The 2023 MDPI Annual Report has
been released!
 
19 pages, 8914 KiB  
Article
Dynamic Analysis and Field-Programmable Gate Array Implementation of a 5D Fractional-Order Memristive Hyperchaotic System with Multiple Coexisting Attractors
by Fei Yu, Wuxiong Zhang, Xiaoli Xiao, Wei Yao, Shuo Cai, Jin Zhang, Chunhua Wang and Yi Li
Fractal Fract. 2024, 8(5), 271; https://doi.org/10.3390/fractalfract8050271 (registering DOI) - 01 May 2024
Abstract
On the basis of the chaotic system proposed by Wang et al. in 2023, this paper constructs a 5D fractional-order memristive hyperchaotic system (FOMHS) with multiple coexisting attractors through coupling of magnetic control memristors and dimension expansion. Firstly, the divergence, Kaplan–Yorke dimension, and [...] Read more.
On the basis of the chaotic system proposed by Wang et al. in 2023, this paper constructs a 5D fractional-order memristive hyperchaotic system (FOMHS) with multiple coexisting attractors through coupling of magnetic control memristors and dimension expansion. Firstly, the divergence, Kaplan–Yorke dimension, and equilibrium stability of the chaotic model are studied. Subsequently, we explore the construction of the 5D FOMHS, introducing the definitions of the Caputo differential operator and the Riemann–Liouville integral operator and employing the Adomian resolving approach to decompose the linears, the nonlinears, and the constants of the system. The complex dynamic characteristics of the system are analyzed by phase diagrams, Lyapunov exponent spectra, time-domain diagrams, etc. Finally, the hardware circuit of the proposed 5D FOMHS is performed by FPGA, and its randomness is verified using the NIST tool. Full article
(This article belongs to the Special Issue Advances in Fractional-Order Chaotic and Complex Systems)
22 pages, 1509 KiB  
Article
Auditable Anonymous Electronic Examination
by Ádám Vécsi and Attila Pethő
Cryptography 2024, 8(2), 19; https://doi.org/10.3390/cryptography8020019 (registering DOI) - 01 May 2024
Abstract
Ensuring security in electronic examination systems represents a significant challenge, particularly when practical considerations dictate that most involved parties cannot be fully trusted due to self-interest. To enhance the security, we introduce auditability to e-exam systems, enabling an auditing authority to verify the [...] Read more.
Ensuring security in electronic examination systems represents a significant challenge, particularly when practical considerations dictate that most involved parties cannot be fully trusted due to self-interest. To enhance the security, we introduce auditability to e-exam systems, enabling an auditing authority to verify the system integrity. This auditability not only ensures system robustness but also creates an opportunity to grant communication between candidates and examiners, allowing for clarification on unclear questions during exams. Additionally, the implementation of attribute-based certifications ensures anonymity for both candidates and examiners throughout all stages of the exam, with the option for revocation in case of audit-detected fraud. Full article
(This article belongs to the Special Issue Privacy-Enhancing Technologies for the Digital Age)
15 pages, 10043 KiB  
Article
Investigation of the Structure and Properties of MoS2 Coatings Obtained by Electrospark Alloying
by Oksana Haponova, Viacheslav Tarelnyk, Tomasz Mościcki, Nataliia Tarelnyk, Joanna Półrolniczak, Oleksandr Myslyvchenko, Bogusława Adamczyk-Cieślak and Joanna Sulej-Chojnacka
Coatings 2024, 14(5), 563; https://doi.org/10.3390/coatings14050563 (registering DOI) - 01 May 2024
Abstract
Electrospark coatings alloyed with MoS2 have been studied. The coatings were obtained by the following two strategies: the first consisted of pre-applying molybdenum disulfide to the treated surface and alloying with a molybdenum electrode (Mo + MoS2 coating); the second consisted [...] Read more.
Electrospark coatings alloyed with MoS2 have been studied. The coatings were obtained by the following two strategies: the first consisted of pre-applying molybdenum disulfide to the treated surface and alloying with a molybdenum electrode (Mo + MoS2 coating); the second consisted of applying a paste with a sulfur content of 33.3% to the treated surface and alloying with a molybdenum electrode (Mo + S coating). The structure, phase composition, and tribological properties of the coatings were investigated. The coatings have a complex structure consisting of an upper soft layer, a hardened white layer, a diffusion zone, and a substrate. Element analysis and cross-sectional hardness changes indicated that element diffusion occurred at the coating/substrate interface. The phase composition of the coatings is represented by BCC and FCC solid solutions on Fe, and MoS2 is also detected. In Mo + S coatings, the molybdenum disulfide on the surface is about 8%; in Mo + MoS2 coatings, it is 27%–46%. The obtained coatings show very good tribological properties compared to molybdenum ESA coatings. The frictional forces and coefficients are reduced by a factor of 10 and 40, depending on the test conditions. Full article
(This article belongs to the Special Issue Functional Surface Modification Using Concentrated Energy Flows)
15 pages, 2813 KiB  
Article
An Engine-Level Safety Assessment Approach of Sustainable Aviation Fuel Based on a Multi-Fidelity Aerodynamic Model
by Shuiting Ding, Qinglin Ma, Tian Qiu, Chenyu Gan and Xinming Wang
Sustainability 2024, 16(9), 3814; https://doi.org/10.3390/su16093814 (registering DOI) - 01 May 2024
Abstract
Safety is essential for sustainable aviation fuels (SAFs). However, evaluating SAFs’ impacts on aero-engine safety is challenging because it involves multiple space scales and the strongly coupled relationships of aero-engine components. Aiming at addressing this problem, a model-based approach is proposed to establish [...] Read more.
