An evaluation of the impact of osteoporosis on loss of spinal stability, with or without intervertebral disc degeneration, using computational analysis is presented. The research also investigates the correlation between osteoporosis and intervertebral disc degeneration. Three-dimensional finite element models of human lumbar spine segments were used to assess the influence of osteoporosis on spinal stability. Five different models of age-related degeneration were created using various material properties for trabecular bone and intervertebral discs. Calculation results indicate that in a spine with osteoporosis, the deformation of the intervertebral discs can increase by more than 30% when compared to a healthy spine. Thus, intervertebral disc deformation depends not only on the degree of degeneration of the discs themselves, but their deformation is also influenced by the degree of osteoporosis of the vertebrae. Additionally, the load-bearing capacity of the spine can decrease by up to 30% with osteoporosis, regardless of the degree of intervertebral disc deformation. In conclusion, osteoporosis can contribute to intervertebral disc degeneration. Full article

To realize the utilization of peanut shell, this study investigates the combustion behavior, chemical kinetics and thermodynamic parameters of peanut shell using TGA under atmospheric air at the heating rates of 10, 20, and 30 K/min. Results indicate that increasing the heating rate leads to higher ignition, burnout, and peak temperatures, as observed in the TG/DTG curves shifting to the right. Analysis of combustion performance parameters suggest that higher heating rates can enhance combustion performances. Kinetic analysis using two model-free methods, KAS and FWO, shows that the activation energy (E_α) ranges from 93.30 to 109.65 kJ/mol for FWO and 89.72 to 103.88 kJ/mol for KAS. The data fit well with coefficient of determination values (R²) close to 1 and the mean squared error values (MSE) less than 0.006. Pre-exponential factors using FWO range from 2.19 × 10⁶ to 8.08 × 10⁷ s^–1, and for KAS range from 9.72 × 10⁵ to 2.25 × 10⁷ s^–1. Thermodynamic analysis indicates a low-energy barrier (≤±6 kJ/mol) between activation energy and enthalpy changes, suggesting easy reaction initiation. Furthermore, variations in enthalpy (ΔH), Gibbs free energy (ΔG), and entropy (ΔS) upon conversion (α) suggest that peanut shell combustion is endothermic and non-spontaneous, with the generation of more homogeneous or well-ordered products as combustion progresses. These findings offer a theoretical basis and data support for the further utilization of agricultural biomass. Full article

Rural landscapes serve as important platforms to determine the landscape characteristics (LCs) of rural areas, demonstrating the landscape characteristics specific to certain regions to the public. However, the development trend of urban and rural areas is continuous and impacts the characteristics of rural landscapes, which directly affects the public’s visual experience and landscape perception. In order to improve the characteristics of rural landscapes, this study evaluates and analyzes their visual quality based on public preferences and eye movement heat maps. The results show that most subjects have a high preference for horizontal, open-view rural landscapes with fields and landform features as the dominant landscape elements. This study also found that the combination of strip-like or planar settlement buildings with regional characteristics and landform features has an active impact on the visual quality of rural landscapes. These results show that rural landscapes characterized by scattered settlement buildings without significant regional characteristics, horizontally curved roads, bridges, and other human-made landscape elements, and mixed and disorderly vegetation have low landscape preference, which degrades their visual quality. These research results provide crucial suggestions for landscape managers to protect and renew rural landscape features. Full article

The Amazon region has the largest diversity of freshwater stingrays; however, there are still places where information about this group is scarce. The present work aims to record the occurrence of freshwater stingrays in the Uatumã river basin, Amazonas, Brazil. For this, collections were carried out in three municipalities bathed by the Uatumã River, Presidente Figueiredo, Itapiranga, and São Sebastião do Uatumã. The rays were collected through fishing using a hand net and, after capture, were identified through the pattern of the dorsal and ventral color of the disc, the absence or presence of the labial groove, and the organization of the row of spines on the tail, and were also measured, weighed, and sexed. In total, 69 specimens of Potamotrygonines were captured, 59 of which were from the genus Potamotrygon and ten individuals from the genus Paratrygon. The present study provides preliminary information on the characteristics of freshwater stingray species that may occur in the Uatumã River. Furthermore, new research is necessary to improve the identification of specimens to determine the diversity and elucidate aspects related to the biology of elasmobranchs in the Uatumã River Basin, Brazil. Full article

