The 2023 MDPI Annual Report has
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23 pages, 6230 KiB  
Article
Influence of Picea Abies Logs on the Distribution of Vascular Plants in Old-Growth Spruce Forests
by Anastasiya V. Kikeeva, Ivan V. Romashkin, Anna Yu. Nukolova, Elena V. Fomina and Alexandr M. Kryshen
Forests 2024, 15(5), 884; https://doi.org/10.3390/f15050884 (registering DOI) - 19 May 2024
Abstract
The deadwood contributes to an increase in soil heterogeneity due to the changing the microrelief (by the formation of windthrow-soil complexes), as well as changes in physical and chemical characteristics of decaying wood directly during xylolysis. We hypothesized that fallen logs as an [...] Read more.
The deadwood contributes to an increase in soil heterogeneity due to the changing the microrelief (by the formation of windthrow-soil complexes), as well as changes in physical and chemical characteristics of decaying wood directly during xylolysis. We hypothesized that fallen logs as an element of microrelief influence the species composition and cover structure of vascular plants. We studied the influence of Picea abies (L.) Karst fallen logs of moderate and advanced decay stages on the horizontal distribution and heterogeneity of vascular plant cover in different microsite types (small boreal grass type, blueberry type, small boreal grass-blueberry type, herbs, and blueberry type) in old-growth middle taiga spruce forest in the Kivach State Nature Reserve (Republic of Karelia, Russia). The fallen deadwood acts as a factor of heterogeneity, causing reversible changes in the homogeneity of the original plant cover. The decaying logs influence the horizontal distribution of small herbs by changing the occurrence and density of shoots of Oxalis acetosella L., Maianthemum bifolium (L.) F.W. Schmidt, Vaccinium myrtillus L., and Vaccinium vitis-idaea L., as well as the occurrence of Luzula pilosa (L.) Willd. and Calamagrostis arundinacea (L.) Roth. Its impact on the heterogeneity parameters can be traced up to 20 cm from the log. The differences in vascular plant cover between fallen logs and the surrounding forest floor depend on the soil conditions of the microsite. The heterogeneity of conditions created by the logs smoothed out with increasing decay class, resulting in decreasing differences in the heterogeneity parameters of vascular plant cover between deadwood and forest floor. The changes in the homogeneity of the initial vascular plant cover by deadwood and the gradual smoothing of heterogeneity between the logs and the forest floor in rich and poor conditions have different, mainly opposite, trends. Finally, the structure of the vegetation cover reaches a state that is typical of particular growth conditions beyond deadwood. Full article
(This article belongs to the Section Forest Soil)
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17 pages, 3627 KiB  
Article
Encapsulation of Nanoparticles with Statistical Copolymers with Different Surface Charges and Analysis of Their Interactions with Proteins and Cells
by Saad Megahed, Nicole Wutke, Yang Liu, Markus Klapper, Florian Schulz, Neus Feliu and Wolfgang J. Parak
Int. J. Mol. Sci. 2024, 25(10), 5539; https://doi.org/10.3390/ijms25105539 (registering DOI) - 19 May 2024
Abstract
Encapsulation with polymers is a well-known strategy to stabilize and functionalize nanomaterials and tune their physicochemical properties. Amphiphilic copolymers are promising in this context, but their structural diversity and complexity also make understanding and predicting their behavior challenging. This is particularly the case [...] Read more.
