The 2023 MDPI Annual Report has
been released!
 
17 pages, 780 KiB  
Review
Ultrasound Elastography: Methods, Clinical Applications, and Limitations: A Review Article
by Ammar A. Oglat and Tala Abukhalil
Appl. Sci. 2024, 14(10), 4308; https://doi.org/10.3390/app14104308 (registering DOI) - 19 May 2024
Abstract
Ultrasound is a highly adaptable medical imaging modality that offers several applications and a wide range of uses, both for diagnostic and therapeutic purposes. The principles of sound wave propagation and reflection enable ultrasound imaging to function as a highly secure modality. This [...] Read more.
Ultrasound is a highly adaptable medical imaging modality that offers several applications and a wide range of uses, both for diagnostic and therapeutic purposes. The principles of sound wave propagation and reflection enable ultrasound imaging to function as a highly secure modality. This technique facilitates the production of real-time visual representations, thereby assisting in the evaluation of various medical conditions such as cardiac, gynecologic, and abdominal diseases, among others. The ultrasound modality encompasses a diverse range of modes and mechanisms that serve to enhance the methodology of pathology and physiology assessment. Doppler imaging and US elastography, in particular, are two such techniques that contribute to this expansion. Elastography-based imaging methods have attracted significant interest in recent years for the non-invasive evaluation of tissue mechanical characteristics. These techniques utilize the changes in soft tissue elasticity in various diseases to generate both qualitative and quantitative data for diagnostic purposes. Specialized imaging techniques collect data by identifying tissue stiffness under mechanical forces such as compression or shear waves. However, in this review paper, we provide a comprehensive examination of the fundamental concepts, underlying physics, and limitations associated with ultrasound elastography. Additionally, we present a concise overview of its present-day clinical utilization and ongoing advancements across many clinical domains. Full article
(This article belongs to the Special Issue Elastography in Evaluating Small Parts)
22 pages, 19346 KiB  
Article
A Two-Layer SD-ANN-CA Model Framework for Multi-Typed Land Use and Land Cover Change Prediction under Constraints: Case Study of Ya’an City Area, Western China
by Jingyao Zhao, Xiaofan Zhu, Fan Zhang and Lei Gao
Land 2024, 13(5), 714; https://doi.org/10.3390/land13050714 (registering DOI) - 19 May 2024
Abstract
Land use and land cover change (LUCC) prediction of cities in Western China requires higher accuracy in quantitative demand and spatial layout because of complex challenges in balancing relationships between urban constructions and ecological developments. Considering city-level areas and various types of land [...] Read more.
Land use and land cover change (LUCC) prediction of cities in Western China requires higher accuracy in quantitative demand and spatial layout because of complex challenges in balancing relationships between urban constructions and ecological developments. Considering city-level areas and various types of land use and land cover, existing LUCC models without constraint or with only loose demand constraints were impractical in providing evidence of high accuracy and high-resolution predictions in areas facing fierce land competition. In this study, we proposed a two-layer SD-ANN-CA model to simulate and explore the LUCC trend and layout predictions for 2018, 2028, and 2038 in Ya’an City, Western China. The two-layer structure with an upper layer of the SD model and a lower layer of the ANN-CA model, as well as the advantages of all three methods of system dynamics (SD), artificial neural network (ANN), and cellular automata (CA), have allowed us to consider the macro-level demand constraints, meso-level driving factors constraints, and the micro-level spatial constraints into a unified model framework. The simulation results of the year 2018 have shown significant improvement in the accuracy of the ANN-CA model constructed in our earlier work, especially in types of forest land (error-accuracy: 0.08%), grassland (error-accuracy: 0.23%), and construction land (error-accuracy: 0.18%). The layout predictions of all six types of land use in 2028 and 2038 are then carried out to provide visual evidence support, which may improve the efficiency of planning and policy-making processes. Our work may also provide insights into new ways to combine quantitative methods into spatial methods in constructing city-level or even regional-level LUCC models with high resolution. Full article
(This article belongs to the Topic Urban Land Use and Spatial Analysis)
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20 pages, 1882 KiB  
Article
Preparation of n-Tetradecane Phase Change Microencapsulated Polyurethane Coating and Experiment on Anti-Icing Performance for Wind Turbine Blades
by Yiting Wang, He Shen, Zheng Sun, Yan Li and Fang Feng
Coatings 2024, 14(5), 645; https://doi.org/10.3390/coatings14050645 (registering DOI) - 19 May 2024
Abstract
Icing is a common physical phenomenon, and the icing of wind turbine blades can significantly affect the performance of wind turbines. Therefore, researching methods to prevent icing is of great significance, and the coating method of anti-icing is an effective way to delay [...] Read more.
Icing is a common physical phenomenon, and the icing of wind turbine blades can significantly affect the performance of wind turbines. Therefore, researching methods to prevent icing is of great significance, and the coating method of anti-icing is an effective way to delay icing, with advantages such as low energy consumption and easy implementation. In this study, using the coating method as the background, tetradecane phase change microcapsules were prepared, with a melting enthalpy of 90.8 J/g and a crystallization enthalpy of 96.3 J/g, exhibiting good coverage and energy storage efficiency. After mixing tetradecane phase change microcapsules (PCMS) with polyurethane coating (PUR) and coating them on wind turbine blades, after a 5 min icing wind tunnel test, the coating could significantly delay the icing on the blade surface, with the highest anti-icing rate reaching 60.41%. This indicates that the coating has a good anti-icing effect and provides basic research data for exploring new anti-icing methods. Full article
11 pages, 354 KiB  
Article
Bioethics, Suffering, and the Culture Wars
by Jonathan B. Imber
Religions 2024, 15(5), 622; https://doi.org/10.3390/rel15050622 (registering DOI) - 19 May 2024
Abstract
This article provides an analysis of the enduring disagreements among bioethicists over the divide between secular and religious boundaries that are reflected in liberal, libertarian, and conservative approaches to medicine as a profession and vocation. At the beginning of the twentieth century, the [...] Read more.