Safety is essential for sustainable aviation fuels (SAFs). However, evaluating SAFs’ impacts on aero-engine safety is challenging because it involves multiple space scales and the strongly coupled relationships of aero-engine components. Aiming at addressing this problem, a model-based approach is proposed to establish the relationship between the fuel-level physical properties and engine-level safety parameters. Firstly, a unified modeling criterion is proposed to consider the interrelations of aero-engine components. Under this criterion, aero-engine secondary air system (SAS) components are included in SAF safety assessment, since they have non-neglectable influences on aero-engine safety. Secondly, this paper proposes a surrogate-based iteration strategy to embed the combustor’s high-dimensional computational fluid dynamics (CFD) model into the aero-engine flow network model. Then, the proposed model-based safety assessment approach is applied to a Fischer–Tropsch hydro-processed synthesized paraffinic kerosine (F-T SPK) safety assessment case. The effects of fuel flow and blending ratio are considered. The results indicate the necessity to evaluate SAFs’ safety at the aero-engine level and consider the influences of SAS components. The proposed model-based approach may provide a preliminary screening before SAFs’ certification tests. This convenience may be beneficial for reducing the cost and accelerating SAFs’ application. Full article
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20 pages, 614 KiB  
Review
Hemp Seeds (Cannabis sativa L.) as a Valuable Source of Natural Ingredients for Functional Foods—A Review
by Virginia Tănase Apetroaei, Eugenia Mihaela Pricop, Daniela Ionela Istrati and Camelia Vizireanu
Molecules 2024, 29(9), 2097; https://doi.org/10.3390/molecules29092097 (registering DOI) - 01 May 2024
Abstract
Hemp (Cannabis sativa L.) has experienced a significant resurgence in popularity, and global interest in diversifying its use in various industries, including the food industry, is growing. Therefore, due to their exceptional nutritional value, hemp seeds have recently gained increasing interest as [...] Read more.
Hemp (Cannabis sativa L.) has experienced a significant resurgence in popularity, and global interest in diversifying its use in various industries, including the food industry, is growing. Therefore, due to their exceptional nutritional value, hemp seeds have recently gained increasing interest as a valuable ingredient for obtaining high-quality foods and dietary supplements. Hemp seeds stand out for their remarkable content of quality proteins, including edestin and albumin, two distinct types of proteins that contribute to exceptional nutritional value. Hemp seeds are also rich in healthy lipids with a high content of polyunsaturated fatty acids, such as linoleic acid (omega-6), alpha-linolenic acid (omega-3), and some vitamins (vitamins E, D, and A). Polyphenols and terpenoids, in particular, present in hemp seeds, provide antimicrobial, antioxidant, and anti-inflammatory properties. This review examines the scientific literature regarding hemp seeds’ physicochemical and nutritional characteristics. The focus is on those characteristics that allow for their use in the food industry, aiming to transform ordinary food products into functional foods, offering additional benefits for the body’s health. Innovating opportunities to develop healthy, nutritionally superior food products are explored by integrating hemp seeds into food processes, promoting a balanced and sustainable diet. Full article
15 pages, 7291 KiB  
Article
In Situ Study on the Structural Evolution of Flexible Ionic Gel Sensors
by Shujun Yan, Jun Tang, Angui Zhang, Nie Zhao, Fu Wang and Shaowei Sun
Coatings 2024, 14(5), 562; https://doi.org/10.3390/coatings14050562 (registering DOI) - 01 May 2024
Abstract
With the development of society, the demand for smart coatings is increasing. The development of flexible strain sensors using block copolymer self-assembled ionic gel materials provides a promising method for promoting the development of smart coatings. The ionic liquid in the ionic part [...] Read more.
With the development of society, the demand for smart coatings is increasing. The development of flexible strain sensors using block copolymer self-assembled ionic gel materials provides a promising method for promoting the development of smart coatings. The ionic liquid in the ionic part of the material is crucial for the performance of the sensor. In this study, the structural changes within FDA/dEAN (self-assembly of acrylated Pluronic F127 (F127-DA) in partially deuterated ethylammonium nitrate (dEAN)) triblock copolymer ionic gel during uniaxial tensile flow were characterized using an in situ SAXS technique. The results revealed that the characteristics of the responses of the ionic gel to strain resistance were intricately linked to the evolution of its microstructure during the tensile process. At low levels of strain, the face-centered cubic lattice arrangement of the micelles tended to remain unchanged. However, when subjected to higher strains, the molecular chains aligned along the stretching direction, resulting in a more ordered structure with reduced entropy. This alignment led to significant disruption in bridging structures within the material. Furthermore, this research explored the impact of the stretching rate on the relaxation process. It was observed that higher stretching rates led to decreases in the average relaxation time, indicating rate dependence in the microstructure’s behavior. These findings provide valuable insights into the behavior and performance of flexible strain sensors based on ionic gel materials in smart coatings. Full article
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24 pages, 27766 KiB  
Article
Driving towards Sustainability: Wireless Charging of Low-Speed Vehicles with PDM-Based Active Bridge Rectifiers
by Yuvaraja Shanmugam, Narayanamoorthi Rajamanickam, Roobaea Alroobaea and Abdulkareem Afandi
Sustainability 2024, 16(9), 3810; https://doi.org/10.3390/su16093810 (registering DOI) - 01 May 2024
Abstract
The surge in demand for eco-friendly transportation and electric vehicle (EV) charging infrastructure necessitates innovative solutions. This study proposed a novel approach to charging slow-moving vehicles, prioritizing efficiency and minimizing output pulsation. Central to the research is the development of a receiver-side power-regulated [...] Read more.