Encapsulation with polymers is a well-known strategy to stabilize and functionalize nanomaterials and tune their physicochemical properties. Amphiphilic copolymers are promising in this context, but their structural diversity and complexity also make understanding and predicting their behavior challenging. This is particularly the case in complex media which are relevant for intended applications in medicine and nanobiotechnology. Here, we studied the encapsulation of gold nanoparticles and quantum dots with amphiphilic copolymers differing in their charge and molecular structure. Protein adsorption to the nanoconjugates was studied with fluorescence correlation spectroscopy, and their surface activity was studied with dynamic interfacial tensiometry. Encapsulation of the nanoparticles without affecting their characteristic properties was possible with all tested polymers and provided good stabilization. However, the interaction with proteins and cells significantly depended on structural details. We identified statistical copolymers providing strongly reduced protein adsorption and low unspecific cellular uptake. Interestingly, different zwitterionic amphiphilic copolymers showed substantial differences in their resulting bio-repulsive properties. Among the polymers tested herein, statistical copolymers with sulfobetaine and phosphatidylcholine sidechains performed better than copolymers with carboxylic acid- and dimethylamino-terminated sidechains. Full article
(This article belongs to the Special Issue Molecular Research on Nanotoxicology)
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21 pages, 577 KiB  
Article
Functional-Combination-Based Comprehensive Benefit Evaluation of Energy Storage Projects under Source-Grid-Load Scenarios via Super-Efficiency DEA
by Hong Qu and Ze Ye
Sustainability 2024, 16(10), 4278; https://doi.org/10.3390/su16104278 (registering DOI) - 19 May 2024
Abstract
As an important support for power systems with high penetration of sustainable energy, the energy storage system (ESS) has changed the traditional model of simultaneous implementation of electricity production and consumption. Its installed capacity under the source-grid-load scenario is rising year by year, [...] Read more.
As an important support for power systems with high penetration of sustainable energy, the energy storage system (ESS) has changed the traditional model of simultaneous implementation of electricity production and consumption. Its installed capacity under the source-grid-load scenario is rising year by year, contributing to sustainable development, but it faces the problems of insufficient utilization and benefits. This study analyzes the functional combination of ESS under source-grid-load scenarios. A comprehensive benefit evaluation method of energy storage projects (ESPs), based on a fuzzy decision-making trial and evaluation laboratory (DEMATEL) and super-efficiency data envelopment analysis (DEA), is proposed. Firstly, the functional requirements of energy storage in source-grid-load scenarios are explored, and the characteristics of various functions are analyzed to form eight functional combination schemes. Secondly, index modeling is carried out from three aspects—the whole life cycle cost, functional combination benefits, and social and environmental benefits—and a comprehensive benefit evaluation index system of ESP is proposed. Then, the intuitionistic trapezoidal fuzzy number (ITFN) is combined with DEMATEL to form an effective analysis method for the input–output relationship of the indices, and the comprehensive evaluation is realized based on the SE-DEA model. Compared with other methods, this model can ensure the objectivity and stability of the evaluation results in ESP evaluation. Finally, the effectiveness of the proposed evaluation method and the rationality of the functional combination are verified under source-grid-load scenarios. The calculation results show that in the application scenario of source-grid-load, after adopting the functional combination scheme formulated in this article, the comprehensive investment benefits of ESPs have been improved. Moreover, the source side effect is at its best, with an efficiency value of 2.209. Full article
19 pages, 1652 KiB  
Review
Novel Insights into Postoperative Surveillance in Resected Pancreatic Cystic Neoplasms—A Review
by Daniel Vasile Balaban, Laura-Ioana Coman, Marina Balaban, Raluca Simona Costache and Mariana Jinga
Diagnostics 2024, 14(10), 1056; https://doi.org/10.3390/diagnostics14101056 (registering DOI) - 19 May 2024
Abstract
Pancreatic cystic lesions (PCL) are frequently encountered in clinical practice and some are referred to surgery due to their neoplastic risk or malignant transformation. The management of PCL involves complex decision-making, with postoperative surveillance being a key component for long-term outcomes, due to [...] Read more.
