The 2023 MDPI Annual Report has
been released!
 
11 pages, 2334 KiB  
Article
Enhanced Efficiency and Stability of Sky Blue Perovskite Light-Emitting Diodes via Introducing Lead Acetate
by Zequan Zhang, Qiaoli Niu, Baoxiang Chai, Junhao Xiong, Yuqing Chen, Wenjin Zeng, Xinwen Peng, Emmanuel Iheanyichukwu Iwuoha and Ruidong Xia
Molecules 2024, 29(11), 2425; https://doi.org/10.3390/molecules29112425 (registering DOI) - 21 May 2024
Abstract
All-inorganic metal halide perovskite is promising for highly efficient and thermally stable perovskite light-emitting diodes (PeLEDs). However, there is still great room for improvement in the film quality, including low coverage and high trap density, which play a vital role in achieving high-efficiency [...] Read more.
All-inorganic metal halide perovskite is promising for highly efficient and thermally stable perovskite light-emitting diodes (PeLEDs). However, there is still great room for improvement in the film quality, including low coverage and high trap density, which play a vital role in achieving high-efficiency PeLEDs. In this work, lead acetate (Pb(Ac)2) was introduced into the perovskite precursor solution as an additive. Experimental results show that perovskite films deposited from a one-step anti-solvent free solution process with increased surface coverage and reduced trap density were obtained, leading to enhanced photoluminescence (PL) intensity. More than that, the valence band maximum (VBM) of perovskite films was reduced, bringing about a better energy level matching the work function of the hole-injection layer (HIL) poly (3,4-ethylenedioxythiophene)-poly (styrene sulfonate) (PEDOT: PSS), which is facilitated for the hole injection, leading to a decrease in the turn-on voltage (Vth) of PeLEDs from 3.4 V for the control device to 2.6 V. Finally, the external quantum efficiency (EQE) of the sky blue PeLEDs (at 484 nm) increased from 0.09% to 0.66%. The principles of Pb(Ac)2 were thoroughly investigated by using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). This work provides a simple and effective strategy for improving the morphology of perovskite and therefore the performance of PeLEDs. Full article
(This article belongs to the Special Issue Molecular Semiconductors for Organic and Perovskite Solar Cells)
18 pages, 5390 KiB  
Article
Deformation Risk Assessment of the Lar Dam: Monitoring Its Stability Condition
by Mehrnoosh Ghadimi and Mohammadali Kiani
Sustainability 2024, 16(11), 4335; https://doi.org/10.3390/su16114335 (registering DOI) - 21 May 2024
Abstract
Dam stability is one of the most essential geotechnical engineering challenges. Studying the structural behavior of dams during their useful life is an essential component of their safety. Terrestrial surveying network approaches are typically expensive and time-consuming. Over the last decade, the interferometric [...] Read more.
Dam stability is one of the most essential geotechnical engineering challenges. Studying the structural behavior of dams during their useful life is an essential component of their safety. Terrestrial surveying network approaches are typically expensive and time-consuming. Over the last decade, the interferometric synthetic aperture radar (InSAR) method has been widely used to monitor millimeter displacements in dam crests. This research investigates the structural monitoring of the Lar Dam in Iran, using InSAR and the terrestrial surveying network technique to identify the possible failure risk of the dam. Sentinel-1A images taken from 5 February 2015 to 30 September 2019 and TerraSAR-X (09.05.2018 to 16.08.2018) images were analyzed to investigate the dam’s behavior. The InSAR results were compared with those of the terrestrial surveying network for the period of 1992 to 2019. The Sentinel-1 results implied that the dam on the left side moved over 8 mm/yr. However, the pillars to the left abutment indicated an uplift, which is consistent with the TerraSAR-X results. Also, the TerraSAR-X data indicated an 8 mm displacement over a three-month period. The terrestrial surveying showed that the largest uplift was 19.68 mm at the TB4 point on the left side and upstream of the body, while this amount was 10 mm in the interferometry analysis for the period of 2015–2020. The subsidence rate increased from the middle part toward the left abutment. The geological observations made during the ninth stage of the terrestrial surveying network indicate that there was horizontal and vertical movement over time, from 1992 to 2019. However, the results of the InSAR processing in the crown were similar to those of the terrestrial surveying network. Although different comparisons were used for the measurements, the difference in the displacement rates was reasonable, but all three methods showed the same trend in terms of uplift and displacement. Full article
(This article belongs to the Section Hazards and Sustainability)
20 pages, 4971 KiB  
Article
Delineating Priority Areas for Preservation and Restoration across Production–Living–Ecological Spaces in Ganzi, China
by Shengbin Chen, Xingwei Deng, Lilei Wu, Kunming Zhao, Zengjing Huang, Qi Chen and Xuan Zhang
Sustainability 2024, 16(11), 4327; https://doi.org/10.3390/su16114327 (registering DOI) - 21 May 2024
Abstract
Delineating conservation priority areas for both preservation and restoration is essential for developing adaptive ecosystem management strategies across production–living–ecological spaces (PLES). This study developed a coherent framework with four steps: (1) mapping spatial distributions of biodiversity and ecosystem services, (2) ranking the relative [...] Read more.