The surge in demand for eco-friendly transportation and electric vehicle (EV) charging infrastructure necessitates innovative solutions. This study proposed a novel approach to charging slow-moving vehicles, prioritizing efficiency and minimizing output pulsation. Central to the research is the development of a receiver-side power-regulated constant charging system, focusing on power regulation and maintaining consistent charging parameters. This system integrates a receiver-side pulse density-modulated active bridge rectifier, dynamically adjusting driving pulse density to regulate delivered power. Additionally, a receiver-side reconfigurable compensation network ensures constant current and voltage delivery to the charging device, eliminating the need for an additional D.C.-D.C. converter. A 3.3 kW charging structure employing a multi-leg inverter topology and energizing four ground-side transmitter pads exemplifies the proposed approach. The vertical air gap of charging pads is 150 mm, and the system achieves a maximal efficiency of 93.4%. This innovative strategy holds significant promise for advancing sustainable transportation infrastructure and meeting the evolving demands of the EV market. Full article
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137 pages, 3338 KiB  
Review
Monte Carlo Based Techniques for Quantum Magnets with Long-Range Interactions
by Patrick Adelhardt, Jan A. Koziol, Anja Langheld and Kai P. Schmidt
Entropy 2024, 26(5), 401; https://doi.org/10.3390/e26050401 (registering DOI) - 01 May 2024
Abstract
Long-range interactions are relevant for a large variety of quantum systems in quantum optics and condensed matter physics. In particular, the control of quantum–optical platforms promises to gain deep insights into quantum-critical properties induced by the long-range nature of interactions. From a theoretical [...] Read more.
Long-range interactions are relevant for a large variety of quantum systems in quantum optics and condensed matter physics. In particular, the control of quantum–optical platforms promises to gain deep insights into quantum-critical properties induced by the long-range nature of interactions. From a theoretical perspective, long-range interactions are notoriously complicated to treat. Here, we give an overview of recent advancements to investigate quantum magnets with long-range interactions focusing on two techniques based on Monte Carlo integration. First, the method of perturbative continuous unitary transformations where classical Monte Carlo integration is applied within the embedding scheme of white graphs. This linked-cluster expansion allows extracting high-order series expansions of energies and observables in the thermodynamic limit. Second, stochastic series expansion quantum Monte Carlo integration enables calculations on large finite systems. Finite-size scaling can then be used to determine the physical properties of the infinite system. In recent years, both techniques have been applied successfully to one- and two-dimensional quantum magnets involving long-range Ising, XY, and Heisenberg interactions on various bipartite and non-bipartite lattices. Here, we summarise the obtained quantum-critical properties including critical exponents for all these systems in a coherent way. Further, we review how long-range interactions are used to study quantum phase transitions above the upper critical dimension and the scaling techniques to extract these quantum critical properties from the numerical calculations. Full article
18 pages, 2513 KiB  
Article
Construction and Change Analysis of Water Ecosystem Service Flow Networks in the Xiangjiang River Basin (XRB)
by Yaoting Gu, Xianlan Lao, Lilisha Zhuo, Xiaochang Li and Chuxiong Deng
Sustainability 2024, 16(9), 3813; https://doi.org/10.3390/su16093813 (registering DOI) - 01 May 2024
Abstract
Clearing and successfully characterizing ecosystem service flow paths has become a key bottleneck restricting in-depth research on the supply and demand relationships of ecosystem services. At present, although some explorations have been performed using water ecosystem services as a pioneer, the nature of [...] Read more.
Clearing and successfully characterizing ecosystem service flow paths has become a key bottleneck restricting in-depth research on the supply and demand relationships of ecosystem services. At present, although some explorations have been performed using water ecosystem services as a pioneer, the nature of its network and the fact that ecological base flow needs to be eliminated have been ignored. This study used InVEST and network models to consider ecological base flow, quantifying the supply, demand, and flow paths of freshwater ecosystem services in the Xiangjiang River Basin. The results showed that the overall distribution of the water supply in the Xiangjiang River Basin from 2000 to 2020 shows a pattern of higher supply in the south and lower supply in the north. The distribution of water demand shows higher levels in the north and lower levels in the south. The network density remains at its maximum level. The results of this study have provided a scientific basis for water resource management in river basins and improving ecological compensation mechanisms. Full article
(This article belongs to the Topic Hydrology and Water Resources Management)
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23 pages, 8319 KiB  
Article
The Influence of Confined Space Size on the Temperature Distribution Characteristics of Internal Window Plume from Well-Ventilated Compartment Fires
by Qiwei Dong, Yanfeng Li, Junmei Li, Fei Xie, Desheng Xu and Zhihe Su
Fire 2024, 7(5), 158; https://doi.org/10.3390/fire7050158 (registering DOI) - 01 May 2024
Abstract
In this research, the influence of confined space size on the temperature distribution characteristics of internal window plumes from well-ventilated compartment fires was studied. Theoretical analysis was firstly used to establish a mathematical model for the smoke after ejecting from the window in [...] Read more.