This article provides an analysis of the enduring disagreements among bioethicists over the divide between secular and religious boundaries that are reflected in liberal, libertarian, and conservative approaches to medicine as a profession and vocation. At the beginning of the twentieth century, the most authoritative voices to address the problem of suffering were Protestants, Strict Calvinists, hydropaths, and homeopaths. Other religious and medical groups had regularly confronted pain and suffering in the nineteenth century in light of the discovery and increasing use of anesthesia. Rationalizations for suffering were first and foremost indebted to strong beliefs about divine will and about the seemingly inevitable course of nature. Did physical pain reflect the wrongdoing of one individual or of an entire community? What was the appropriate way to respond to the natural circumstances of growth, decay, and healing? Such questions produced a varied rhetoric of suffering that emerged in new ways in the second half of the twentieth century. Questions and concerns about the ethical foundations of medical practice—what should and should not be permitted—illustrate the present cultural struggles. Full article
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16 pages, 1348 KiB  
Article
Integration of Chemical Looping Combustion to a Gasified Stream with Low Hydrogen Content
by Guadalupe S. Fraga-Cruz, Mario A. Pérez-Méndez, Gladys Jiménez-García, Rafael Huirache-Acuña, Fabricio Nápoles-Rivera, Jaime Espino-Valencia and Rafael Maya-Yescas
Processes 2024, 12(5), 1033; https://doi.org/10.3390/pr12051033 (registering DOI) - 19 May 2024
Abstract
Global population growth requires the use of various natural resources to satisfy the basic needs of humanity. Fossil fuels are mainly used to produce electricity, transportation and the artificial air conditioning of habitats. Nevertheless, countries around the world are looking for alternative energy [...] Read more.
Global population growth requires the use of various natural resources to satisfy the basic needs of humanity. Fossil fuels are mainly used to produce electricity, transportation and the artificial air conditioning of habitats. Nevertheless, countries around the world are looking for alternative energy sources due to the decrease in the availability of these fuels and their high environmental impact. The mixture of hydrogen and carbon monoxide (H2 + CO), commonly called syngas, is a high-value feedstock for various industrial applications. By varying the composition of syngas, especially the H2/CO molar ratio, it can be used to produce methanol, fuels or synthetic natural gas. However, when this ratio is very low, the separation of this gas usually represents a great problem when making the energy balance, which is why it is proposed to adapt a combustion process in chemical cycles, taking advantage of the energy of this gas, reducing the energy impact of the process. During the present project, mass and energy balances were developed for combustion in chemical cycles, using ilmenite as a carrier, integrating heat exchangers to take advantage of the residual energy at the output of the process, to preheat the inlet current in the regenerator. Here, a comparative was made at different temperatures of the air stream and evaluating the mechanism of the ilmenite when a syngas stream is used as fuel. Full article
(This article belongs to the Section Chemical Processes and Systems)
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21 pages, 3224 KiB  
Article
Factors Influencing Public Building Energy Consumption: A Case Study of Changjiang River Administration of Navigation Affairs in China
by Longhua Wang, Jingxin Cao, Yuanzhou Zheng, Yang Xu, Long You and Yibo Wang
Sustainability 2024, 16(10), 4289; https://doi.org/10.3390/su16104289 (registering DOI) - 19 May 2024
Abstract
Based on the energy consumption data of the Changjiang River Administration of Navigation Affairs public building located in Wuhan, China, this paper analyzes the energy consumption characteristics of public buildings. Using the DesignBuilder energy simulation software (v7.0.0.096), various factors influencing building energy consumption [...] Read more.
Based on the energy consumption data of the Changjiang River Administration of Navigation Affairs public building located in Wuhan, China, this paper analyzes the energy consumption characteristics of public buildings. Using the DesignBuilder energy simulation software (v7.0.0.096), various factors influencing building energy consumption are investigated. Furthermore, SPSS (v26.0.0.0) is employed to conduct correlation analyses between measured and simulated energy consumption data. The results indicate that the most significant factors affecting energy consumption are outdoor temperature, office equipment usage time, anticipated room temperature settings, boiler usage time, and per capita daily water consumption. By exploring the factors influencing energy consumption in public buildings, this study contributes novel insights into setting targets, adjusting schemes, and achieving energy-saving effects. Full article
13 pages, 1694 KiB  
Article
Effects of CO2 Geosequestration on Opalinus Clay
by Taimoor Asim and Haval Kukha Hawez
Energies 2024, 17(10), 2431; https://doi.org/10.3390/en17102431 (registering DOI) - 19 May 2024
Abstract
CO2 geosequestration is an important contributor to United Nations Sustainable Development Goal 13, i.e., Climate Action, which states a global Net-Zero CO2 emissions by 2050. A potential impact of CO2 geosequestration in depleted oil and gas reservoirs is the variations [...] Read more.