Pancreatic cystic lesions (PCL) are frequently encountered in clinical practice and some are referred to surgery due to their neoplastic risk or malignant transformation. The management of PCL involves complex decision-making, with postoperative surveillance being a key component for long-term outcomes, due to the potential for recurrence and postoperative morbidity. Unfortunately, the follow-up of resected patients is far from being optimal and there is a lack of consensus on recommendations with regard to timing and methods of surveillance. Here, we summarize the current knowledge on the postoperative surveillance of neoplastic pancreatic cysts, focusing on the mechanisms and risk factors for recurrence, the recurrence rates according to the initial indication for surgery, the final result of the surgical specimen and neoplastic risk in the remaining pancreas, as well as the postsurgical morbidity comprising pancreatic exocrine insufficiency, metabolic dysfunction and diabetes after resection, according to the type of surgery performed. We analyze postsurgical recurrence rates and morbidity profiles, as influenced by different surgical techniques, to better delineate at-risk patients, and highlight the need for tailored surveillance strategies adapted to preoperative and operative factors with an impact on outcomes. Full article
(This article belongs to the Special Issue Pancreas Diseases: Diagnosis and Management)
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19 pages, 12703 KiB  
Article
Predicting Impacts of Climate Change on Suitable Distribution of Critically Endangered Tree Species Yulania zenii (W. C. Cheng) D. L. Fu in China
by Haoran Wang, Feiyun Zhi and Guangfu Zhang
Forests 2024, 15(5), 883; https://doi.org/10.3390/f15050883 (registering DOI) - 19 May 2024
Abstract
The ancient Magnoliaceae family is being seriously threatened by climate change, especially for Yulania trees under threat. Little is currently understood regarding the appropriate geographic range of Yulania zenii, as well as how it has reacted to various climate situations from past [...] Read more.
The ancient Magnoliaceae family is being seriously threatened by climate change, especially for Yulania trees under threat. Little is currently understood regarding the appropriate geographic range of Yulania zenii, as well as how it has reacted to various climate situations from past to present. Here, we chose MaxEnt for final modeling after first using ten Biomod2 models to approximate its possible distribution in China. The findings indicated that the three main environmental parameters impacting its distribution were the monthly mean diurnal range of temperature, the precipitation seasonality of variation coefficient, and elevation. Currently, its appropriate distribution is primarily in southern Anhui, eastern Hunan, central Hubei, southern Jiangsu, and both northern Jiangxi and Zhejiang. The total suitable area of Y. zenii was found to be 14.68 × 104 km2, only taking up 1.53% of China’s total territory, which is larger than known. During the Last Interglacial and Middle Holocene, its suitable habitats were larger than they are currently, exhibiting a relatively continuous distribution. Under various future climate scenarios, its suitable habitats may averagely decrease by 20.26% compared with the current case, and these habitats may become more fragmented. Collectively, the centroid of Y. zenii is expected to migrate towards the southeast in the future. Therefore, our findings demonstrate, for the first time, that climate change has had an adverse effect on this species in terms of its distribution from the past to the current and into the future. Our study could contribute to the conservation, management, introduction, and cultivation of Y. zenii in China and provide a reference for other endangered Yulania species in this country under the conditions of climate change. Full article
(This article belongs to the Section Forest Ecology and Management)
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20 pages, 4617 KiB  
Article
Possible Factors of Poplar Susceptibility to Large Poplar Borer Infestation
by Valentyna Meshkova, Kateryna Zhupinska, Oleksandr Borysenko, Olga Zinchenko, Yuriy Skrylnyk and Natalia Vysotska
Forests 2024, 15(5), 882; https://doi.org/10.3390/f15050882 (registering DOI) - 19 May 2024
Abstract
Poplars (Populus spp.) are of significant ecological and economic importance. Long-term breeding efforts were aimed mainly at obtaining fast-growing and productive plants and less considered resistance to pests. This study aimed to identify patterns of susceptibility or resistance to Saperda carcharias (Linnaeus, [...] Read more.