In this research, the influence of confined space size on the temperature distribution characteristics of internal window plumes from well-ventilated compartment fires was studied. Theoretical analysis was firstly used to establish a mathematical model for the smoke after ejecting from the window in the space. The study considered fire heat release rate and vertical height as dependent variables. Numerical simulations and experimental methods were carried out to study the temperature variations. A critical distance L2 was obtained. Results show that when the space D between the vertical retaining wall and the building façade is greater than L2, the variation of D has little influence on radial temperature. Once D is less than L2, the radial temperature distribution inside the confined space will tend to be consistent, and the temperature in the confined space sharply increases as D decreases. In addition, a dimensionless model was derived to quantify the relationship between temperature rise and vertical height. The experimental and numerical simulation results were processed, which are in good agreement with the model. The study can provide a framework for managing building safety. Full article
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32 pages, 4362 KiB  
Article
Experimental Evaluation of the Methane Number Measurement Procedure for Gaseous Fuel Rating
by Dawson P. Baucke, Daniel M. Wise, Robin J. Bremmer and Daniel B. Olsen
Energies 2024, 17(9), 2172; https://doi.org/10.3390/en17092172 (registering DOI) - 01 May 2024
Abstract
Methane Number (MN) is a fuel rating technique for gaseous fuels analogous to Octane Number. This study establishes and shares a repeatable and reproducible method for MN determination of a gaseous fuel using a modified Cooperative Fuel Research Engine (CFR). Adaptations required to [...] Read more.
Methane Number (MN) is a fuel rating technique for gaseous fuels analogous to Octane Number. This study establishes and shares a repeatable and reproducible method for MN determination of a gaseous fuel using a modified Cooperative Fuel Research Engine (CFR). Adaptations required to convert a CFR engine for use in the MN test procedure are identified. The investigation includes allowable environmental parameters and operating variation limits. An essential aspect of the MN method involves identifying and quantifying Knock Intensity (KI) during engine operation. CFR engines, originally designed for gasoline testing, come equipped with their own knock measurement systems utilizing a capacitive detonation sensor. The original system is compared with a Fast Fourier Transform (FFT) approach that uses a piezoelectric pressure transducer. Quantification of methane number requires an accurate assessment of the reference fuel blend (CH4 + H2). A comparison is carried out between dynamic blending using mass flow meters and bracketing using certified gas bottles containing various CH4/H2 blends from a gas supplier. Full article
(This article belongs to the Section B: Energy and Environment)
48 pages, 17876 KiB  
Review
Self-Assembled Block Copolymers as a Facile Pathway to Create Functional Nanobiosensor and Nanobiomaterial Surfaces
by Marion Ryan C. Sytu, David H. Cho and Jong-in Hahm
Polymers 2024, 16(9), 1267; https://doi.org/10.3390/polym16091267 (registering DOI) - 01 May 2024
Abstract
Block copolymer (BCP) surfaces permit an exquisite level of nanoscale control in biomolecular assemblies solely based on self-assembly. Owing to this, BCP-based biomolecular assembly represents a much-needed, new paradigm for creating nanobiosensors and nanobiomaterials without the need for costly and time-consuming fabrication steps. [...] Read more.
Block copolymer (BCP) surfaces permit an exquisite level of nanoscale control in biomolecular assemblies solely based on self-assembly. Owing to this, BCP-based biomolecular assembly represents a much-needed, new paradigm for creating nanobiosensors and nanobiomaterials without the need for costly and time-consuming fabrication steps. Research endeavors in the BCP nanobiotechnology field have led to stimulating results that can promote our current understanding of biomolecular interactions at a solid interface to the never-explored size regimes comparable to individual biomolecules. Encouraging research outcomes have also been reported for the stability and activity of biomolecules bound on BCP thin film surfaces. A wide range of single and multicomponent biomolecules and BCP systems has been assessed to substantiate the potential utility in practical applications as next-generation nanobiosensors, nanobiodevices, and biomaterials. To this end, this Review highlights pioneering research efforts made in the BCP nanobiotechnology area. The discussions will be focused on those works particularly pertaining to nanoscale surface assembly of functional biomolecules, biomolecular interaction properties unique to nanoscale polymer interfaces, functionality of nanoscale surface-bound biomolecules, and specific examples in biosensing. Systems involving the incorporation of biomolecules as one of the blocks in BCPs, i.e., DNA–BCP hybrids, protein–BCP conjugates, and isolated BCP micelles of bioligand carriers used in drug delivery, are outside of the scope of this Review. Looking ahead, there awaits plenty of exciting research opportunities to advance the research field of BCP nanobiotechnology by capitalizing on the fundamental groundwork laid so far for the biomolecular interactions on BCP surfaces. In order to better guide the path forward, key fundamental questions yet to be addressed by the field are identified. In addition, future research directions of BCP nanobiotechnology are contemplated in the concluding section of this Review. Full article
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24 pages, 5508 KiB  
Article
The ZmbHLH47-ZmSnRK2.9 Module Promotes Drought Tolerance in Maize
by Zhenwei Yan, Fajun Zhang, Chunhua Mu, Changle Ma, Guoqi Yao, Yue Sun, Jing Hou, Bingying Leng and Xia Liu
Int. J. Mol. Sci. 2024, 25(9), 4957; https://doi.org/10.3390/ijms25094957 (registering DOI) - 01 May 2024
Abstract
Drought stress globally poses a significant threat to maize (Zea mays L.) productivity and the underlying molecular mechanisms of drought tolerance remain elusive. In this study, we characterized ZmbHLH47, a basic helix–loop–helix (bHLH) transcription factor, as a positive regulator of drought tolerance [...] Read more.