CO2 geosequestration is an important contributor to United Nations Sustainable Development Goal 13, i.e., Climate Action, which states a global Net-Zero CO2 emissions by 2050. A potential impact of CO2 geosequestration in depleted oil and gas reservoirs is the variations in induced pressure across the caprocks, which can lead to significant local variations in CO2 saturation. A detailed understanding of the relationship between the pressure gradient across the caprock and local CO2 concentration is of utmost importance for assessing the potential of CO2 geosequestration. Achieving this through experimental techniques is extremely difficult, and thus, we employ a coupled Computational Fluid Dynamics (CFD) and Finite Element Method (FEM) based solver to mimic sub-critical CO2 injection in Opalinus Clay under various pressure gradients across the sample. The geomechanical and multiphase flow modelling utilising Darcy Law helps evaluate local variations in CO2 concentration in Opalinus Clay. Well-validated numerical results indicate favourable sub-critical CO2 geosequestration under a positive pressure gradient across Opalinus Clay. In the absence of a positive pressure gradient, a peak CO2 concentration of 5% has been recorded, which increases substantially (above 90%) as the pressure gradient across the sample increases. Full article
(This article belongs to the Section B3: Carbon Emission and Utilization)
13 pages, 328 KiB  
Article
Valuation of Goodwill for an Engineering Firm
by Bhushan Lohar, John Wade and Sean Walker
J. Risk Financial Manag. 2024, 17(5), 212; https://doi.org/10.3390/jrfm17050212 (registering DOI) - 19 May 2024
Abstract
The concept of valuing personal and enterprise goodwill is a study in the art of quantifying subjective values. Sellers strive to maximize goodwill, while buyers strive to minimize goodwill. No persons are denying the existence of goodwill; rather, the debate is centered around [...] Read more.
The concept of valuing personal and enterprise goodwill is a study in the art of quantifying subjective values. Sellers strive to maximize goodwill, while buyers strive to minimize goodwill. No persons are denying the existence of goodwill; rather, the debate is centered around the value of that goodwill. This paper seeks to define a holistic approach to fairly quantifying the value of goodwill for an engineering firm. The Graph Model for Conflict Resolution (GMCR), a decision tool grounded in game theory, is used to illustrate the inherent conflict around setting an accurate goodwill value and the inherent negotiation between buyers and sellers. Full article
(This article belongs to the Section Business and Entrepreneurship)
12 pages, 753 KiB  
Article
The Landscape of Presence/Absence Variations during the Improvement of Rice
by Xia Zhou, Chenggen Qiang, Lei Chen, Dongjin Qing, Juan Huang, Jilong Li and Yinghua Pan
Genes 2024, 15(5), 645; https://doi.org/10.3390/genes15050645 (registering DOI) - 19 May 2024
Abstract
Rice is one of the most important staple crops in the world; therefore, the improvement of rice holds great significance for enhancing agricultural production and addressing food security challenges. Although there have been numerous studies on the role of single-nucleotide polymorphisms (SNPs) in [...] Read more.
Rice is one of the most important staple crops in the world; therefore, the improvement of rice holds great significance for enhancing agricultural production and addressing food security challenges. Although there have been numerous studies on the role of single-nucleotide polymorphisms (SNPs) in rice improvement with the development of next-generation sequencing technologies, research on the role of presence/absence variations (PAVs) in the improvement of rice is limited. In particular, there is a scarcity of studies exploring the traits and genes that may be affected by PAVs in rice. Here, we extracted PAVs utilizing resequencing data from 148 improved rice varieties distributed in Asia. We detected a total of 33,220 PAVs and found that the number of variations decreased gradually as the length of the PAVs increased. The number of PAVs was the highest on chromosome 1. Furthermore, we identified a 6 Mb hotspot region on chromosome 11 containing 1091 PAVs in which there were 29 genes related to defense responses. By conducting a genome-wide association study (GWAS) using PAV variation data and phenotypic data for five traits (flowering time, plant height, flag leaf length, flag leaf width, and panicle number) across all materials, we identified 186 significantly associated PAVs involving 20 cloned genes. A haplotype analysis and expression analysis of candidate genes revealed that important genes might be affected by PAVs, such as the flowering time gene OsSFL1 and the flag leaf width gene NAL1. Our work investigated the pattern in PAVs and explored important PAV key functional genes associated with agronomic traits. Consequently, these results provide potential and exploitable genetic resources for rice breeding. Full article
(This article belongs to the Special Issue Genetics and Genomics of Rice)
12 pages, 3824 KiB  
Article
The Development and Implementation of Innovative Blind Source Separation Techniques for Real-Time Extraction and Analysis of Fetal and Maternal Electrocardiogram Signals
by Mohcin Mekhfioui, Aziz Benahmed, Ahmed Chebak, Rachid Elgouri and Laamari Hlou
Bioengineering 2024, 11(5), 512; https://doi.org/10.3390/bioengineering11050512 (registering DOI) - 19 May 2024
Abstract
This article presents an innovative approach to analyzing and extracting electrocardiogram (ECG) signals from the abdomen and thorax of pregnant women, with the primary goal of isolating fetal ECG (fECG) and maternal ECG (mECG) signals. To resolve the difficulties related to the low [...] Read more.