This study explores the application effect of the new non-isocyanate polyurethane curing agent on the rapid curing mechanism and bearing characteristics of piles in beach foundations. Through laboratory tests and field tests, the effects of the curing agent on the physical and mechanical properties of sand were systematically analyzed, including compressive strength, shear strength, and elastic modulus, and the effects of water content and cement–sand mass ratio on the properties of sand after curing were investigated. The results show that introducing a curing agent significantly improves the mechanical properties of sand, and the cohesion and internal friction angle increase exponentially with the sand mass ratio. In addition, the increase in water content leads to a decrease in the strength of solidified sand, and the microstructure analysis reveals the change in the bonding effect between the solidified gel and the sand particles. The field static load tests of single piles and pile groups verify the effectiveness of the rapid solidification pile in beach foundations and reveal the significant influence of pile length and pile diameter on the bearing capacity. This study provides a theoretical basis and technical support for the rapid solidification and reinforcement of tidal flat foundations and provides important guidance for related engineering applications. Full article

The role of lncRNA and circRNA in wheat grain development is still unclear. The objectives of this study were to characterize the lncRNA and circRNA in the wheat grain development and to construct the interaction network among lncRNA, circRNA, and their target miRNA to propose a lncRNA–circRNA–miRNA module related to wheat grain development. Full transcriptome sequencing on two wheat varieties (Annong 0942 and Anke 2005) with significant differences in 1000-grain weight at 10 d (days after pollination), 20 d, and 30 d of grain development were conducted. We detected 650, 736, and 609 differentially expressed lncRNA genes, and 769, 1054, and 1062 differentially expressed circRNA genes in the grains of 10 days, 20 days and 30 days after pollination between Annong 0942 and Anke 2005, respectively. An analysis of the lncRNA–miRNA and circRNA–miRNA targeting networks reveals that circRNAs exhibit a more complex and extensive interaction network in the development of cereal grains and the formation of grain shape. Central to these interactions are tae-miR1177, tae-miR1128, and tae-miR1130b-3p. In contrast, lncRNA genes only form a singular network centered around tae-miR1133 and tae-miR5175-5p when comparing between varieties. Further analysis is conducted on the underlying genes of all target miRNAs, we identified TaNF-YB1 targeted by tae-miR1122a and TaTGW-7B targeted by miR1130a as two pivotal regulatory genes in the development of wheat grains. The quantitative real-time PCR (qRT-PCR) and dual-luciferase reporter assays confirmed the target regulatory relationships between miR1130a-TaTGW-7B and miR1122a-TaNF-YB1. We propose a network of circRNA and miRNA-mediated gene regulation in the development of wheat grains. Full article

This research investigates the influence of intellectual capital on the stability of banks in the evolving context of Saudi Arabia’s banking sector. Against the backdrop of rapid economic reforms under Vision 2030 and the challenges imposed by the COVID-19 pandemic, this research incorporates specific metrics related to these contexts and provides a nuanced analysis of how intellectual capital and its components (human capital efficiency (HCE), structural capital efficiency (SCE), and capital employed efficiency (CEE)) affect the financial stability of Saudi banks. This research analyzes a decade-long panel dataset for ten major Saudi banks from 2012 to 2022, utilizing both fixed-effects and cross-section random-effects models to discern the impact of intellectual capital on bank stability. The findings reveal a positive overall influence of intellectual capital on bank stability; however, individual components present a complex relationship, with CEE showing a positive association and HCE and SCE demonstrating unexpected negative correlations with bank stability. The research identifies leverage (LEV) as a significant factor negatively impacting stability. Operational efficiency (OPEF) and size (SIZE) also negatively affect stability. Surprisingly, macroeconomic indicators and bank size exhibit non-significant effects on bank stability. Similarly, the direct impact of the COVID-19 pandemic was found to be non-significant, suggesting a resilient banking environment or the presence of effective mitigating strategies. As Saudi Arabia continues its ambitious economic transformation, this research underscores the critical role of effectively managed intellectual capital in ensuring the banking sector’s stability. It provides a foundation for ongoing research in this vital area. Full article