Drought stress globally poses a significant threat to maize (Zea mays L.) productivity and the underlying molecular mechanisms of drought tolerance remain elusive. In this study, we characterized ZmbHLH47, a basic helix–loop–helix (bHLH) transcription factor, as a positive regulator of drought tolerance in maize. ZmbHLH47 expression was notably induced by both drought stress and abscisic acid (ABA). Transgenic plants overexpressing ZmbHLH47 displayed elevated drought tolerance and ABA responsiveness, while the zmbhlh47 mutant exhibited increased drought sensitivity and reduced ABA sensitivity. Mechanistically, it was revealed that ZmbHLH47 could directly bind to the promoter of ZmSnRK2.9 gene, a member of the subgroup III SnRK2 kinases, activating its expression. Furthermore, ZmSnRK2.9-overexpressing plants exhibited enhanced ABA sensitivity and drought tolerance, whereas the zmsnrk2.9 mutant displayed a decreased sensitivity to both. Notably, overexpressing ZmbHLH47 in the zmsnrk2.9 mutant closely resembled the zmsnrk2.9 mutant, indicating the importance of the ZmbHLH47-ZmSnRK2.9 module in ABA response and drought tolerance. These findings provided valuable insights and a potential genetic resource for enhancing the environmental adaptability of maize. Full article
(This article belongs to the Special Issue Advance in Plant Abiotic Stress)
15 pages, 480 KiB  
Article
The Influence of Personality Type D and Coping Strategies on Cognitive Functioning in Students
by Alexey N. Sumin, Ingrid Yu. Prokashko and Anna V. Shcheglova
Behav. Sci. 2024, 14(5), 382; https://doi.org/10.3390/bs14050382 (registering DOI) - 01 May 2024
Abstract
Introduction: Academic and emotional challenges faced by medical students can affect their psychological well-being and health. Personal characteristics may also predispose one to the manifestation of distress reactions. Individuals with type D personality have an increased tendency to develop depressive reactions and somatic [...] Read more.
Introduction: Academic and emotional challenges faced by medical students can affect their psychological well-being and health. Personal characteristics may also predispose one to the manifestation of distress reactions. Individuals with type D personality have an increased tendency to develop depressive reactions and somatic diseases, including the presence of cognitive dysfunction. In students, the presence of cognitive dysfunction may additionally adversely affect academic and psycho-emotional problems. The purpose of this study was to examine the influence of type D personality and coping strategies on cognitive functioning in medical students. Methods: A cross-sectional study included 258 medical students (age 19 ± 1.2 years, 79 men). All participants completed psychological questionnaires (DS-14 to identify type D personality, and The Coping Strategy Indication, CSI—to determine coping strategies), as well as extensive neuropsychological testing of cognitive functions. Results: Among the medical students examined, the frequency of identification of type D personality was 44%. In persons with personality type D, according to psychometric testing, a decrease in the level of functional mobility of nervous processes (FMNP) was noted, which was manifested in an increase in the test completion time (p < 0.001) and an increase in the number of errors (p < 0.001) during the FMNP test, and an increase in the test completion time in the attention concentration test. In addition, in type D participants, an increase in the test execution time during the attention test was noted (p = 0.007). Personality type D was an independent risk factor for cognitive decline in students in multiple linear regression analysis, when type D was analyzed as a dichotomous construct. Conclusions: Assessing personal characteristics and identifying personality type D is advisable for medical students, to develop subsequent programs to increase their resistance to academic challenges, improve cognitive function, and also to prepare for future stress loads during professional activities in the field of healthcare. Full article
(This article belongs to the Special Issue Wellbeing and Mental Health among Students)
26 pages, 12288 KiB  
Article
Biopolymeric Blends of Thermoplastic Starch and Polylactide as Sustainable Packaging Materials
by Antun Jozinović, Mario Kovač, Vesna Ocelić Bulatović, Dajana Kučić Grgić, Martina Miloloža, Drago Šubarić and Đurđica Ačkar
Polymers 2024, 16(9), 1268; https://doi.org/10.3390/polym16091268 (registering DOI) - 01 May 2024
Abstract
The improper disposal of plastics is a growing concern due to increasing global environmental problems such as the rise of CO2 emissions, diminishing petroleum sources, and pollution, which necessitates the research and development of biodegradable materials as an alternative to conventional packaging [...] Read more.