This article presents an innovative approach to analyzing and extracting electrocardiogram (ECG) signals from the abdomen and thorax of pregnant women, with the primary goal of isolating fetal ECG (fECG) and maternal ECG (mECG) signals. To resolve the difficulties related to the low amplitude of the fECG, various noise sources during signal acquisition, and the overlapping of R waves, we developed a new method for extracting ECG signals using blind source separation techniques. This method is based on independent component analysis algorithms to detect and accurately extract fECG and mECG signals from abdomen and thorax data. To validate our approach, we carried out experiments using a real and reliable database for the evaluation of fECG extraction algorithms. Moreover, to demonstrate real-time applicability, we implemented our method in an embedded card linked to electronic modules that measure blood oxygen saturation (SpO2) and body temperature, as well as the transmission of data to a web server. This enables us to present all information related to the fetus and its mother in a mobile application to assist doctors in diagnosing the fetus’s condition. Our results demonstrate the effectiveness of our approach in isolating fECG and mECG signals under difficult conditions and also calculating different heart rates (fBPM and mBPM), which offers promising prospects for improving fetal monitoring and maternal healthcare during pregnancy. Full article
(This article belongs to the Section Biosignal Processing)
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36 pages, 1278 KiB  
Review
Developing Next-Generation Live Attenuated Vaccines for Porcine Epidemic Diarrhea Using Reverse Genetic Techniques
by Ruisong Yu, Shijuan Dong, Bingqing Chen, Fusheng Si and Chunhua Li
Vaccines 2024, 12(5), 557; https://doi.org/10.3390/vaccines12050557 (registering DOI) - 19 May 2024
Abstract
Porcine epidemic diarrhea virus (PEDV) is the etiology of porcine epidemic diarrhea (PED), a highly contagious digestive disease in pigs and especially in neonatal piglets, in which a mortality rate of up to 100% will be induced. Immunizing pregnant sows remains the most [...] Read more.
Porcine epidemic diarrhea virus (PEDV) is the etiology of porcine epidemic diarrhea (PED), a highly contagious digestive disease in pigs and especially in neonatal piglets, in which a mortality rate of up to 100% will be induced. Immunizing pregnant sows remains the most promising and effective strategy for protecting their neonatal offspring from PEDV. Although half a century has passed since its first report in Europe and several prophylactic vaccines (inactivated or live attenuated) have been developed, PED still poses a significant economic concern to the swine industry worldwide. Hence, there is an urgent need for novel vaccines in clinical practice, especially live attenuated vaccines (LAVs) that can induce a strong protective lactogenic immune response in pregnant sows. Reverse genetic techniques provide a robust tool for virological research from the function of viral proteins to the generation of rationally designed vaccines. In this review, after systematically summarizing the research progress on virulence-related viral proteins, we reviewed reverse genetics techniques for PEDV and their application in the development of PED LAVs. Then, we probed into the potential methods for generating safe, effective, and genetically stable PED LAV candidates, aiming to provide new ideas for the rational design of PED LAVs. Full article
(This article belongs to the Special Issue Porcine Virus and Vaccines)
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19 pages, 7906 KiB  
Article
Abundant New Optical Soliton Solutions to the Biswas–Milovic Equation with Sensitivity Analysis for Optimization
by Md Nur Hossain, Faisal Alsharif, M. Mamun Miah and Mohammad Kanan
Mathematics 2024, 12(10), 1585; https://doi.org/10.3390/math12101585 (registering DOI) - 19 May 2024
Abstract
This study extensively explores the Biswas–Milovic equation (BME) with Kerr and power law nonlinearity to extract the unique characteristics of optical soliton solutions. These optical soliton solutions have different applications in the field of precision in optical switching, applications in waveguide design, exploration [...] Read more.
This study extensively explores the Biswas–Milovic equation (BME) with Kerr and power law nonlinearity to extract the unique characteristics of optical soliton solutions. These optical soliton solutions have different applications in the field of precision in optical switching, applications in waveguide design, exploration of nonlinear optical effects, imaging precision, reduced intensity fluctuations, suitability for optical signal processing in optical physics, etc. Through the powerful (G/G, 1/G)-expansion analytical method, a variety of soliton solutions are expressed in three distinct forms: trigonometric, hyperbolic, and rational expressions. Rigorous validation using Mathematica software ensures precision, while dynamic visual representations vividly portray various soliton patterns such as kink, anti-kink, singular soliton, hyperbolic, dark soliton, and periodic bright soliton solutions. Indeed, a sensitivity analysis was conducted to assess how changes in parameters affect the exact solutions, aiding in the understanding of system behavior and informing decision-making, especially in accurately designing or analyzing real-world optical phenomena. This investigation reveals the significant influence of parameters λ, τ, c, B, and Κ on the precise solutions in Kerr and power law nonlinearities within the BME. Notably, parameter λ exhibits consistently high sensitivity across all scenarios, while parameters τ and c demonstrate pronounced sensitivity in scenario III. The outcomes derived from this method are distinctive and carry significant implications for the dynamics of optical fibers and wave phenomena across various optical systems. Full article
(This article belongs to the Special Issue Exact Solutions and Numerical Solutions of Differential Equations)
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17 pages, 3544 KiB  
Article
New Solutions in Single-Cell Protein Production from Methane: Construction of Glycogen-Deficient Mutants of Methylococcus capsulatus MIR
by Sergey Y. But, Ruslan Z. Suleimanov, Igor Y. Oshkin, Olga N. Rozova, Ildar I. Mustakhimov, Nikolai V. Pimenov, Svetlana N. Dedysh and Valentina N. Khmelenina
Fermentation 2024, 10(5), 265; https://doi.org/10.3390/fermentation10050265 (registering DOI) - 19 May 2024
Abstract
The biotechnology of converting methane to single-cell protein (SCP) implies using fast-growing thermotolerant aerobic methanotrophic bacteria. Among the latter, members of the genus Methylococcus received significant research attention and are used in operating commercial plants. Methylococcus capsulatus MIR is a recently discovered member [...] Read more.
