improved by adding alloying elements. The effects of Sb content on the microstructure, tensile, and creep properties of [...] Read more.
SnPb solder was widely used in electronic packaging for aerospace devices due to its high reliability. However, its creep resistance is poor and can be improved by adding alloying elements. The effects of Sb content on the microstructure, tensile, and creep properties of eutectic SnPb solder were investigated. Sb addition effectively improved the mechanical properties of the SnPb solder. When Sb content exceeds 1.7 wt.%, SbSn intermetallic compounds (IMCs) occurred. And increasing the Sb content increased the tensile strength. Furthermore, Sb addition decreased the steady-state creep rate and increased the stress exponent n, suggesting that the creep resistance had been enhanced, which may be attributed to the hindrance of dislocation movement by SbSn IMCs, as well as the reduction in phase boundaries, which consequently reduced grain boundary sliding. Full article
(This article belongs to the Special Issue Physical Metallurgy of Metals and Alloys II)
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12 pages, 1218 KiB  
Article
Enhancing Mechanical Properties and Microstructures of Mass-Manufactured Sand Concrete by Incorporating Granite Powder
by Jian Huang, Guangfeng Xu, Shujie Chen, Demei Yu, Tengfei Fu, Chao Feng and Yulin Wang
Materials 2024, 17(10), 2234; https://doi.org/10.3390/ma17102234 - 9 May 2024
Abstract
The production of manufactured sand and stone processing can cause dust pollution due to the generation of a significant amount of stone powder. This dust (mainly granite powder) was collected and incorporated as a cement replacement into mass-manufactured sand concrete in order to [...] Read more.
The production of manufactured sand and stone processing can cause dust pollution due to the generation of a significant amount of stone powder. This dust (mainly granite powder) was collected and incorporated as a cement replacement into mass-manufactured sand concrete in order to enhance the mechanical properties and microstructures. The heat of the hydration was measured by adding the granite powder into the cementitious material system. The mechanical properties, autogenous shrinkage, and pore structures of the concrete were tested. The results showed that the mechanical strength of the concrete increased first and then decreased with the increase in granite powder content. By replacing the 5% cement with the granite powder, the 28 d compressive and flexural strength increased by 17.6% and 20.9%, respectively. The autogenous shrinkage was mitigated by the incorporation of the 10% granite powder and decreased by 19.7%. The mechanism of the granite powder in the concrete was studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP). The porosity decreased significantly within the 10% granite powder. A microstructure analysis did not reveal a change in the type of hydration products but rather that the granite powder played a role in the microcrystalline nucleation during the hydration process. Full article
(This article belongs to the Special Issue Functional Cement-Based Composites for Civil Engineering (Volume II))
17 pages, 5460 KiB  
Article
Transient Temperature at Tool–Chip Interface during Initial Period of Chip Formation in Orthogonal Cutting of Inconel 718
by Youssef Alammari, Jian Weng, Jannis Saelzer and Dirk Biermann
Materials 2024, 17(10), 2232; https://doi.org/10.3390/ma17102232 - 9 May 2024
Abstract
Machining nickel-based super alloys such as Inconel 718 generates a high thermal load induced via friction and plastic deformation, causing these alloys to be among most difficult-to-cut materials. Localized heat generation occurring in machining induces high temperature gradients. Experimental techniques for determining cutting [...] Read more.
Machining nickel-based super alloys such as Inconel 718 generates a high thermal load induced via friction and plastic deformation, causing these alloys to be among most difficult-to-cut materials. Localized heat generation occurring in machining induces high temperature gradients. Experimental techniques for determining cutting tool temperature are challenging due to the small dimensions of the heat source and the chips produced, making it difficult to observe the tool–chip interface. Therefore, theoretical analysis of cutting temperatures is crucial for understanding heat generation and temperature distribution during cutting operations. Periodic heating and cooling occurring during cutting and interruption, respectively, are modeled using a hybrid analytical and finite element (FE) transient thermal model. In addition to identifying a transition distance associated with initial period of chip formation (IPCF) from apparent coefficient of friction results using a sigmoid function, the transition temperature is also identified using the thermal model. The model is validated experimentally by measuring the tool–chip interface temperature using a two-color pyrometer at a specific cutting distance. Due to the cyclic behavior in interrupted cutting, where a steady-state condition may or may not be achieved, transient thermal modeling is required in this case. Input parameters required to identify the heat flux for the transient thermal model are obtained experimentally and the definitions of heat-flux-reducing factors along the cutting path are associated with interruptions and the repeating IPCF. The thermal model consists of two main parts: one is related to identifying the heat flux, and the other part involves the determination of the temperature field within the tool using a partial differential equation (PDE) solved numerically via a 2D finite element method. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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14 pages, 2588 KiB  
Article
Thermogravimetric Analysis of Moisture in Natural and Thermally Treated Clay Materials
by Giulia Lo Dico, Lorenzo Lisuzzo, Verónica Carcelén, Giuseppe Cavallaro and Maciej Haranczyka
Materials 2024, 17(10), 2231; https://doi.org/10.3390/ma17102231 - 9 May 2024
Abstract
Clays are a class of porous materials; their surfaces are naturally covered by moisture. Weak thermal treatment may be considered practical to remove the water molecules, changing the surface properties and making the micro- and/or mesoporosities accessible to interact with other molecules. Herein, [...] Read more.