The improper disposal of plastics is a growing concern due to increasing global environmental problems such as the rise of CO2 emissions, diminishing petroleum sources, and pollution, which necessitates the research and development of biodegradable materials as an alternative to conventional packaging materials. The purpose of this research was to analyse the properties of biodegradable polymer blends of thermoplastic potato starch (TPS) and polylactide, (PLA) without and with the addition of citric acid (CA) as a potential compatibilizer and plasticizer. The prepared blends were subjected to a comprehensive physicochemical characterization, which included: FTIR-ATR spectroscopy, morphological analysis by scanning electron microscopy (SEM), determination of thermal and mechanical properties by differential scanning calorimetry (DSC), water vapour permeability (WVP), as well as biodegradation testing in soil. The obtained results indicate an improvement in adhesion between the TPS and PLA phases due to the addition of citric acid, better homogeneity of the structure, and greater compatibility of the polymer blends, leading to better thermal, mechanical and barrier properties of the studied biodegradable TPS/PLA polymer blends. After conducting the comprehensive research outlined in this paper, it has been determined that the addition of 5 wt.% of citric acid serves as an effective compatibilizer and plasticizer. This supplementation achieves an optimal equilibrium across thermal, mechanical, morphological, and barrier properties, while also promoting material sustainability through biodegradation. In conclusion, it can be stated that the use of thermoplastic starch in TPS/PLA blends accelerates the biodegradation of PLA as a slowly biodegradable polymer. While the addition of citric acid offers significant advantages for TPS/PLA blends, further research is needed to optimize the formulation and processing parameters to achieve the desired balance between mechanical strength, thermal and barrier properties and biodegradability. Full article
(This article belongs to the Special Issue Sustainable Polymers for Value Added and Functional Packaging)
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17 pages, 3575 KiB  
Article
Scorpion Venom Antimicrobial Peptide Derivative BmKn2-T5 Inhibits Enterovirus 71 in the Early Stages of the Viral Life Cycle In Vitro
by Zhiqiang Xia, Huijuan Wang, Weilie Chen, Aili Wang and Zhijian Cao
Biomolecules 2024, 14(5), 545; https://doi.org/10.3390/biom14050545 (registering DOI) - 01 May 2024
Abstract
Enterovirus 71 (EV71), a typical representative of unenveloped RNA viruses, is the main pathogenic factor responsible for hand, foot, and mouth disease (HFMD) in infants. This disease seriously threatens the health and lives of humans worldwide, especially in the Asia–Pacific region. Numerous animal [...] Read more.
Enterovirus 71 (EV71), a typical representative of unenveloped RNA viruses, is the main pathogenic factor responsible for hand, foot, and mouth disease (HFMD) in infants. This disease seriously threatens the health and lives of humans worldwide, especially in the Asia–Pacific region. Numerous animal antimicrobial peptides have been found with protective functions against viruses, bacteria, fungi, parasites, and other pathogens, but there are few studies on the use of scorpion-derived antimicrobial peptides against unenveloped viruses. Here, we investigated the antiviral activities of scorpion venom antimicrobial peptide BmKn2 and five derivatives, finding that BmKn2 and its derivative BmKn2-T5 exhibit a significant inhibitory effect on EV71. Although both peptides exhibit characteristics typical of amphiphilic α-helices in terms of their secondary structure, BmKn2-T5 displayed lower cellular cytotoxicity than BmKn2. BmKn2-T5 was further found to inhibit EV71 in a dose-dependent manner in vitro. Moreover, time-of-drug-addition experiments showed that BmKn2-T5 mainly restricts EV71, but not its virion or replication, at the early stages of the viral cycle. Interestingly, BmKn2-T5 was also found to suppress the replication of the enveloped viruses DENV, ZIKV, and HSV-1 in the early stages of the viral cycle, which suggests they may share a common early infection step with EV71. Together, the results of our study identified that the scorpion-derived antimicrobial peptide BmKn2-T5 showed valuable antiviral properties against EV71 in vitro, but also against other enveloped viruses, making it a potential new candidate therapeutic molecule. Full article
(This article belongs to the Section Natural and Bio-inspired Molecules)
14 pages, 1736 KiB  
Article
Electrical Ear Canal Stimulation as a Therapeutic Approach for Tinnitus—A Proof of Concept Study
by Jana Vater, Moritz Gröschel, Agnieszka J. Szczepek and Heidi Olze
J. Clin. Med. 2024, 13(9), 2663; https://doi.org/10.3390/jcm13092663 (registering DOI) - 01 May 2024
Abstract
Background: Tinnitus—the perception of sound despite the absence of an external source—can be a debilitating condition for which there are currently no pharmacological remedies. Our proof of concept study focused on the immediate effects of non-invasive electrical stimulation through the ear canal on [...] Read more.
Background: Tinnitus—the perception of sound despite the absence of an external source—can be a debilitating condition for which there are currently no pharmacological remedies. Our proof of concept study focused on the immediate effects of non-invasive electrical stimulation through the ear canal on loudness and tinnitus-induced distress. In addition, we aimed to identify variables that may affect the simulation outcomes. Methods: Sixty-six patients (29 women and 37 men, mean age 54.4 ± 10.4) with chronic tinnitus were recruited to the tertiary referral hospital between December 2019 and December 2021. They underwent 10 min of electrical stimulation through the ear canal for three consecutive days. Visual analog scales measured loudness and tinnitus-induced distress immediately before and after stimulation. Results: After three days of electrical stimulation, tinnitus loudness decreased in 47% of patients, 45.5% reported no change, and 7.6% reported worsening. Tinnitus severity decreased in 36.4% of cases, 59.1% of patients reported no change, and 4.5% reported worsening. Women responded positively to therapy earlier than men. In addition, tinnitus distress decreased in patients with compensated tinnitus but not in those with uncompensated tinnitus. Finally, patients with bilateral tinnitus improved earlier than those with unilateral tinnitus, and the age of the patients did not influence the stimulation results. Conclusions: Our proof of concept study confirms the potential of non-invasive electrical stimulation of the ear as a promising screening approach to identifying patients for more advanced electrostimulation treatment, such as an extracochlear anti-tinnitus implant. These findings have practical implications for tinnitus management, offering hope for improved patient care. Full article
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27 pages, 6902 KiB  
Article
Revealing Daily Mobility Pattern Disparities of Monomodal and Multimodal Travelers through a Multi-Layer Cluster Analysis: Insights from a Combined Big Dataset
by Jingyao Zhao, Fan Zhang, Lei Gao, Chunhai Han and Xiongxiong Chen
Sustainability 2024, 16(9), 3811; https://doi.org/10.3390/su16093811 (registering DOI) - 01 May 2024
Abstract
More detailed and precise mobility patterns are needed for policies to reduce monomodal automotive dependency and promote multimodality in travel behaviors. Yet, empirical evidence from an integrated view of a complete door-to-door trip mode chain with daily mobility for pattern identification is still [...] Read more.