The biotechnology of converting methane to single-cell protein (SCP) implies using fast-growing thermotolerant aerobic methanotrophic bacteria. Among the latter, members of the genus Methylococcus received significant research attention and are used in operating commercial plants. Methylococcus capsulatus MIR is a recently discovered member of this genus with the potential to be used for the purpose of SCP production. Like other Methylococcus species, this bacterium stores carbon and energy in the form of glycogen, particularly when grown under nitrogen-limiting conditions. The genome of strain MIR encodes two glycogen synthases, GlgA1 and GlgA2, which are only moderately related to each other. To obtain glycogen-free cell biomass of this methanotroph, glycogen synthase mutants, ΔglgA1, ΔglgA2, and ΔglgA1ΔglgA2, were constructed. The mutant lacking both glycogen synthases exhibited a glycogen-deficient phenotype, whereas the intracellular glycogen content was not reduced in strains defective in either GlgA1 or GlgA2, thus suggesting functional redundancy of these enzymes. Inactivation of the glk gene encoding glucokinase also resulted in a sharp decrease in glycogen content and accumulation of free glucose in cells. Wild-type strain MIR and the mutant strain ΔglgA1ΔglgA2 were also grown in a bioreactor operated in batch and continuous modes. Cell biomass of ΔglgA1ΔglgA2 mutant obtained during batch cultivation displayed high protein content (71% of dry cell weight (DCW) compared to 54% DCW in wild-type strain) as well as a strong reduction in glycogen content (10.8 mg/g DCW compared to 187.5 mg/g DCW in wild-type strain). The difference in protein and glycogen contents in biomass of these strains produced during continuous cultivation was less pronounced, yet biomass characteristics relevant to SCP production were slightly better for ΔglgA1ΔglgA2 mutant. Genome analysis revealed the presence of glgA1-like genes in all methanotrophs of the Gammaproteobacteria and Verrucomicrobia, while only a very few methanotrophic representatives of the Alphaproteobacteria possessed these determinants of glycogen biosynthesis. The glgA2-like genes were present only in genomes of gammaproteobacterial methanotrophs with predominantly halo- and thermotolerant phenotypes. The role of glycogen in terms of energy reserve is discussed. Full article
10 pages, 920 KiB  
Systematic Review
Opiate Withdrawal-Associated Esotropia: A Case Report and Systematic Review
by Varun Kasula, Brody M. Fogleman, Maaya Dev, Tyler Rizzieri, Corinne O’Brien and Rupa Shetty
Psychiatry Int. 2024, 5(2), 231-240; https://doi.org/10.3390/psychiatryint5020016 (registering DOI) - 19 May 2024
Abstract
Esotropia, which is the medial deviation of one or both eyes, is a rare withdrawal symptom that has been associated with opiate addiction. We report a case of a 36-year-old female patient who developed acute-onset esotropia and diplopia after self-admission to a psychiatric [...] Read more.
Esotropia, which is the medial deviation of one or both eyes, is a rare withdrawal symptom that has been associated with opiate addiction. We report a case of a 36-year-old female patient who developed acute-onset esotropia and diplopia after self-admission to a psychiatric facility for fentanyl addiction treatment and a systematic review of this rare presentation. A search of four databases (PubMed, Scopus, Embase, and Google Scholar) was conducted as of January 2024. We found 15 documented cases of opiate withdrawal-associated esotropia, with an average age of 27.2 years and an average time between last use and symptom onset of 5.61 days. The most common symptom was diplopia, especially binocular diplopia, and the majority of cases resolved without pharmacologic intervention. Considering the current opioid crisis, our systematic review and case report add valuable insight into the less-explored neurological and ophthalmological consequences of opiate withdrawal, a condition that should always be considered in cases of acute or chronic onset esotropia. Full article
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38 pages, 22809 KiB  
Review
Nanoscale Cu2ZnSnSxSe(4−x) (CZTS/Se) for Sustainable Solutions in Renewable Energy, Sensing, and Nanomedicine
by Sayedmahdi Mohammadi, Navdeep Kaur and Daniela R. Radu
Crystals 2024, 14(5), 479; https://doi.org/10.3390/cryst14050479 (registering DOI) - 19 May 2024
Abstract
The importance and breadth of applications of the family of quaternary chalcogenides with the formula Cu2ZnSnSxSe(4−x) (CZTS/Se) where x = 0–4 are steadily expanding due to the tunable optoelectronic properties of these compounds and the Earth abundance of [...] Read more.