The significance of developing shared road infrastructure in cities throughout the world is growing. Driven by the need to improve traffic management in ways that enhance multiple sustainability outcomes, developing the tools needed to test shared space proposals is becoming more sought after by responsible agencies. This paper reviews approaches to simulation modeling focused on representing and assessing shared spaces, culminating in a new approach presented here called the Integrated Pedestrian–Vehicle Model (IPVM)—a novel framework that combines social force models, car-following models and other algorithms from the robotics domain to better describe both mobility and activity within a shared space. The IPVM recognizes that while shared spaces are inherently multimodal, past efforts have tended to use pedestrian models as a starting point. Most consider the interaction of pedestrians with other pedestrians and static road infrastructure. Shared space models are generally microscopic models that integrate a social force model with a variety of car-following models to describe the interaction between vehicles and pedestrians. However, there is little research and few practical methodologies that address the long-range conflict avoidance between vehicles and pedestrians. This aspect is crucial for accurately representing the desire lines and pathways of pedestrians and active transport users in complex environments like shared spaces. The IPVM describes and visualizes shared road infrastructure with an absence of separating infrastructure between users and outputs. It generates metrics that can be used in conjunction with the latest evaluation approaches to gauge the sustainability credentials of shared space road proposals. Enhanced modeling of shared space solutions can lead to more effective implementation, which can potentially reduce the presence of cars, increase public and active transport use and lead to a more sustainable transport system. Full article

Biologists and veterinarians rely on dart projectors to inject animals with drugs, take biopsies from specimens, or inject tracking chips. Firearms, air guns, and other launchers are limited in their ability to precisely control the kinetic energy of a projectile, which can injure the animal if too high. In order to improve the safety of remote drug delivery, a lidar-modulated electromagnetic launcher and a soft drug delivery dart were prototyped. A single-stage revolver coilgun and soft dart were designed and tested at distances up to 8 m. With a coil efficiency of 2.25%, the launcher could consistently deliver a projectile at a controlled kinetic energy of 1.00 ± 0.006 J and an uncontrolled kinetic energy of 2.66 ± 0.076 J. Although modifications to charging time, sensors, and electronics could improve performance, our launcher performed at the required level at the necessary distances. The precision achieved with commercial components enables many other applications, from law enforcement to manufacturing. Full article

Silicon represents one of the most attractive anode materials in lithium-ion batteries (LIBs) due to its highest theoretical specific capacity. Thus, there is a most urgent need to prepare Si-based nano materials in a very efficient way and develop some reasonable approaches for their modification in order to resolve the short-falls of Si anodes, which include both low conductivity and huge volume changes during intercalation of lithium ions. In this work, the kerf loss silicon (KL Si) from the photovoltaic industry has been used as an inexpensive Si source for the preparation of a porous silicon/silver/carbon composite (pSi/Ag@C) as an anode material. Porous silicon was embedded with Ag particles via the Ag-catalyzed chemical etching process, providing additional space to accommodate the large volume expansion of silicon. After carbon coating from polymerization of tannic acid on the surface of pSi/Ag, a high-speed conductive network over the surface of silicon was built and contributed to enhancing the electrochemical performance of the anode. The pSi/Ag@C electrode discharge capacity maintained at a stable value of 665.3 mAh g⁻¹ after 100 cycles under 0.5 A g⁻¹ and exhibited good rate performance. Therefore, this study recommends that the method is very promising for producing a silicon anode material for LIBs from KL Si. Full article