Delineating conservation priority areas for both preservation and restoration is essential for developing adaptive ecosystem management strategies across production–living–ecological spaces (PLES). This study developed a coherent framework with four steps: (1) mapping spatial distributions of biodiversity and ecosystem services, (2) ranking the relative importance of ecosystems across spaces, (3) delineating priority areas for preservation and restoration according to the human footprint and priority ranks, and (4) contrasting with current conservation networks and overlapping with PLES. This framework was applied in Ganzi, China, to delineate the preservation priority areas (PPAs) of 8714.2 km2 and 11,308.1 km2, and restoration priority areas (RPAs) of 36,817.7 km2 and 63,578.4 km2 under the target to conserve 30% and 50% of territories, respectively. The priority areas, including PPAs and RPAs, achieve higher conservation capacity than the current Ecological Conservation Redline (ECR) in terms of biodiversity conservation or ecosystem service delivery. Roughly 67% of PPAs, 40% of RPAs, and a total of 75% of large patches with high priority are covered by ECR, indicating the necessity to adjust boundary and conduct restoration for ECR. As for PLES, the conservation priority areas encompass proportionally more ecological space (67–76%) than ECR (63.5%) or Ganzi (61.4%), implying the lower potential conflict between local residents’ production and conservation, and meanwhile, new opportunities and challenges in sustainable development in human-dominated spaces. The coherent framework to delineate PPAs and RPAs is flexible in terms of threshold in human impact or ecological degradation and can be improved by considering the complex relationships between indicators of biodiversity and ecosystem services. This study highlights the importance of incorporating ecosystem features, land uses, and human activities in developing different strategies according to different conservation purposes in the context of sustainable development. Full article
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15 pages, 452 KiB  
Article
Uniformly Shifted Exponential Distribution
by Abdulhamid. A. Alzaid and Najla Qarmalah
Axioms 2024, 13(6), 339; https://doi.org/10.3390/axioms13060339 (registering DOI) - 21 May 2024
Abstract
The use of life distributions has increased over the past decade, receiving particular attention in recent years, both from a practical and theoretical point of view. Life distributions can be used in a number of applied fields, such as medicine, biology, public health, [...] Read more.
The use of life distributions has increased over the past decade, receiving particular attention in recent years, both from a practical and theoretical point of view. Life distributions can be used in a number of applied fields, such as medicine, biology, public health, epidemiology, engineering, economics, and demography. This paper presents and investigates a new life distribution. The proposed model shows favorable characteristics in terms of reliability theory, which makes it competitive against other commonly used life distributions, such as the exponential, gamma, and Weibull distributions. The methods of maximum likelihood and moments are used to estimate the parameters of the proposed model. Additionally, real-life data drawn from different fields are used to illustrate the usefulness of the new distribution. Further, the R programming language is used to perform all computations and produce all graphs. Full article
13 pages, 3434 KiB  
Article
Stable Structure and Fast Ion Diffusion: A Flexible MoO2@Carbon Hollow Nanofiber Film as a Binder-Free Anode for Sodium-Ion Batteries with Superior Kinetics and Excellent Rate Capability
by Na Feng, Mingzhen Gao, Junyu Zhong, Chuantao Gu, Yuanming Zhang and Bing Liu
Polymers 2024, 16(11), 1452; https://doi.org/10.3390/polym16111452 (registering DOI) - 21 May 2024
Abstract
Designing innovative anode materials that exhibit excellent ion diffusion kinetics, enhanced structural stability, and superior electrical conductivity is imperative for advancing the rapid charge–discharge performance and widespread application of sodium-ion batteries. Hollow-structured materials have received significant attention in electrode design due to their [...] Read more.
Designing innovative anode materials that exhibit excellent ion diffusion kinetics, enhanced structural stability, and superior electrical conductivity is imperative for advancing the rapid charge–discharge performance and widespread application of sodium-ion batteries. Hollow-structured materials have received significant attention in electrode design due to their rapid ion diffusion kinetics. Building upon this, we present a high-performance, free-standing MoO2@hollow carbon nanofiber (MoO2@HCNF) electrode, fabricated through facile coaxial electrospinning and subsequent heat treatment. In comparison to MoO2@carbon nanofibers (MoO2@CNFs), the MoO2@HCNF electrode demonstrates superior rate capability, attributed to its larger specific surface area, its higher pseudocapacitance contribution, and the enhanced diffusion kinetics of sodium ions. The discharge capacities of the MoO2@HCNF (MoO2@CNF) electrode at current densities of 0.1, 0.2, 0.5, 1.0, 2.0 and 5.0 A g−1 are 195.55 (155.49), 180.98 (135.20), 163.81 (109.71), 144.05 (90.46), 121.16 (71.21) and 88.90 (44.68) mAh g−1, respectively. Additionally, the diffusion coefficients of sodium ions in the MoO2@HCNFs are 8.74 × 10−12 to 1.37 × 10−12 cm2 s−1, which surpass those of the MoO2@CNFs (6.49 × 10−12 to 9.30 × 10−13 cm2 s−1) during the discharging process. In addition, these prepared electrode materials exhibit outstanding flexibility, which is crucial to the power storage industry and smart wearable devices. Full article
(This article belongs to the Section Smart and Functional Polymers)
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21 pages, 1930 KiB  
Article
Distributed Drive Autonomous Vehicle Trajectory Tracking Control Based on Multi-Agent Deep Reinforcement Learning
by Yalei Liu, Weiping Ding, Mingliang Yang, Honglin Zhu, Liyuan Liu and Tianshi Jin
Mathematics 2024, 12(11), 1614; https://doi.org/10.3390/math12111614 (registering DOI) - 21 May 2024
Abstract
In order to enhance the trajectory tracking accuracy of distributed-driven intelligent vehicles, this paper formulates the tasks of torque output control for longitudinal dynamics and steering angle output control for lateral dynamics as Markov decision processes. To dissect the requirements of action output [...] Read more.