More detailed and precise mobility patterns are needed for policies to reduce monomodal automotive dependency and promote multimodality in travel behaviors. Yet, empirical evidence from an integrated view of a complete door-to-door trip mode chain with daily mobility for pattern identification is still lacking. As an improvement and a solution on this issue, a multi-layer cluster model was designed and proposed for distinguishing 20 mobility pattern clusters, including six monomodal traveler groups, two non-transit multimodal traveler groups, and 12 transit multimodal based on big data mining. Statistical analysis with seven indicator measurements and a spatial distribution analysis with the Kernel density GIS maps of travelers’ residential location were carried out to reveal significant disparities across pattern clusters concerning spatial, social, and trip characteristics, based on which more precise and target policies for each group were discussed. This research may help provide more detailed information in establishing traveler mobility pattern profiles and solutions in filling the planning–implementation gap from the perspective of planners, policymakers, and travelers. Full article
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15 pages, 5760 KiB  
Article
Assessment of Stormwater Harvesting Potential: The Case Study of South Korea
by Amjad Khan, Yoonkyung Park, Jongpyo Park, Inkyeong Sim and Reeho Kim
Sustainability 2024, 16(9), 3812; https://doi.org/10.3390/su16093812 (registering DOI) - 01 May 2024
Abstract
Stormwater harvesting (SWH) is emerging as a vital adaptive strategy for urban climate resilience. In South Korea, different types of storage facilities have been constructed under different regulations and laws. Each type of storage facility has its own original purpose of construction. Although [...] Read more.
Stormwater harvesting (SWH) is emerging as a vital adaptive strategy for urban climate resilience. In South Korea, different types of storage facilities have been constructed under different regulations and laws. Each type of storage facility has its own original purpose of construction. Although these facilities have better outcomes, we aim to investigate the potential use of these facilities as additional water resources. In this study, we assess the stormwater harvesting (SWH) potential of different types of already-constructed storage facilities. Five different types of storage facilities and three different cases are considered in the present study. Case 1 excludes SWH volume during the flood and winter seasons, while in Case 2, only winter season SWH volume is excluded. In Case 3, the winter season and combined sewer overflows (CSOs) facilities are excluded. The Rainwater Utilization Facility is considered as a baseline for comparison in the present study. The results show that, in Case 2, the Sewage Storage Facility, Stormwater Runoff Reduction Facility, Nonpoint Pollution Reduction Facility, and Buffer Storage Facility has 53.5, 4, 2.4, and 1.2 times more stormwater average annual usage potential, respectively. The findings suggest that these facilities can be utilized as additional water resources. It should be mentioned that the primary objective for which each facility was constructed will remain unaffected. Nevertheless, forthcoming research should focus on a detailed exploration of the quality of the collected stormwater and the energy required to supply the stormwater for the end usage. Full article
(This article belongs to the Section Sustainable Water Management)
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14 pages, 1659 KiB  
Article
Fabrication of Human Milk Fat Substitute: Based on the Similarity Evaluation Model and Computer Software
by Huiquan Zhu, Pu Zhao, Xiaodan Wang, Yunna Wang, Shuwen Zhang, Xiaoyang Pang and Jiaping Lv
Molecules 2024, 29(9), 2096; https://doi.org/10.3390/molecules29092096 (registering DOI) - 01 May 2024
Abstract
We aimed to obtain the optimal formula for human milk fat substitute (HMFS) through a combination of software and an evaluation model and further verify its practicability through an animal experiment. The results showed that a total of 33 fatty acid (FA) and [...] Read more.
We aimed to obtain the optimal formula for human milk fat substitute (HMFS) through a combination of software and an evaluation model and further verify its practicability through an animal experiment. The results showed that a total of 33 fatty acid (FA) and 63 triglyceride (TAG) molecular species were detected in vegetable oils. Palmitic acid, oleic acid, linoleic acid, 18:1/16:0/18:1, 18:2/16:0/18:2, 18:1/18:1/18:1 and 18:1/18:2/18:1, were the main molecular species among the FAs and TAGs in the vegetable oils. Based on the HMFS evaluation model, the optimal mixed vegetable oil formula was blended with 21.3% palm oil, 2.8% linseed oil, 2.6% soybean oil, 29.9% rapeseed oil and 43.4% maize oil, with the highest score of 83.146. Moreover, there was no difference in the weight, blood routine indices or calcium and magnesium concentrations in the feces of the mice between the homemade mixed vegetable oil (HMVO) group and the commercial mixed vegetable oil (CMVO) group, while nervonic acid (C24:1) and octanoic acid (C8:0) were absorbed easily in the HMVO group. Therefore, these results demonstrate that the mixing of the different vegetable oils was feasible via a combination of computer software and an evaluation model and provided a new way to produce HMFS. Full article
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20 pages, 775 KiB  
Article
Quantitative Accident Risk Estimation for Infrastructure Facilities Based on Accident Case Analysis
by Jeongung Lee and Jaewook Jeong
Buildings 2024, 14(5), 1283; https://doi.org/10.3390/buildings14051283 (registering DOI) - 01 May 2024
Abstract
The construction industry records higher accident rates than other industries, and thus, risk estimation is necessary to manage accident rates. Risk levels differ based on facility type and construction project size. In this sense, this study aims to calculate the quantitative accident risk [...] Read more.