As global arid conditions worsen and groundwater resources diminish, drought stress has emerged as a critical impediment to plant growth and development globally, notably causing declines in crop yields and even the extinction of certain cultivated species. Numerous studies on drought resistance have demonstrated that DNA methylation dynamically interacts with plant responses to drought stress by modulating gene expression and developmental processes. However, the precise mechanisms underlying these interactions remain elusive. This article consolidates the latest research on the role of DNA methylation in plant responses to drought stress across various species, focusing on methods of methylation detection, mechanisms of methylation pattern alteration (including DNA de novo methylation, DNA maintenance methylation, and DNA demethylation), and overall responses to drought conditions. While many studies have observed significant shifts in genome-wide or gene promoter methylation levels in drought-stressed plants, the identification of specific genes and pathways involved remains limited. This review aims to furnish a reference for detailed research into plant responses to drought stress through epigenetic approaches, striving to identify drought resistance genes regulated by DNA methylation, specific signaling pathways, and their molecular mechanisms of action. Full article

As nanoparticle syntheses on a large scale usually yield products with broad size and shape distributions, the properties of nanoparticle-based products need to be tuned after synthesis by narrowing the size and shape distributions or via the removal of undesired fractions. The development of property-selective classification processes requires a universal framework for the quantitative evaluation of multi-dimensional particle fractionation processes. This framework must be applicable to any property and any particle classification process. We extended the well-known one-dimensional methodology commonly used for describing particle size distributions and fractionation processes to the multi-dimensional case to account for the higher complexity of the property distribution and separation functions. In particular, multi-dimensional lognormal distributions are introduced and applied to diameter and length distributions of gold nanorods. The fractionation of nanorods via centrifugation and by orthogonal centrifugal and electric forces is modeled. Moreover, we demonstrate that analytical ultracentrifugation with a multi-wavelength detector (MWL-AUC) is a fast and very accurate method for the measurement of two-dimensional particle size distributions in suspension. The MWL-AUC method is widely applicable to any class of nanoparticles with size-, shape- or composition-dependent optical properties. In addition, we obtained distributions of the lateral diameter and the number of layers of molybdenum disulfide nanosheets via stepwise centrifugation and spectroscopic evaluation of the size fractions. Full article

Current orbit uncertainty propagation (OUP) and orbit determination (OD) methods suffer from drawbacks related to high computational burden, limiting their applications in deep space missions. To this end, this paper proposes a multivariate attention-based method for efficient OUP and OD of Earth–Jupiter transfer. First, a neural network-based OD framework is utilized, in which the orbit propagation process in a traditional unscented transform (UT) and unscented Kalman filter (UKF) is replaced by the neural network. Then, the sample structure of training the neural network for the Earth–Jupiter transfer is discussed and designed. In addition, a method for efficiently generating a large number of samples for the Earth–Jupiter transfer is presented. Next, a multivariate attention-based neural network (MANN) is designed for orbit propagation, which shows better capacity in terms of accuracy and generalization than the deep neural network. Finally, the proposed method is successfully applied to solve the OD problem in an Earth–Jupiter transfer. Simulations show that the proposed method can obtain a similar estimation to the UKF while saving more than 90% of the computational cost. Full article

The Internet of Things (IoT) presents great potential in various fields such as home automation, healthcare, and industry, among others, but its infrastructure, the use of open source code, and lack of software updates make it vulnerable to cyberattacks that can compromise access to data and services, thus making it an attractive target for hackers. The complexity of cyberattacks has increased, posing a greater threat to public and private organizations. This study evaluated the performance of deep learning models for classifying cybersecurity attacks in IoT networks, using the CICIoT2023 dataset. Three architectures based on DNN, LSTM, and CNN were compared, highlighting their differences in layers and activation functions. The results show that the CNN architecture outperformed the others in accuracy and computational efficiency, with an accuracy rate of 99.10% for multiclass classification and 99.40% for binary classification. The importance of data standardization and proper hyperparameter selection is emphasized. These results demonstrate that the CNN-based model emerges as a promising option for detecting cyber threats in IoT environments, supporting the relevance of deep learning in IoT network security. Full article