In order to enhance the trajectory tracking accuracy of distributed-driven intelligent vehicles, this paper formulates the tasks of torque output control for longitudinal dynamics and steering angle output control for lateral dynamics as Markov decision processes. To dissect the requirements of action output continuity for longitudinal and lateral control, this paper adopts the deep deterministic policy gradient algorithm (DDPG) for longitudinal velocity control and the deep Q-network algorithm (DQN) for lateral motion control. Multi-agent reinforcement learning methods are applied to the task of trajectory tracking in distributed-driven vehicle autonomous driving. By contrasting with two classical trajectory tracking control methods, the proposed approach in this paper is validated to exhibit superior trajectory tracking performance, ensuring that both longitudinal velocity deviation and lateral position deviation of the vehicle remain at lower levels. Compared with classical control methods, the maximum lateral position deviation is improved by up to 90.5% and the maximum longitudinal velocity deviation is improved by up to 97%. Furthermore, it demonstrates excellent generalization and high computational efficiency, and the running time can be reduced by up to 93.7%. Full article
26 pages, 2373 KiB  
Article
Advancements in Battery Management Systems for Electric Vehicles: A MATLAB-Based Simulation of 4S3P Lithium-Ion Battery Packs
by Rakesh P. Tapaskar, Prashant P. Revankar and Sharanabasava V. Ganachari
World Electr. Veh. J. 2024, 15(6), 222; https://doi.org/10.3390/wevj15060222 (registering DOI) - 21 May 2024
Abstract
As electric vehicles (EVs) gain momentum in the shift towards sustainable transportation, the efficiency and reliability of energy storage systems become paramount. Lithium-ion batteries stand at the forefront of this transition, necessitating sophisticated battery management systems (BMS) to enhance their performance and lifespan. [...] Read more.
As electric vehicles (EVs) gain momentum in the shift towards sustainable transportation, the efficiency and reliability of energy storage systems become paramount. Lithium-ion batteries stand at the forefront of this transition, necessitating sophisticated battery management systems (BMS) to enhance their performance and lifespan. This research presents an innovative simulation of a 4S3P lithium-ion battery pack using MATLAB R2023b, designed to refine BMS capabilities by employing advanced mathematical modelling and computational intelligence. The simulation meticulously analyses critical operational metrics such as state of charge (SOC), state of health (SOH), temperature variations, and electrical behaviour under diverse load scenarios, offering deep insights into the intricate dynamics of lithium-ion batteries in EV applications. The results corroborate the simulation model’s accuracy in reflecting actual battery pack performance and underscore significant improvements in BMS strategies, especially concerning predictive maintenance and adaptive charging techniques. By seamlessly integrating computational intelligence into BMS, this study lays the groundwork for more durable, efficient, and intelligent energy storage systems in electric vehicles, marking a significant stride in e-mobility technology. Full article
(This article belongs to the Special Issue Lithium-Ion Batteries for Electric Vehicle)
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12 pages, 693 KiB  
Article
Effect of Methylfolate, Pyridoxal-5′-Phosphate, and Methylcobalamin (SolowaysTM) Supplementation on Homocysteine and Low-Density Lipoprotein Cholesterol Levels in Patients with Methylenetetrahydrofolate Reductase, Methionine Synthase, and Methionine Synthase Reductase Polymorphisms: A Randomized Controlled Trial
by Evgeny Pokushalov, Andrey Ponomarenko, Sevda Bayramova, Claire Garcia, Inessa Pak, Evgenya Shrainer, Marina Ermolaeva, Dmitry Kudlay, Michael Johnson and Richard Miller
Nutrients 2024, 16(11), 1550; https://doi.org/10.3390/nu16111550 (registering DOI) - 21 May 2024
Abstract
Exploring the link between genetic polymorphisms in folate metabolism genes (MTHFR, MTR, and MTRR) and cardiovascular disease (CVD), this study evaluates the effect of B vitamin supplements (methylfolate, pyridoxal-5′-phosphate, and methylcobalamin) on homocysteine and lipid levels, potentially guiding personalized CVD risk management. In [...] Read more.
Exploring the link between genetic polymorphisms in folate metabolism genes (MTHFR, MTR, and MTRR) and cardiovascular disease (CVD), this study evaluates the effect of B vitamin supplements (methylfolate, pyridoxal-5′-phosphate, and methylcobalamin) on homocysteine and lipid levels, potentially guiding personalized CVD risk management. In a randomized, double-blind, placebo-controlled trial, 54 patients aged 40–75 with elevated homocysteine and moderate LDL-C levels were divided based on MTHFR, MTR, and MTRR genetic polymorphisms. Over six months, they received either a combination of methylfolate, P5P, and methylcobalamin, or a placebo. At the 6 months follow-up, the treatment group demonstrated a significant reduction in homocysteine levels by 30.0% (95% CI: −39.7% to −20.3%) and LDL-C by 7.5% (95% CI: −10.3% to −4.7%), compared to the placebo (p < 0.01 for all). In the subgroup analysis, Homozygous Minor Allele Carriers showed a more significant reduction in homocysteine levels (48.3%, 95% CI: −62.3% to −34.3%, p < 0.01) compared to mixed allele carriers (18.6%, 95% CI: −25.6% to −11.6%, p < 0.01), with a notable intergroup difference (29.7%, 95% CI: −50.7% to −8.7%, p < 0.01). LDL-C levels decreased by 11.8% in homozygous carriers (95% CI: −15.8% to −7.8%, p < 0.01) and 4.8% in mixed allele carriers (95% CI: −6.8% to −2.8%, p < 0.01), with a significant between-group difference (7.0%, 95% CI: −13.0% to −1.0%, p < 0.01). Methylfolate, P5P, and methylcobalamin supplementation tailored to genetic profiles effectively reduced homocysteine and LDL-C levels in patients with specific MTHFR, MTR, and MTRR polymorphisms, particularly with homozygous minor allele polymorphisms. Full article
(This article belongs to the Section Proteins and Amino Acids)
21 pages, 1723 KiB  
Article
The Residue Chemistry Transformation Linked to the Fungi Keystone Taxa during Different Residue Tissues Incorporation into Mollisols in Northeast China
by Qilin Zhang, Xiujun Li, Guoshuang Chen, Nana Luo, Jing Sun, Ezemaduka Anastasia Ngozi and Xinrui Lu
Agriculture 2024, 14(6), 792; https://doi.org/10.3390/agriculture14060792 (registering DOI) - 21 May 2024
Abstract
Managing carbon input from crop straw in cropland ecosystems could increase soil organic carbon (SOC) sequestration to achieve C neutrality and mitigate climate change. The complexity of the chemical structures of crop residue largely affects SOC sequestration. Fungi communities play an important role [...] Read more.