Clays are a class of porous materials; their surfaces are naturally covered by moisture. Weak thermal treatment may be considered practical to remove the water molecules, changing the surface properties and making the micro- and/or mesoporosities accessible to interact with other molecules. Herein, a modulated thermogravimetric analysis (MTGA) study of the moisture behavior on the structures of five, both fibrous and laminar, clay minerals is reported. The effect of the thermal treatment at 150 °C, which provokes the release of weakly adsorbed water molecules, was also investigated. The activation energies for the removal of the adsorbed water (Ea) were calculated, and they were found to be higher, namely, from 160 to 190 kJ mol−1, for fibrous clay minerals compared to lamellar structures, ranging in this latter case from 80 to 100 kJ mol−1. The thermal treatment enhances the rehydration in Na-montmorillonite, stevensite, and sepiolite structures with a decrease in the energy required to remove it, while Ea increases significantly in palygorskite (from 164 to 273 kJ mol−1). As a proof of concept, the MTGA results are statistically correlated, together with a full characterization of the physico-chemical properties of the five clay minerals, with the adsorption of two molecules, i.e., aflatoxin B1 (AFB1) and β-carotene. Herein, the amount of adsorbed molecules ranges from 12 to 97% for the former and from 22 to 35% for the latter, depending on the particular clay. The Ea was correlated with AFB1 adsorption with a Spearman score of −0.9. When the adsorbed water is forcibly removed, e.g., under vacuum conditions and high temperatures, the structure becomes the most important, decreasing the Spearman score between β-carotene and Ea to −0.6. Full article
(This article belongs to the Special Issue Porous Ceramics, Glasses and Composites, Volume II)
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18 pages, 21085 KiB  
Article
High-Temperature Cyclic Oxidation Behavior and Microstructure Evolution of W- and Ce-Containing 18Cr-Mo Type Ferritic Stainless Steel
by Jiahao Zheng, Yang Feng, Yang Zhao and Liqing Chen
Materials 2024, 17(10), 2230; https://doi.org/10.3390/ma17102230 - 9 May 2024
Abstract
Due to the recurrent starting and stopping operations of automobiles during service, their engines’ hot ends are continually subjected to high-temperature cyclic oxidation. Therefore, it is crucial to develop ferritic stainless steels with better high-temperature oxidation resistance. This study focuses on improving the [...] Read more.
Due to the recurrent starting and stopping operations of automobiles during service, their engines’ hot ends are continually subjected to high-temperature cyclic oxidation. Therefore, it is crucial to develop ferritic stainless steels with better high-temperature oxidation resistance. This study focuses on improving the high-temperature cyclic oxidation performance of 18Cr-Mo (444-type) ferritic stainless steel by alloying with high-melting-point metal W and the rare earth element Ce. For this purpose, a high-temperature cyclic oxidation experiment was designed to simulate the actual service environment and investigate the high-temperature cyclic oxidation behavior and microstructure evolution of 444-type ferritic stainless steel alloyed with W and Ce. The oxide structure and composition formed during this process were analyzed and characterized using scanning electron microscopy/energy dispersive spectroscopy (SEM-EDS) and electron probe X-ray micro-analyzer (EPMA), in order to reveal the mechanism of action of W and Ce in the cyclic oxidation process. The results show that 18Cr-Mo ferritic stainless steel alloyed with W and Ce exhibits an excellent resistance to high-temperature cyclic oxidation. The element W can promote the precipitation of the Laves phase between the matrix and the oxide film, and the small-sized Laves phase can inhibit the interfacial diffusion of oxidation reaction elements and prevent the inward growth of the oxide film. The element Ce can refine oxide particles and reduce the thickness of the oxide film. CeO2 particles within the oxide film can serve as nucleation sites for the formation of oxide particles from reactive elements, and they also contribute to pinning the oxide film, thereby enhancing its adhesion. Full article
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41 pages, 762 KiB  
Review
Anomaly Detection in Blockchain Networks Using Unsupervised Learning: A Survey
by Christos Cholevas, Eftychia Angeli, Zacharoula Sereti, Emmanouil Mavrikos and George E. Tsekouras
Algorithms 2024, 17(5), 201; https://doi.org/10.3390/a17050201 - 9 May 2024
Abstract
In decentralized systems, the quest for heightened security and integrity within blockchain networks becomes an issue. This survey investigates anomaly detection techniques in blockchain ecosystems through the lens of unsupervised learning, delving into the intricacies and going through the complex tapestry of abnormal [...] Read more.
In decentralized systems, the quest for heightened security and integrity within blockchain networks becomes an issue. This survey investigates anomaly detection techniques in blockchain ecosystems through the lens of unsupervised learning, delving into the intricacies and going through the complex tapestry of abnormal behaviors by examining avant-garde algorithms to discern deviations from normal patterns. By seamlessly blending technological acumen with a discerning gaze, this survey offers a perspective on the symbiotic relationship between unsupervised learning and anomaly detection by reviewing this problem with a categorization of algorithms that are applied to a variety of problems in this field. We propose that the use of unsupervised algorithms in blockchain anomaly detection should be viewed not only as an implementation procedure but also as an integration procedure, where the merits of these algorithms can effectively be combined in ways determined by the problem at hand. In that sense, the main contribution of this paper is a thorough study of the interplay between various unsupervised learning algorithms and how this can be used in facing malicious activities and behaviors within public and private blockchain networks. The result is the definition of three categories, the characteristics of which are recognized in terms of the way the respective integration takes place. When implementing unsupervised learning, the structure of the data plays a pivotal role. Therefore, this paper also provides an in-depth presentation of the data structures commonly used in unsupervised learning-based blockchain anomaly detection. The above analysis is encircled by a presentation of the typical anomalies that have occurred so far along with a description of the general machine learning frameworks developed to deal with them. Finally, the paper spotlights challenges and directions that can serve as a comprehensive compendium for future research efforts. Full article
(This article belongs to the Special Issue Deep Learning for Anomaly Detection)

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