This study presents a novel framework for improving indoor augmented reality (AR) navigation with modern smartphone technology, which is achieved by addressing two major challenges: managing large absolute coordinate spaces and reducing error accumulation in camera-based spatial tracking. Our contribution is significant in two ways. First, we integrate geofencing with indoor navigation by considering spatial tracking errors, timing for audio guidance, and dynamic 3D arrow visualization for effective local-to-global spatial coordinate transformation. This method achieves precise local positioning and seamlessly integrates with larger spatial contexts, overcoming the limitations of current AR systems. Second, we introduce a periodic image-based calibration approach to minimize the inherent error accumulation in camera-based tracking, enhancing accuracy over longer distances. Unlike prior studies focusing on individual technologies, our work explores the software architecture of indoor AR navigation by providing a comprehensive framework for its design and practical use. The practicality of our approach is validated through the implementation of a smartphone application at the Mineral Industry Museum of Akita University, highlighting the limitations of component technologies and demonstrating our framework’s effectiveness. Full article

This paper focuses on the study of current knowledge regarding the use of hydrogen as a reducing agent in the metallurgical processes of iron and steel production. This focus is driven by the need to introduce environmentally suitable energy sources and reducing agents in this sector. This theoretical study primarily examines laboratory research on the reduction of Fe-based, metal-bearing materials. The article presents a critical analysis of the reduction in iron oxides using hydrogen, highlighting the advantages and disadvantages of this method. Most experimental facilities worldwide employ their unique original methodologies, with techniques based on Thermogravimetric analysis (TGA) devices, fluidized beds, and reduction retorts being the most common. The analysis indicates that the mineralogical composition of the Fe ores used plays a crucial role in hydrogen reduction. Temperatures during hydrogen reduction typically range from 500 to 900 °C. The reaction rate and degree of reduction increase with higher temperatures, with the transformation of wüstite to iron being the slowest step. Furthermore, the analysis demonstrates that reduction of iron ore with hydrogen occurs more intensively and quickly than with carbon monoxide (CO) or a hydrogen/carbon monoxide (H₂/CO) mixture in the temperature range of 500 °C to 900 °C. The study establishes that hydrogen is a superior reducing agent for iron oxides, offering rapid reduction kinetics and a higher degree of reduction compared to traditional carbon-based methods across a broad temperature range. These findings underscore hydrogen’s potential to significantly reduce greenhouse gas emissions in the steel production industry, supporting a shift towards more sustainable manufacturing practices. However, the implementation of hydrogen as a primary reducing agent in industrial settings is constrained by current technological limitations and the need for substantial infrastructural developments to support large-scale hydrogen production and utilization. Full article

This study documents an investigation of the flow stress properties and microstructural features of Ti6Al4V (ELI) alloy produced using laser powder bed fusion (LPBF). Selected heat treatment strategies were applied to the material to obtain different microstructures. The influence of quasi-static strain rates and temperature on the obtained microstructures of this material and their strain hardening properties are documented in this study. All microstructures of the alloy formed in this study were found to be sensitive to quasi-static strain rates and temperatures, where their flow stresses increased with increasing strain rate and decreased for tests conducted at elevated temperatures. The strain hardening rates of the fine microstructures were found to be high compared to those of coarse microstructures. The strain hardening rates for the various forms of LPBF Ti6Al4V (ELI) examined here were found to diminish with increasing test temperature. Though the deformed surfaces of the built samples were largely dominated by adiabatic shear bands (ASBs), the absence of ASBs was noted for all samples tested at a temperature of 500 °C and an imposed strain of 30%. Full article

The Program for International Student Assessment highlights the persistent lack of commitment and motivation among students worldwide in their school activities, which are resulting in decreased proficiency levels in reading, mathematics, and science. The magnitude of this phenomenon, with its clear social implications, suggests that we are facing a concerning quest for immediate answers and results. This research focuses on the impact of the relationships between self-regulated learning processes and the planning of time management that is dedicated to school activities on student performance, specifically in the subjects of the Mother Tongue and Mathematics. The instruments used for analysis included the Inventory of Self-Regulated Learning Processes, the Inventory of Time Management Planning, a personal data sheet, and a school data sheet. The sample in this study consisted of 688 students from primary schools in northern Portugal. The results reveal that self-regulated learning has a positive influence on how students plan time management, both in the short and long term. Additionally, a positive and statistically significant relationship is observed between short-term and long-term time management planning and students’ academic performance. This study provides an in-depth perspective on the dynamics between these elements, shedding light on the crucial nuances that shape students’ academic journeys. Full article