Managing carbon input from crop straw in cropland ecosystems could increase soil organic carbon (SOC) sequestration to achieve C neutrality and mitigate climate change. The complexity of the chemical structures of crop residue largely affects SOC sequestration. Fungi communities play an important role in the degradation of crop residues. However, the relationship between the fungal community composition and the chemical structures of crop residues remains unclear and requires further investigation. Therefore, a 120-day incubation experiment was conducted in Mollisols in Northeast China to investigate the decomposition processes and dynamics of maize straw stem (ST), leaf (LE) and sheath (SH) residues using 13C-NMR spectroscopy. Additionally, the microbiomes associated with these residues were analyzed through high-throughput sequencing to explore their relationship. Our results showed that the alkyl C contents in all treatments exhibited increases ranging from 15.1% to 49.1%, while the O-alkyl C contents decreased, ranging from 0.02% to 11.2%, with the incubation time. The A/OA ratios of ST, LE and SH treatments were increased by 23.7%, 43.4% and 49.3% with incubation time, respectively. During the early stages of straw decomposition, Ascomycota dominated, and in the later stage, Basidiomycota were predominant. The class of Sordariomycetes played a key role in the chemistry transformation of straw tissues during decomposition. The keystone taxa abundances, Fusarium_kyushuense, and Striatibotrys_eucylindrospora, showed strong negative correlations with di-O-alkyl C and carbonyl-C content and positive correlations with the β-glucosidase and peroxidase enzyme activity, respectively. In conclusion, our study demonstrated that the keystone taxa play a significant role in regulating the chemical structures of straw tissues, providing a better understanding of the influence of residue quality on SOC sequestration. Full article
13 pages, 667 KiB  
Article
Traffic Sign Recognition Using Multi-Task Deep Learning for Self-Driving Vehicles
by Khaldaa Alawaji, Ramdane Hedjar and Mansour Zuair
Sensors 2024, 24(11), 3282; https://doi.org/10.3390/s24113282 (registering DOI) - 21 May 2024
Abstract
Over the coming years, the advancement of driverless transport systems for people and goods that are designed to be used on fixed routes will revolutionize the transportation system. Therefore, for a safe transportation system, detecting and recognizing traffic signals based on computer [...] Read more.
Over the coming years, the advancement of driverless transport systems for people and goods that are designed to be used on fixed routes will revolutionize the transportation system. Therefore, for a safe transportation system, detecting and recognizing traffic signals based on computer vision has become increasingly important. Deep learning approaches, particularly convolutional neural networks, have shown exceptional performance in various computer vision applications. The goal of this research is to precisely detect and recognize traffic signs that are present on the streets using computer vision and deep learning techniques. Previous work has focused on symbol-based traffic signals, where popular single-task learning models have been trained and tested. Therefore, several comparisons have been conducted to select accurate single-task learning models. For further improvement, these models are employed in a multi-task learning approach. Indeed, multi-task learning algorithms are built by sharing the convolutional layer parameters between the different tasks. Hence, for the multi-task learning approach, different experiments have been carried out using pre-trained architectures like, for instance, InceptionResNetV2 and DenseNet201. A range of traffic signs and traffic lights are employed to validate the designed model. An accuracy of 99.07% is achieved when the entire network has been trained. To further enhance the accuracy of the model for traffic signs obtained from the street, a region of interest module is added to the multi-task learning module to accurately extract the traffic signs available in the image. To check the effectiveness of the adopted methodology, the designed model has been successfully tested in real-time on a few Riyadh highways. Full article
(This article belongs to the Special Issue Advances in Intelligent Transportation Systems Based on Sensor Fusion)
11 pages, 615 KiB  
Article
Corneal Biomechanics and Other Factors Associated with Postoperative Astigmatism after Cataract Surgery
by Kata Čulina, Martina Tomić, Tomislav Bulum, Aleksej Medić, Ivan Šoša, Kristina Ivanišević and Tomislav Jukić
Life 2024, 14(6), 655; https://doi.org/10.3390/life14060655 (registering DOI) - 21 May 2024
Abstract
This study aimed to investigate the impact of the cornea’s biomechanical properties, corneal hysteresis (CH), and corneal resistance factor (CRF) on postoperative astigmatism after cataract surgery and determine the other factors that influence it. Forty eyes of 40 patients (13M/27F; the median age [...] Read more.
This study aimed to investigate the impact of the cornea’s biomechanical properties, corneal hysteresis (CH), and corneal resistance factor (CRF) on postoperative astigmatism after cataract surgery and determine the other factors that influence it. Forty eyes of 40 patients (13M/27F; the median age of 74) were included in this prospective study, underwent 2.75 mm incision cataract surgery, and were followed for 30 days. Visits were scheduled at baseline before surgery (V0), the 1st (V1), the 7th (V2), and the 30th (V3) postoperative days. The main parameters estimated and analyzed with Statistica® 14.0.1 were CH, CRF, astigmatism diopter, and axis. Following the cataract surgery, the CH did not significantly change during the study visits (p = 0.109). However, there was a significant change in the CRF from baseline during the study visits (per protocol set) (p = 0.002). After a slight but insignificant increase from V0 to V1, post hoc analysis found a significant decrease in the mean CRF from V1 to V2 (p = 0.049) with no substantial change from V2 to V3. According to the post hoc analysis, the median astigmatism diopter increased significantly only from V0 to V1 (p = 0.001) and slightly but not significantly decreased to the end of the study with the achievement of a near-baseline value. The main predictors for the final astigmatism diopter (R2 = 0.898) obtained by stepwise regression analysis were its values at V0, V1, and V2 (p < 0.001). The CRF at V1 was marginally significant, with a negative parameter estimate of −0.098303 (p = 0.0623). In conclusion, there was no correlation between preoperative CH and CRF and postoperative astigmatism using 2.75 mm incision cataract surgery. However, the final astigmatism diopter’s main predictors were its baseline values before cataract surgery, the first, and the seventh postoperative days. Full article
(This article belongs to the Special Issue Eye Diseases: Diagnosis and Treatment, 2nd Edition)
19 pages, 1323 KiB  
Article
Recovery of Ellagic Acid from Pomegranate Peels with the Aid of Ultrasound-Assisted Alkaline Hydrolysis
by Anastasia Kyriakoudi, Evmorfia Kalfa, Eleni Zymvrakaki, Natasa Kalogiouri and Ioannis Mourtzinos
Molecules 2024, 29(11), 2424; https://doi.org/10.3390/molecules29112424 (registering DOI) - 21 May 2024
Abstract
The pomegranate processing industry generates worldwide enormous amounts of by-products, such as pomegranate peels (PPs), which constitute a rich source of phenolic compounds. In this view, PPs could be exploited as a sustainable source of ellagic acid, which is a compound that possesses [...] Read more.