The importance and breadth of applications of the family of quaternary chalcogenides with the formula Cu2ZnSnSxSe(4−x) (CZTS/Se) where x = 0–4 are steadily expanding due to the tunable optoelectronic properties of these compounds and the Earth abundance of the elements in their composition. These p-type semiconductors are viewed as a viable alternative to Si, gallium arsenide, CdTe, and CIGS solar cells due to their cost effectiveness, Earth’s crust abundance, and non-toxic elements. Additionally, CZTS/Se compounds have demonstrated notable capabilities beyond solar cells, such as photoelectrochemical CO2 reduction, solar water splitting, solar seawater desalination, hydrogen production, and use as an antibacterial agent. Various routes have been explored for synthesizing pure CZTS/Se nanomaterials and significant efforts have been dedicated to reducing the occurrence of secondary phases. This review focuses on synthetic approaches for CZTS/Se nanomaterials, with emphasis on controlling the size and morphology of the nanoparticles and their recent application in solar energy harvesting and beyond, highlighting challenges in achieving the desired purity required in all these applications. Full article
(This article belongs to the Special Issue Semiconductor Nanocrystal Studies for Optoelectronic Applications)
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22 pages, 5413 KiB  
Article
Adsorbent Biomaterials Based on Natural Clays and Orange Peel Waste for the Removal of Anionic Dyes from Water
by Sonia Mihai, Andreea Bondarev, Cătalina Călin and Elena-Emilia Sȋrbu
Processes 2024, 12(5), 1032; https://doi.org/10.3390/pr12051032 (registering DOI) - 19 May 2024
Abstract
This study demonstrates the efficient removal of Alizarin Yellow R anionic dye (AY) from aqueous solutions using green adsorbents. Natural kaolin clay (A1), acid-modified natural clay (A2), chemically treated orange peel (C1) and biochar produced by the thermal treatment of orange peel (C2) [...] Read more.
This study demonstrates the efficient removal of Alizarin Yellow R anionic dye (AY) from aqueous solutions using green adsorbents. Natural kaolin clay (A1), acid-modified natural clay (A2), chemically treated orange peel (C1) and biochar produced by the thermal treatment of orange peel (C2) were tested for the adsorption of AY. The characteristics of the sorbents were determined by instrumental methods: SEM, EDS, FTIR, BET and TGA. The adsorption experiments were performed under different conditions, including the initial AY dye concentration, adsorbent weight, pH, temperature and contact time. The maximum adsorption capacities had values between 15.72 and 74.62 mg/g at 298 K and the optimal pH of 6.5 at initial concentrations ranging from 30 to 70 mg/L for all adsorbents. The equilibrium data were used for the adsorption isotherm models: Freundlich, Langmuir and Temkin. The Freundlich model fit best for the adsorbents A2, C1 and C2, and the Langmuir isotherm had the highest regression value for the adsorbent A1 (R2 = 0.9935). Thermodynamic parameters indicated the spontaneous and favorable adsorption process of AY. A study of the adsorption kinetics proved that they best fit the pseudo-second-order model, with the highest coefficients of determination (R2), outperforming the pseudo-first-order model. The results of this study indicate the potential for the valorization of locally available clays and orange peel waste in the purification processes of water. Full article
(This article belongs to the Section Environmental and Green Processes)
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12 pages, 6228 KiB  
Article
Construction of Monolayer Ti3C2Tx MXene on Nickel Foam under High Electrostatic Fields for High-Performance Supercapacitors
by Liyong Zhang, Jijie Chen, Guangzhi Wei, Han Li, Guanbo Wang, Tongjie Li, Juan Wang, Yehu Jiang, Le Bao and Yongxing Zhang
Nanomaterials 2024, 14(10), 887; https://doi.org/10.3390/nano14100887 (registering DOI) - 19 May 2024
Abstract
Ti3C2Tx MXene, as a common two-dimensional material, has a wide range of applications in electrochemical energy storage. However, the surface forces of few-layer or monolayer Ti3C2Tx MXene lead to easy agglomeration, which hinders [...] Read more.
Ti3C2Tx MXene, as a common two-dimensional material, has a wide range of applications in electrochemical energy storage. However, the surface forces of few-layer or monolayer Ti3C2Tx MXene lead to easy agglomeration, which hinders the demonstration of its performance due to the characteristics of layered materials. Herein, we report a facile method for preparing monolayer Ti3C2Tx MXene on nickel foam to achieve a self-supporting structure for supercapacitor electrodes under high electrostatic fields. Moreover, the specific capacitance varies with the deposition of different-concentration monolayer Ti3C2Tx MXene on nickel foam. As a result, Ti3C2Tx/NF has a high specific capacitance of 319 mF cm−2 at 2 mA cm−2 and an excellent long-term cycling stability of 94.4% after 7000 cycles. It was observed that the areal specific capacitance increases, whereas the mass specific capacitance decreases with the increasing loading mass. Attributable to the effect of the high electrostatic field, the self-supporting structure of the Ti3C2Tx/NF becomes denser as the concentration of the monolayer Ti3C2Tx MXene ink increases, ultimately affecting its electrochemical performance. This work provides a simple way to overcome the agglomeration problem of few-layer or monolayer MXene, then form a self-supporting electrode exhibiting excellent electrochemical performance. Full article
(This article belongs to the Special Issue Nanomaterials for Supercapacitors)
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11 pages, 400 KiB  
Article
Applying Resistant Starch to Improve the Gel and Water Retention of Reduced-Fat Pork Batter
by Chun Xie, Guang-Hui Liu, Ming-Hui Liang, Si-Han Li and Zhuang-Li Kang
Gels 2024, 10(5), 347; https://doi.org/10.3390/gels10050347 (registering DOI) - 19 May 2024
Abstract
Emulsified meat products contain high animal fat content, and excessive intake of animal fat is not good for health, so people are paying more and more attention to reduced-fat meat products. This study investigated the impact of varying proportions of pork back-fat and/or [...] Read more.