Ninth grade on-track is predictive of high school graduation, more than race, socio-economic status, and prior achievement combined. Although initiatives characterized by an intense focus on the ninth-grade year are being increasingly implemented, research has not fully documented and tested mechanisms linked to improved outcomes. Using survey and transcript-level data and causal mediation analysis, this study tests the effects of students attending high teacher efficacy (self and collective—TSE and CTE) schools on ninth grade on-track in an urban school district in a northeast state in the United States. It further examines the extent to which ambitious instructional practices, defined as culturally relevant and transformative pedagogy, mediate the effects of TSE on ninth grade on-track and how levels of supportive school culture moderate these relationships. The findings indicate that urban ninth-graders attending schools with high TSE and CTE are more likely to be on track at the end of ninth grade. Additionally, the direct effect of students attending a school with high TSE was mediated by the level of ambitious instruction. We discuss implications for teacher education (TE) and professional development. Full article

In the development of bone graft substitutes, a fundamental step is the use of scaffolds with adequate composition and architecture capable of providing support in regenerative processes both on the tissue scale, where adequate resistance to mechanical stress is required, as well as at the cellular level where compliant chemical–physical and mechanical properties can promote cellular activity. In this study, based on a previous optimization study of this group, the potential of a three-dimensional construct based on polycaprolactone (PCL) and a novel biocompatible Mg- and Sr-containing glass named BGMS10 was explored. Fourier-transform infrared spectroscopy and scanning electron microscopy showed the inclusion of BGMS10 in the scaffold structure. Mesenchymal stem cells cultured on both PCL and PCL-BGMS10 showed similar tendencies in terms of osteogenic differentiation; however, no significant differences were found between the two scaffold types. This circumstance can be explained via X-ray microtomography and atomic force microscopy analyses, which correlated the spatial distribution of the BGMS10 within the bulk with the elastic properties and topography at the cell scale. In conclusion, our study highlights the importance of multidisciplinary approaches to understand the relationship between design parameters, material properties, and cellular response in polymer composites, which is crucial for the development and design of scaffolds for bone regeneration. Full article

In the Standard Model, ad hoc hypotheses assume the existence of three generations of point-like leptons and quarks, which possess a point-like structure and follow the Dirac equation involving four anti-commutative matrices. In this work, we consider the sedenion hypercomplex algebra as an extension of the Standard Model and show its close link to SU(5), which is the underlying symmetry group for the grand unification theory (GUT). We first consider the direct-product quaternion model and the eight-element octonion algebra model. We show that neither the associative quaternion model nor the non-associative octonion model could generate three fermion generations. Instead, we show that the sedenion model, which contains three octonion sub-algebras, leads naturally to precisely three fermion generations. Moreover, we demonstrate the use of basis sedenion operators to construct twenty-four 5 × 5 generalized lambda matrices representing SU(5) generators, in analogy to the use of octonion basis operators to generate Gell-Mann’s eight 3 × 3 lambda-matrix generators for SU(3). Thus, we provide a link between the sedenion algebra and Georgi and Glashow’s SU(5) GUT model that unifies the electroweak and strong interactions for the Standard Model’s elementary particles, which obey SU(3)SU(2)U(1) symmetry. Full article

Laser bending is a kind of cumulative forming technology and bending efficiency is one of its most important indexes. This study investigates the bending behavior and the microstructure of DP980 steel plates under different laser scanning strategies, using an IPG laser system. Two sets of experiments varied the accumulated line energy density (AED) by altering the laser scanning velocity and number of scans. The results show that, for the single laser scanning process, the bending angle of the plate increases with AED, due to a larger temperature gradient through the thickness direction; however, this relationship is nonlinear. A higher AED led to a sharper initial increase in bending angle, which then plateaued. Under the same AED conditions, the bending angle of the plate undergoing multiple laser scans increases by at least 26% compared to the single one, due to the microstructure changes. It is revealed that the bending efficiency is affected by both the AED and the resultant microstructure evolution in the DP980 steel. Higher AED values and appropriate peak temperatures facilitate better bending behavior due to the formation of uniform martensite and grain refinement. Conversely, excessive peak temperatures can hinder bending due to grain growth. Full article