The pomegranate processing industry generates worldwide enormous amounts of by-products, such as pomegranate peels (PPs), which constitute a rich source of phenolic compounds. In this view, PPs could be exploited as a sustainable source of ellagic acid, which is a compound that possesses various biological actions. The present study aimed at the liberation of ellagic acid from its bound forms via ultrasound-assisted alkaline hydrolysis, which was optimized using response surface methodology. The effects of duration of sonication, solvent:solid ratio, and NaOH concentration on total phenol content (TPC), antioxidant activity, and punicalagin and ellagic acid content were investigated. Using the optimum hydrolysis conditions (i.e., 32 min, 1:48 v/w, 1.5 mol/L NaOH), the experimental responses were found to be TCP: 4230 ± 190 mg GAE/100 g dry PPs; AABTS: 32,398 ± 1817 µmol Trolox/100 g dry PPs; ACUPRAC: 29,816 ± 1955 µmol Trolox/100 g dry PPs; 59 ± 3 mg punicalagin/100 g dry PPs; and 1457 ± 71 mg ellagic acid/100 g dry PPs. LC-QTOF-MS and GC-MS analysis of the obtained PP extract revealed the presence of various phenolic compounds (e.g., ellagic acid), organic acids (e.g., citric acid), sugars (e.g., fructose) and amino acids (e.g., glycine). The proposed methodology could be of use for food, pharmaceutical, and cosmetics applications, thus reinforcing local economies. Full article
9 pages, 377 KiB  
Article
The Stigma and Infertility-Related Stress of Chinese Infertile Women: A Cross-Sectional Study
by Dan Luo, Yi-Bei Zhouchen, Lu Li, Yu-Lei Jiang, Yi Liu, Sharon R. Redding, Rong Wang and Yan-Qiong Ouyang
Healthcare 2024, 12(11), 1053; https://doi.org/10.3390/healthcare12111053 (registering DOI) - 21 May 2024
Abstract
Objectives: This study was conducted to investigate the stigma status of infertile women in China and to determine the influencing factors. Methods: 366 infertile women from the gynecological and reproductive departments of two tertiary hospitals completed socio-demographic questionnaires, the Infertility Stigma Scale (ISS) [...] Read more.
Objectives: This study was conducted to investigate the stigma status of infertile women in China and to determine the influencing factors. Methods: 366 infertile women from the gynecological and reproductive departments of two tertiary hospitals completed socio-demographic questionnaires, the Infertility Stigma Scale (ISS) and the Mandarin Fertility Problem Inventory (M-FPI). Results: The scores of stigma and infertility-related stress in infertile women were (52.51 ± 17.74) and (150.03 ± 17.51), respectively. Multiple regression analysis found that location of residence, regarding children as the most important thing in life, talking to others about infertility and infertility-related stress were the main influencing factors of stigma in infertile women, which explained 17.3% of the total variance. Conclusions: In the current study, the level of stigma in women with infertility was at the middle range. Location of residence, regarding children as the most important thing in life, whether to talk with others about infertility and infertility-related stress were the four main influencing factors of stigma. Full article
(This article belongs to the Section Women's Health Care)
17 pages, 4586 KiB  
Article
Material Removal and Surface Modification of Copper under Ultrasonic-Assisted Electrochemical Polishing
by Xinqian Zhang, Jinhu Wang, Jiaqi Chen, Binghai Lyu and Julong Yuan
Processes 2024, 12(6), 1046; https://doi.org/10.3390/pr12061046 (registering DOI) - 21 May 2024
Abstract
Electrochemical polishing exhibits high efficiency and simplicity of operation and presents broad prospects in metal field processing. However, the poor conductivity of the surface oxides generated during electrochemical polishing may lead to uneven electrolysis and surface protrusions if not promptly removed. This study [...] Read more.
Electrochemical polishing exhibits high efficiency and simplicity of operation and presents broad prospects in metal field processing. However, the poor conductivity of the surface oxides generated during electrochemical polishing may lead to uneven electrolysis and surface protrusions if not promptly removed. This study combined ultrasonic treatment with electrochemical polishing and adjusted the angle of the ultrasonic jet to investigate the effect of ultrasonic-assisted electrochemical polishing on the removal of protruding microstructures. The study examined the surface morphology, hardness, residual stress, and workpiece contact angle before and after processing. The results demonstrated that ultrasonic assistance can effectively promote electrochemical reactions and improve the removal efficiency of the workpiece surface. With an increase in ultrasonic power and processing time, the corrosion potential of the workpiece decreased, which accelerated the material removal rate. The roughness of the workpiece surface increased within the threshold. Additionally, the surface hardness increased to 105.3 HV, the residual stress was enhanced by 517.89 MPa, and the contact angle increased to 104.7°. The erosion characteristics and hydrophobicity of the workpiece were also enhanced. Full article
(This article belongs to the Section Materials Processes)
19 pages, 3423 KiB  
Article
Microstructural Assessment of Pozzolanic Activity of Ilmenite Mud Waste Compared to Fly Ash in Cement Composites
by Filip Chyliński
Materials 2024, 17(11), 2483; https://doi.org/10.3390/ma17112483 (registering DOI) - 21 May 2024
Abstract
This paper presents the influence of adding rinsed ilmenite mud waste (R-MUD) on the microstructure of Portland cement composites, compared to similar composites containing fly ash (FA). The aim of the study is the assessment of the pozzolanic activity of ilmenite mud waste [...] Read more.