Poplars (Populus spp.) are of significant ecological and economic importance. Long-term breeding efforts were aimed mainly at obtaining fast-growing and productive plants and less considered resistance to pests. This study aimed to identify patterns of susceptibility or resistance to Saperda carcharias (Linnaeus, 1758) (Coleoptera: Cerambycidae) infestation among clones of Populus hybrids and pure species, focusing on the influence of their placement, seasonal development, stem diameter, height increment, and crossing combinations. Among 34 clones of poplar species and hybrids of Ukrainian and foreign selection, in 2019–2023 S. carcharias infested 14 clones every year. Six clones (‘Ivantiivska’, ‘Kytaiska × pyramidalna’, ‘Volosystoplidna’, ‘Novoberlinska-3’, ‘Robusta’, and ‘Lada’) were the most susceptible to the infestation by S. carcharias. The clones of all presented poplar sections and their crossing combinations, except the Tacamahaca and Leucoides cross, were infested. Greater height increment promoted the infestation by S. carcharias. Ambiguous results were obtained regarding the susceptibility of Populus hybrids compared to pure species to S. carcharias infestations. Considering infestation by S. carcharias and plant placement in the site, it can be concluded that the clones ‘Sakrau45-51’, ‘Deltopodibna’, ‘Rosijska’, ‘Slava Ukrayiny’, ‘Lubenska’, ‘Rohanska’, and ‘Nocturne’ are resistant to this pest. Selecting native species clones or creating mixed clone plantations could enhance the resilience of poplar plantations to pest threats. Full article
(This article belongs to the Special Issue Forest Resistance to Insect Pests)
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19 pages, 5939 KiB  
Article
Antimicrobial Properties of Flavonoid Derivatives with Bromine, Chlorine, and Nitro Group Obtained by Chemical Synthesis and Biotransformation Studies
by Martyna Perz, Daria Szymanowska, Tomasz Janeczko and Edyta Kostrzewa-Susłow
Int. J. Mol. Sci. 2024, 25(10), 5540; https://doi.org/10.3390/ijms25105540 (registering DOI) - 19 May 2024
Abstract
The search for new substances of natural origin, such as flavonoids, is necessary in the fight against the growing number of diseases and bacterial resistance to antibiotics. In our research, we wanted to check the influence of flavonoids with chlorine or bromine atoms [...] Read more.
The search for new substances of natural origin, such as flavonoids, is necessary in the fight against the growing number of diseases and bacterial resistance to antibiotics. In our research, we wanted to check the influence of flavonoids with chlorine or bromine atoms and a nitro group on pathogenic and probiotic bacteria. We synthesized flavonoids using Claisen–Schmidt condensation and its modifications, and through biotransformation via entomopathogenic filamentous fungi, we obtained their glycoside derivatives. Biotransformation yielded two new flavonoid glycosides: 8-amino-6-chloroflavone 4′-O-β-D-(4″-O-methyl)-glucopyranoside and 6-bromo-8-nitroflavone 4′-O-β-D-(4″-O-methyl)-glucopyranoside. Subsequently, we checked the antimicrobial properties of the aforementioned aglycon flavonoid compounds against pathogenic and probiotic bacteria and yeast. Our studies revealed that flavones have superior inhibitory effects compared to chalcones and flavanones. Notably, 6-chloro-8-nitroflavone showed potent inhibitory activity against pathogenic bacteria. Conversely, flavanones 6-chloro-8-nitroflavanone and 6-bromo-8-nitroflavanone stimulated the growth of probiotic bacteria (Lactobacillus acidophilus and Pediococcus pentosaceus). Our research has shown that the presence of chlorine, bromine, and nitro groups has a significant effect on their antimicrobial properties. Full article
(This article belongs to the Special Issue New Research on Bioactive Natural Products)
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2 pages, 527 KiB  
Editorial
Editorial for the Special Issue “Recent Advances in Nanomaterials Science”
by Gang Ho Lee
Int. J. Mol. Sci. 2024, 25(10), 5541; https://doi.org/10.3390/ijms25105541 (registering DOI) - 19 May 2024
Abstract
Nanoparticles and nanomaterials are important, because they are potentially applicable to energy, storage, bioimaging, biosensors, catalysts, nanomedicine, batteries, solar energy, bioenergy, and so on (Figure 1) [...] Full article
(This article belongs to the Special Issue Recent Advances in Nanomaterials Science)
25 pages, 11824 KiB  
Article
Occurrence of Differences between Alkali and Alkaline Earth Metals (AAEMs), Including Sodium, Potassium, Calcium, and Magnesium, in the Maceral Groups of the Xiheishan Coal, Zhundong Coalfield, Xinjiang, China
by Kexin Che, Jiaxin Li, Qingfeng Lu, Fengjun Shao, Wenlong Wang, Wenfeng Wang and Xin He
Minerals 2024, 14(5), 525; https://doi.org/10.3390/min14050525 (registering DOI) - 19 May 2024
Abstract
This study investigated the differences and correlation between the occurrence characteristics of alkali and alkaline earth metals (AAEMs) among different maceral groups in high-alkali, high-inertinite coal, and provides scientific guidance for the co-separation of AAEMs and inertinite groups in Xinjiang coal. The total [...] Read more.