Emulsified meat products contain high animal fat content, and excessive intake of animal fat is not good for health, so people are paying more and more attention to reduced-fat meat products. This study investigated the impact of varying proportions of pork back-fat and/or resistant starch on the proximate composition, water and fat retention, texture properties, color, and rheology characteristic of pork batter. The results found that replacing pork back-fat with resistant starch and ice water significantly decreased the total lipid and energy contents of cooked pork batter (p < 0.05) while improving emulsion stability, cooking yield, texture, and rheology properties. Additionally, when the pork back-fat replacement ratio was no more than 50%, there was a significant increase in emulsion stability, cooking yield, hardiness, springiness, cohesiveness, chewiness, and L* and G’ values (p < 0.05). Furthermore, resistant starch and ice water enhanced myosin head and tail thermal stability and increased G’ value at 80 °C. However, the initial relaxation times significantly decreased (p < 0.05) and the peak ratio of P21 significantly increased from 84.62% to 94.03%, suggesting reduced fluidity of water. In conclusion, it is feasible to use resistant starch and ice water as a substitute for pork back-fat in order to produce reduced-fat pork batter with favorable gel and rheology properties. Full article
(This article belongs to the Special Issue Recent Advances in Food Gels)
35 pages, 1750 KiB  
Article
The Past, Present, and Future of the Internet: A Statistical, Technical, and Functional Comparison of Wired/Wireless Fixed/Mobile Internet
by Shahriar Shirvani Moghaddam
Electronics 2024, 13(10), 1986; https://doi.org/10.3390/electronics13101986 (registering DOI) - 19 May 2024
Abstract
This paper examines the quantitative and qualitative situation of the current fixed and mobile Internet and its expected future. It provides a detailed insight into the past, present, and future of the Internet along with the development of technology and the problems that [...] Read more.
This paper examines the quantitative and qualitative situation of the current fixed and mobile Internet and its expected future. It provides a detailed insight into the past, present, and future of the Internet along with the development of technology and the problems that have arisen in accessing and using broadband Internet. First, the number of users and penetration rate of the Internet, the various types of services in different countries, the ranking of countries in terms of the mean and median download and upload Internet data speeds, Internet data volume, and number and location of data centers in the world are presented. The second task introduces and details twelve performance evaluation metrics for broadband Internet access. Third, different wired and wireless Internet technologies are introduced and compared based on data rate, coverage, type of infrastructure, and their advantages and disadvantages. Based on the technical and functional criteria, in the fourth work, two popular wired and wireless Internet platforms, one based on optical fiber and the other based on the 5G cellular network, are compared in the world in general and Australia in particular. Moreover, this paper has a look at Starlink as the latest satellite Internet candidate, especially for rural and remote areas. The fifth task outlines the latest technologies and emerging broadband Internet-based services and applications in the spotlight. Sixthly, it focuses on three problems in the future Internet in the world, namely the digital divide due to the different qualities of available Internet and new Internet-based services and applications of emerging technologies, the impact of the Internet on social interactions, and hacking and insecurity on the Internet. Finally, some solutions to these problems are proposed. Full article
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39 pages, 3140 KiB  
Article
Can Digital Finance Enable China’s Industrial Carbon Unlocking under Environmental Regulatory Constraints? Joint Tests of Regression Analysis and Qualitative Comparative Analysis
by Weicheng Xu and Hanxia Li
Sustainability 2024, 16(10), 4288; https://doi.org/10.3390/su16104288 (registering DOI) - 19 May 2024
Abstract
Sustainable development goals challenge the carbon lock-in dilemma of the industrial economy, and identifying the motivation and mechanism behind carbon unlocking has become an urgent priority. With its inclusive and precise advantages, digital finance (DF) provides a new impetus for the economy’s low-carbon [...] Read more.
Sustainable development goals challenge the carbon lock-in dilemma of the industrial economy, and identifying the motivation and mechanism behind carbon unlocking has become an urgent priority. With its inclusive and precise advantages, digital finance (DF) provides a new impetus for the economy’s low-carbon transformation, while reasonable environmental regulation (ER) acts as an important guiding constraint. We focus on the carbon unlocking performance of DF under ER constraints. After constructing and calculating the industrial carbon unlocking efficiency (ICUE), we observe the trends of ICUE fluctuating positively, clustering towards the eastern region, and polarization. Subsequently, based on theoretical analyses, we explore the marginal and configuration effects of DF and ER in improving ICUE using panel data from 30 Chinese provinces between 2011 and 2021 and adopt a mixed research method with regression analysis (Tobit hierarchical regression and quantile regression for panel data (QRPD)) and dynamic fuzzy-set qualitative comparative analysis (fsQCA). The regression analysis results show that DF can notably enhance China’s provincial ICUE, with ER generally serving as a positive moderator; however, the unlocking potential of informal environmental regulations needs further exploration. As ICUE improves in a specific location or time, the positive contribution of DF to ICUE also increases, whereas the moderating effect of ER exhibits an optimal range and follows an inverted U-shape. The dynamic fsQCA results support the findings of the regression analysis and further emphasize that effective cooperation between DF and ER is crucial for high ICUE, while inadequate DF support and the absence of formal environmental regulations remain bottlenecks in industrial carbon lock-in. Moreover, configuration paths demonstrate clear path dependency in both time and space, indicating a prolonged unlocking endeavor. Full article
(This article belongs to the Special Issue Sustainable Growth and Carbon Neutrality)
33 pages, 1127 KiB  
Article
Conceptual Models of Franchisee Behaviors in the Dietary Supplements and Cosmetics to Imply the Business Investments
by Patcharapol Suttidharm and Adisorn Leelasantitham
Sustainability 2024, 16(10), 4287; https://doi.org/10.3390/su16104287 (registering DOI) - 19 May 2024
Abstract
Franchise businesses have demonstrated resilience before, through, and after the circumstances of COVID-19. This can be attributed to the inherent appeal of rapid success and risk mitigation for investors. Therefore, investors are attached to engaging in a franchise business model. Fierce competition exists [...] Read more.