This paper presents the influence of adding rinsed ilmenite mud waste (R-MUD) on the microstructure of Portland cement composites, compared to similar composites containing fly ash (FA). The aim of the study is the assessment of the pozzolanic activity of ilmenite mud waste by its impact on the microstructure of the cement matrix in comparison to the undoubted pozzolanic activity of fly ash. The presented test results include pore size distribution, phase composition, pozzolanic activity using thermal analysis, R3 bound water test, and microstructural analysis using scanning electron microscopy (SEM). Tests were performed on mortars cured for up to 360 days. The results presented in this paper have shown that R-MUD has a pozzolanic activity level similar to FA or better, which influences pore size distribution in the composite and its microstructure. During the curing process, the microstructure of composites containing R-MUD became more compact and sealed than those with FA, which might also increase their durability. The results of the R3 tests have proven the pozzolanic activity of R-MUD but its level was lower than FA. R-MUD might be a useful substitute for fly ash, especially given the lack of good-quality fly ash on the market. Full article
(This article belongs to the Special Issue Environmentally Friendly Composites Incorporating Waste Materials)
29 pages, 2481 KiB  
Article
Research on Active Safety Situation of Road Passenger Transportation Enterprises: Evaluation, Prediction, and Analysis
by Lili Zheng, Shiyu Cao, Tongqiang Ding, Jian Tian and Jinghang Sun
Entropy 2024, 26(6), 434; https://doi.org/10.3390/e26060434 (registering DOI) - 21 May 2024
Abstract
The road passenger transportation enterprise is a complex system, requiring a clear understanding of their active safety situation (ASS), trends, and influencing factors. This facilitates transportation authorities to promptly receive signals and take effective measures. Through exploratory factor analysis and confirmatory factor analysis, [...] Read more.
The road passenger transportation enterprise is a complex system, requiring a clear understanding of their active safety situation (ASS), trends, and influencing factors. This facilitates transportation authorities to promptly receive signals and take effective measures. Through exploratory factor analysis and confirmatory factor analysis, we delved into potential factors for evaluating ASS and extracted an ASS index. To predict obtaining a higher ASS information rate, we compared multiple time series models, including GRU (gated recurrent unit), LSTM (long short-term memory), ARIMA, Prophet, Conv_LSTM, and TCN (temporal convolutional network). This paper proposed the WDA-DBN (water drop algorithm-Deep Belief Network) model and employed DEEPSHAP to identify factors with higher ASS information content. TCN and GRU performed well in the prediction. Compared to the other models, WDA-DBN exhibited the best performance in terms of MSE and MAE. Overall, deep learning models outperform econometric models in terms of information processing. The total time spent processing alarms positively influences ASS, while variables such as fatigue driving occurrences, abnormal driving occurrences, and nighttime driving alarm occurrences have a negative impact on ASS. Full article
(This article belongs to the Special Issue Recent Advances in Statistical Inference for High Dimensional Data)
18 pages, 592 KiB  
Review
Spider and Wasp Acylpolyamines: Venom Components and Versatile Pharmacological Leads, Probes, and Insecticidal Agents
by Gandhi Rádis-Baptista and Katsuhiro Konno
Toxins 2024, 16(6), 234; https://doi.org/10.3390/toxins16060234 (registering DOI) - 21 May 2024
Abstract
Polyamines (PAs) are polycationic biogenic amines ubiquitously present in all life forms and are involved in molecular signaling and interaction, determining cell fate (e.g., cell proliferation, dif-ferentiation, and apoptosis). The intricate balance in the PAs’ levels in the tissues will determine whether beneficial [...] Read more.
Polyamines (PAs) are polycationic biogenic amines ubiquitously present in all life forms and are involved in molecular signaling and interaction, determining cell fate (e.g., cell proliferation, dif-ferentiation, and apoptosis). The intricate balance in the PAs’ levels in the tissues will determine whether beneficial or detrimental effects will affect homeostasis. It’s crucial to note that endoge-nous polyamines, like spermine and spermidine, play a pivotal role in our understanding of neu-rological disorders as they interact with membrane receptors and ion channels, modulating neuro-transmission. In spiders and wasps, monoamines (histamine, dopamine, serotonin, tryptamine) and polyamines (spermine, spermidine, acyl polyamines) comprise, with peptides and other sub-stances, the low molecular weight fraction of the venom. Acylpolyamines are venom components exclusively from spiders and a species of solitary wasp, which cause inhibition chiefly of iono-tropic glutamate receptors (AMPA, NMDA, and KA iGluRs) and nicotinic acetylcholine receptors (nAChRs). The first venom acylpolyamines ever discovered (argiopines, Joro and Nephila toxins, and philanthotoxins) have provided templates for the design and synthesis of numerous analogs. Thus far, analogs with high potency exert their effect at nanomolar concentrations, with high se-lectivity toward their ionotropic and ligand receptors. These potent and selective acylpolyamine analogs can serve biomedical purposes and pest control management. The structural modification of acylpolyamine with photolabile and fluorescent groups converted these venom toxins into use-ful molecular probes to discriminate iGluRs and nAchRs in cell populations. In various cases, the linear polyamines, like spermine and spermidine, constituting venom acyl polyamine backbones, have served as cargoes to deliver active molecules via a polyamine uptake system on diseased cells for targeted therapy. In this review, we examined examples of biogenic amines that play an essential role in neural homeostasis and cell signaling, contributing to human health and disease outcomes, which can be present in the venom of arachnids and hymenopterans. With an empha-sis on the spider and wasp venom acylpolyamines, we focused on the origin, structure, derivatiza-tion, and biomedical and biotechnological application of these pharmacologically attractive, chemically modular venom components. Full article
(This article belongs to the Section Animal Venoms)
21 pages, 603 KiB  
Article
Relation of the Content of Sustainable Components (HEFAs) in Blends with Hydrotreated Straight-Run Kerosene to the Properties of Aviation Fuel
by Rosen Dinkov, Dicho Stratiev, Ivo Andreev, Georgi Georgiev, Magdalena Angelova, Rositsa Zhivkova Dimitrova and Vesislava Toteva
Processes 2024, 12(6), 1045; https://doi.org/10.3390/pr12061045 (registering DOI) - 21 May 2024
Abstract
An expected increase in the demand for aviation transport service will result in the deterioration of the environment and human health, respectively, due to extra greenhouse gas (GHG) emissions. Concerns from EU institutions about the issue have led to legislation initiatives and, [...] Read more.