The construction industry records higher accident rates than other industries, and thus, risk estimation is necessary to manage accident rates. Risk levels differ based on facility type and construction project size. In this sense, this study aims to calculate the quantitative accident risk level according to the construction project size per infrastructure facility type. To this end, the following five-step risk estimation was performed: (1) data collection and classification; (2) calculation of fatality rate based on construction cost; (3) calculation of fatal construction probability by construction cost classification; (4) reclassification of construction cost considering fatal construction probability; and (5) calculation of risk level by facility type and construction cost classification. As a result, the fatality rate per facility type was the highest in ‘Dam’ at 0.01024 (person/USD million). Additionally, the risk level according to the construction project size per facility type was the highest for ‘Dam’ (0.00403 person/USD million) for a construction of less than USD 0.77 million. The risk level presented in this study can be utilized as basic data in the design stage for safety management. Our results also indicate the necessity of preparing a separate construction cost classification for safety management. Full article
11 pages, 1191 KiB  
Article
Temperature-Decoupled Single-Crystal MgO Fiber-Optic Fabry–Perot Vibration Sensor Based on MEMS Technology for Harsh Environments
by Chengxin Su, Pinggang Jia, Aihao Zhao, Jiacheng Tu, Jia Liu, Qianyu Ren and Jijun Xiong
Micromachines 2024, 15(5), 616; https://doi.org/10.3390/mi15050616 (registering DOI) - 01 May 2024
Abstract
A high-temperature-resistance single-crystal magnesium oxide (MgO) extrinsic Fabry–Perot (FP) interferometer (EFPI) fiber-optic vibration sensor is proposed and experimentally demonstrated at 1000 °C. Due to the excellent thermal properties (melting point > 2800 °C) and optical properties (transmittance ≥ 90%), MgO is chosen as [...] Read more.
A high-temperature-resistance single-crystal magnesium oxide (MgO) extrinsic Fabry–Perot (FP) interferometer (EFPI) fiber-optic vibration sensor is proposed and experimentally demonstrated at 1000 °C. Due to the excellent thermal properties (melting point > 2800 °C) and optical properties (transmittance ≥ 90%), MgO is chosen as the ideal material to be placed in the high-temperature testing area. The combination of wet chemical etching and direct bonding is used to construct an all-MgO sensor head, which is favorable to reduce the temperature gradient inside the sensor structure and avoid sensor failure. A temperature decoupling method is proposed to eliminate the cross-sensitivity between temperature and vibration, improving the accuracy of vibration detection. The experimental results show that the sensor is stable at 20−1000 °C and 2−20 g, with a sensitivity of 0.0073 rad (20 °C). The maximum nonlinearity error of the vibration sensor measurement after temperature decoupling is 1.17%. The sensor with a high temperature resistance and outstanding dynamic performance has the potential for applications in testing aero-engines and gas turbine engines. Full article
(This article belongs to the Special Issue Micro/Nano Sensors: Fabrication and Applications)
12 pages, 2758 KiB  
Article
Enhancing Moisture-Induced Defect Detection in Insulated Steel Pipes through Infrared Thermography and Hybrid Dataset
by Reza Khoshkbary Rezayiye, Clemente Ibarra-Castanedo and Xavier Maldague
Electronics 2024, 13(9), 1748; https://doi.org/10.3390/electronics13091748 (registering DOI) - 01 May 2024
Abstract
It is crucial to accurately detect moisture-induced defects in steel pipe insulation in order to combat corrosion under insulation (CUI). This study enhances the capabilities of infrared thermography (IRT) by integrating it with top-performing machine learning models renowned for their effectiveness in image [...] Read more.
It is crucial to accurately detect moisture-induced defects in steel pipe insulation in order to combat corrosion under insulation (CUI). This study enhances the capabilities of infrared thermography (IRT) by integrating it with top-performing machine learning models renowned for their effectiveness in image segmentation tasks. A novel methodology was developed to enrich machine learning training, incorporating synthetic datasets generated via finite element method (FEM) simulations with experimental data. The performance of four advanced models—UNet, UNet++, DeepLabV3+, and FPN—was evaluated. These models demonstrated significant enhancements in defect detection capabilities, with notable improvements observed in FPN, which exhibited a mean intersection over union (IoU) increase from 0.78 to 0.94, a reduction in loss from 0.19 to 0.06, and an F1 score increase from 0.92 to 0.96 when trained on hybrid datasets compared to those trained solely on real data. The results highlight the benefits of integrating synthetic and experimental data, effectively overcoming the challenges of limited dataset sizes, and significantly improving the models’ accuracy and generalization capabilities in identifying defects. This approach marks a significant advancement in industrial maintenance and inspection, offering a precise, reliable, and scalable solution to managing the risks associated with CUI. Full article
(This article belongs to the Special Issue Adversarial Machine Learning: Attacks, Defenses and Security)
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