Franchise businesses have demonstrated resilience before, through, and after the circumstances of COVID-19. This can be attributed to the inherent appeal of rapid success and risk mitigation for investors. Therefore, investors are attached to engaging in a franchise business model. Fierce competition exists among franchise businesses, with numerous brands within the same industry, especially the cosmetic and dietary supplement franchise category, which has garnered significant popularity in Southeast Asia, particularly Thailand. The expansion of this franchise category has accelerated, surpassing the growth rates observed in other countries. Investment decisions across various investor levels are influenced by diverse factors, including intense competition, contributing to the rapid expansion. Therefore, a comprehensive study and understanding of the investment behavior of cosmetic and dietary supplement franchise businesses has become imperative. The success of a franchise business hinges on different factors encompassing decisions made before, during, and after investments. This study delves into the decision-making behaviors preceding and following investments across different investor levels in the cosmetics and dietary supplement franchise industry, utilizing fundamental aspects derived from rational choice theory (RCT) and additional variables. The researcher gathered responses through questionnaires from 490 respondents with investment experience in the cosmetics and dietary supplement franchise business. The study revealed that factors postulated in this study significantly influenced investment choices within cosmetics and dietary supplement franchises. When segmented based on investor levels, distinct considerations emerged for each group. Furthermore, there is a compelling need for cosmetic and dietary supplement franchise owners to implement enhancements in services to uphold and expand investor bases, representing an intense challenge in the cosmetics and dietary supplement franchise business nowadays. This study is intended only for individuals with prior investment experience in the cosmetics and dietary supplement franchise industry. It focuses on examining the factors that influence investment decisions both before and after the initial investment, particularly with regard to dietary supplement and cosmetics franchises. Full article
(This article belongs to the Special Issue Sustainable Management and Consumer Behavior Studies)
24 pages, 2833 KiB  
Review
A Comprehensive Review of Plant-Based Biopolymers as Viscosity-Modifying Admixtures in Cement-Based Materials
by Yousra Boutouam, Mahmoud Hayek, Kamal Bouarab and Ammar Yahia
Appl. Sci. 2024, 14(10), 4307; https://doi.org/10.3390/app14104307 (registering DOI) - 19 May 2024
Abstract
As the construction industry is facing the challenge of meeting the ever-increasing demand for environmentally friendly and durable concrete, the role of viscosity-modifying admixtures (VMAs) has become increasingly essential to improve the rheological properties, stability, and mechanical properties of concrete. Additionally, natural polymers [...] Read more.
As the construction industry is facing the challenge of meeting the ever-increasing demand for environmentally friendly and durable concrete, the role of viscosity-modifying admixtures (VMAs) has become increasingly essential to improve the rheological properties, stability, and mechanical properties of concrete. Additionally, natural polymers are ever evolving, offering multiple opportunities for innovative applications and sustainable solutions. This comprehensive review delves into the historical context and classifications of VMAs, accentuating their impact in enhancing the rheological properties, stability, and mechanical properties of concrete. Emphasis is placed on the environmental impact of synthetic VMAs, promoting the exploration of sustainable alternatives derived from plant-based biopolymers. Indeed, biopolymers, such as cellulose, starch, alginate, pectin, and carrageenan are considered in this paper, focusing on understanding their efficacy in improving concrete properties while enhancing the environmental sustainability within the concrete. Full article
(This article belongs to the Special Issue Innovative Building Materials for Sustainable Built Environment)
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16 pages, 9672 KiB  
Article
Experimental Evaluation of a Granular Damping Element
by Sanel Avdić, Marko Nagode, Jernej Klemenc and Simon Oman
Polymers 2024, 16(10), 1440; https://doi.org/10.3390/polym16101440 (registering DOI) - 19 May 2024
Abstract
Due to their advantages—longer internal force delay compared to bulk materials, resistance to harsh conditions, damping of a wide frequency spectrum, insensitivity to ambient temperature, high reliability and low cost—granular materials are seen as an opportunity for the development of high-performance, lightweight vibration-damping [...] Read more.
Due to their advantages—longer internal force delay compared to bulk materials, resistance to harsh conditions, damping of a wide frequency spectrum, insensitivity to ambient temperature, high reliability and low cost—granular materials are seen as an opportunity for the development of high-performance, lightweight vibration-damping elements (particle dampers). The performance of particle dampers is affected by numerous parameters, such as the base material, the size of the granules, the flowability, the initial prestress, etc. In this work, a series of experiments were performed on specimens with different combinations of influencing parameters. Energy-based design parameters were used to describe the overall vibration-damping performance. The results provided information for a deeper understanding of the dissipation mechanisms and their mutual correlation, as well as the influence of different parameters (base material, granule size and flowability) on the overall damping performance. A comparison of the performance of particle dampers with carbon steel and polyoxymethylene granules and conventional rubber dampers is given. The results show that the damping performance of particle dampers can be up to 4 times higher compared to conventional bulk material-based rubber dampers, even though rubber as a material has better vibration-damping properties than the two granular materials in particle dampers. However, when additional design features such as mass and stiffness are introduced, the results show that the overall performance of particle dampers with polyoxymethylene granules can be up to 3 times higher compared to particle dampers with carbon steel granules and conventional bulk material-based rubber dampers. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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