An expected increase in the demand for aviation transport service will result in the deterioration of the environment and human health, respectively, due to extra greenhouse gas (GHG) emissions. Concerns from EU institutions about the issue have led to legislation initiatives and, later, to development of Regulation (EU) 2023/2405 for the reduction of GHG emissions via the substitution of fossil kerosene with an increasing share of sustainable components. Hydroprocessed esters and fatty acids (HEFAs) are the most commercially acceptable sustainable alternative but their influence on aviation fuel properties needs to be further evaluated in terms of all required and extended properties, as per ASTM D1655. The main properties, together with the rarely reported upon existent gum, water separation, corrosion, and the electrical conductivity of HEFAs and their blends with fossil kerosene were quantitatively evaluated in this study. For every increase of 10% (v/v) of HEFAs, the following fuel properties improve: the freezing point decreases by 1.3 °C, the smoke point increases by an average of 3 mm, and the specific net energy increases by 0.08 MJ/kg. The acidity of HEFAs are an order of magnitude higher than that of conventional aviation fuel and, thus, close to the limit. The existent gum of the studied SAF is higher than that of fossil kerosene due to, most probably, the presence of non-evaporated residual material. Full article
(This article belongs to the Section Chemical Processes and Systems)
22 pages, 1235 KiB  
Article
Time-Optimal Trajectory Planning and Tracking for Autonomous Vehicles
by Jun-Ting Li, Chih-Keng Chen and Hongbin Ren
Sensors 2024, 24(11), 3281; https://doi.org/10.3390/s24113281 (registering DOI) - 21 May 2024
Abstract
This article presents a hierarchical control framework for autonomous vehicle trajectory planning and tracking, addressing the challenge of accurately following high-speed, at-limit maneuvers. The proposed time-optimal trajectory planning and tracking (TOTPT) framework utilizes a hierarchical control structure, with an offline trajectory optimization (TRO) [...] Read more.
This article presents a hierarchical control framework for autonomous vehicle trajectory planning and tracking, addressing the challenge of accurately following high-speed, at-limit maneuvers. The proposed time-optimal trajectory planning and tracking (TOTPT) framework utilizes a hierarchical control structure, with an offline trajectory optimization (TRO) module and an online nonlinear model predictive control (NMPC) module. The TRO layer generates minimum-lap-time trajectories using a direct collocation method, which optimizes the vehicle’s path, velocity, and control inputs to achieve the fastest possible lap time, while respecting the vehicle dynamics and track constraints. The NMPC layer is responsible for precisely tracking the reference trajectories generated by the TRO in real time. The NMPC also incorporates a preview algorithm that utilizes the predicted future travel distance to estimate the optimal reference speed and curvature for the next time step, thereby improving the overall tracking performance. Simulation results on the Catalunya circuit demonstrated the framework’s capability to accurately follow the time-optimal raceline at an average speed of 116 km/h, with a maximum lateral error of 0.32 m. The NMPC module uses an acados solver with a real-time iteration (RTI) scheme, to achieve a millisecond-level computation time, making it possible to implement it in real time in autonomous vehicles. Full article
(This article belongs to the Section Navigation and Positioning)
23 pages, 995 KiB  
Article
Analysis of the Impact of U.S. Trade Policy Uncertainty on China’s Grain Trade
by Lulu Yang, Yankai Gai, An Zhang and Lihui Wang
Sustainability 2024, 16(11), 4332; https://doi.org/10.3390/su16114332 (registering DOI) - 21 May 2024
Abstract
U.S. trade protectionism has frequently risen recently, and trade policy fluctuations have become increasingly significant. In this context, examining the impact of U.S. trade policy uncertainty on China’s grain trade is of great significance to China’s response to changes in the international trade [...] Read more.
U.S. trade protectionism has frequently risen recently, and trade policy fluctuations have become increasingly significant. In this context, examining the impact of U.S. trade policy uncertainty on China’s grain trade is of great significance to China’s response to changes in the international trade situation, guaranteeing national food security and promoting sustainable agricultural development. From the statistical data, the U.S. trade policy uncertainty and China’s grain imports primarily show a reverse trend, and China’s grain exports show a positive trend. To further explore the impact of U.S. trade policy uncertainty on China’s grain trade, this study selects the monthly data from July 2003 to December 2022. It conducts impulse response analysis by constructing a vector autoregressive model with stochastic volatility. It is found that the impact of U.S. trade policy uncertainty on China’s grain trade has prominent time-varying characteristics and point-in-time effects, and the impact on different kinds of grain is heterogeneous. In this regard, China needs to clarify the nature of the trade dispute between China and the United States, reasonably utilize the multilateral coordination mechanism of the WTO, coordinate the international and domestic markets, adjust the short board of grain trade, and safeguard the sustainable development of Chinese agriculture. Full article
(This article belongs to the Special Issue Agri-Food Economics and Rural Sustainable Development)
13 pages, 978 KiB  
Article
Effect of the Spading Machine on Various Soil Parameters at Different Tillage Depths
by Neeraj Kumar Singh, Baldev Dogra, Gursahib Singh Manes, Dilwar Singh Parihar, Ali Salem and Ahmed Elbeltagi
Sustainability 2024, 16(11), 4334; https://doi.org/10.3390/su16114334 (registering DOI) - 21 May 2024
Abstract
This study was carried out to investigate the effect of the spading machine as a sustainable tillage tool at different depths of tillage on soil parameters. The spading machine was evaluated for two independent parameters: soil type and depth of cut. The observed [...] Read more.
This study was carried out to investigate the effect of the spading machine as a sustainable tillage tool at different depths of tillage on soil parameters. The spading machine was evaluated for two independent parameters: soil type and depth of cut. The observed dependent parameters were the bulk density of soil, mean clod size, soil strength, torque requirement, fuel consumption, and cost of operation. The bulk density varied from 1.18 to 1.39 g/cm3, the mean clod size between 12.72 and 68.37 mm, the soil strength between 69 and 4714.5 kPa, the torque requirement between 206 and 344.62 N-m, the fuel consumption between 13.60 and 21.83 l/ha, and cost of operation ranged between 2670.37 INR/ha (34.71 USD/ha) and 3635.87 INR/ha (47.27 USD/ha). It was observed that with the increase in tillage depth, the dependent parameters were also increasing, except the cost of operation varied nonsignificantly. In comparison to the spading machine, other primary tillage tools resulted in higher bulk density and fuel consumption, whereas mean clod size and cost of operation were reported higher except for the rotary tillage tool. Thus, the spading machine could be a sustainable tillage tool for long-term agricultural goals. Full article
(This article belongs to the Special Issue Sustainable Soil Management and Crop Production Research)
19 pages, 3122 KiB  
Article
Enhancing Human Key Point Identification: A Comparative Study of the High-Resolution VICON Dataset and COCO Dataset Using BPNET
by Yunju Lee, Bibash Lama, Sunghwan Joo and Jaerock Kwon
Appl. Sci. 2024, 14(11), 4351; https://doi.org/10.3390/app14114351 (registering DOI) - 21 May 2024
Abstract
Accurately identifying human key points is crucial for various applications, including activity recognition, pose estimation, and gait analysis. This study introduces a high-resolution dataset formed via the VICON motion capture system and three diverse 2D cameras. It facilitates the training of neural networks [...] Read more.
Accurately identifying human key points is crucial for various applications, including activity recognition, pose estimation, and gait analysis. This study introduces a high-resolution dataset formed via the VICON motion capture system and three diverse 2D cameras. It facilitates the training of neural networks to estimate 2D key joint positions from images and videos. The study involved 25 healthy adults (17 males, 8 females), executing normal gait for 2 to 3 s. The VICON system captured 3D ground truth data, while the three 2D cameras collected images from different perspectives (0°, 45°, and 135°). The dataset was used to train the Body Pose Network (BPNET), a popular neural network model developed by NVIDIA TAO. Additionally, a comparison entails another BPNET model trained on the COCO 2017 dataset, featuring over 118,000 annotated images. Notably, the proposed dataset exhibited a higher level of accuracy (14.5%) than COCO 2017, despite comprising one-fourth of the image count (23,741 annotated image). This substantial reduction in data size translates to improvements in computational efficiency during model training. Furthermore, the unique dataset’s emphasis on gait and precise prediction of key joint positions during normal gait movements distinguish it from existing alternatives. This study has implications ranging from gait-based person identification, and non-invasive concussion detection through sports temporal analysis, to pathologic gait pattern identification. Full article
(This article belongs to the Special Issue Advanced Sensors for Postural or Gait Stability Assessment)
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18 pages, 3008 KiB  
Review
Laying Hens: Why Smothering and Not Surviving?—A Literature Review
by Caroline Citta Mazocco, Sérgio Luís de Castro Júnior, Robson Mateus Freitas Silveira, Rosangela Poletto and Iran José Oliveira da Silva
Animals 2024, 14(11), 1518; https://doi.org/10.3390/ani14111518 (registering DOI) - 21 May 2024
Abstract
The proliferation of rearing systems providing opportunities for birds to engage in natural behaviors can trigger behavioral repertoires that when not manageable compromise animal welfare and the economic viability of the flock. Smothering in laying hens has long been perceived as “natural” or [...] Read more.
The proliferation of rearing systems providing opportunities for birds to engage in natural behaviors can trigger behavioral repertoires that when not manageable compromise animal welfare and the economic viability of the flock. Smothering in laying hens has long been perceived as “natural” or the result of hysteria among birds in the flock. However, the current literature has recognized smothering as an abnormal outcome with the potential to result in significant losses in cage-free poultry systems. Recent studies have specifically aimed to categorize the organization of smothering behavior and highlight its potential causes and consequences. In this study, literature review and bibliographic mapping, drawing on published articles and engagement with poultry farmers through extension and rural technical assistance, were employed. The findings indicate that smothering is a behavior triggered by factors related to the environment in which the laying hens are kept. This study concludes that there is a critical need for more rigorous and detailed research to elucidate the nuances of avian behavioral physiology and assess the impact of production systems on animal welfare and the economic impacts on the flock. This research contributes to a deeper understanding of bird behavior in high-production environments and provides practical insights for the poultry industry. Full article
(This article belongs to the Special Issue Advances in Poultry Behaviour and Welfare)
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