This study investigated the differences and correlation between the occurrence characteristics of alkali and alkaline earth metals (AAEMs) among different maceral groups in high-alkali, high-inertinite coal, and provides scientific guidance for the co-separation of AAEMs and inertinite groups in Xinjiang coal. The total AAEMs of inertinite-enriched samples were significantly higher than those in raw coals and vitrinite-enriched samples. Five-step sequential extraction showed that Na mainly occurs as water-soluble sodium (Na-Water) in raw coal and inertinite-enriched samples, accounting for about 53% of the total content, while it exists as organic sodium (Na-NH4Cl and Na-EDTA) in vitrinite-enriched samples, accounting for about 52% of the total content. Ca and Mg are both mainly present in organic form (Ca/Mg-NH4Cl and Ca/Mg-EDTA) in all the samples, with slightly higher proportions present in vitrinite-enriched samples. The contents of K are low in all the samples, which exist in an insoluble state (K-I). Combined microscopy and SEM-EDS analyses have revealed that the localized enrichment of Na in raw coal and inertinite-enriched samples occurs in the inertinite cell cavity, which primarily exists as NaHCO3 combined with quartz crystals, with a maximum content of up to 5.85 wt%. In this study, although EDS spectra could not directly characterize organic Ca and Mg, dolomite and calcite minerals were repeatedly found in the inertinite cell cavity. Moreover, the contents of Ca and Mg in the vitrinite-enriched samples were significantly lower than those in the other samples, which suggests that Ca and Mg are enriched with the inertinite groups. The localized enrichment of AAEMs could not be detected in any of the vitrinite-enriched samples. In summary, though there are significant differences between the occurrence modes of AAEMs in different maceral groups of high-alkali coal, AAEMs have a strong affinity with inertinite, which may be due to the inertinite’s abundant pore structures. Full article
(This article belongs to the Section Mineral Deposits)
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13 pages, 1829 KiB  
Review
Biosynthesis of Pteridines in Insects: A Review
by Juan Ferré
Insects 2024, 15(5), 370; https://doi.org/10.3390/insects15050370 (registering DOI) - 19 May 2024
Abstract
Pteridines are important cofactors for many biological functions of all living organisms, and they were first discovered as pigments of insects, mainly in butterfly wings and the eye and body colors of insects. Most of the information on their structures and biosynthesis has [...] Read more.
Pteridines are important cofactors for many biological functions of all living organisms, and they were first discovered as pigments of insects, mainly in butterfly wings and the eye and body colors of insects. Most of the information on their structures and biosynthesis has been obtained from studies with the model insects Drosophila melanogaster and the silkworm Bombyx mori. This review discusses, and integrates into one metabolic pathway, the different branches which lead to the synthesis of the red pigments “drosopterins”, the yellow pigments sepiapterin and sepialumazine, the orange pigment erythropterin and its related yellow metabolites (xanthopterin and 7-methyl-xanthopterin), the colorless compounds with violet fluorescence (isoxanthopterin and isoxantholumazine), and the branch leading to tetrahydrobiopterin, the essential cofactor for the synthesis of aromatic amino acids and biogenic amines. Full article
20 pages, 8443 KiB  
Article
A Rapid Localization Method Based on Super Resolution Magnetic Array Information for Unknown Number Magnetic Sources
by Linliang Miao, Tianyi Zhang, Chao Zuo, Zijie Chen, Xiaofei Yang and Jun Ouyang
Sensors 2024, 24(10), 3226; https://doi.org/10.3390/s24103226 (registering DOI) - 19 May 2024
Abstract
A rapid method that uses super-resolution magnetic array data is proposed to localize an unknown number of magnets in a magnetic array. A magnetic data super-resolution (SR) neural network was developed to improve the resolution of a magnetic sensor array. The approximate 3D [...] Read more.
A rapid method that uses super-resolution magnetic array data is proposed to localize an unknown number of magnets in a magnetic array. A magnetic data super-resolution (SR) neural network was developed to improve the resolution of a magnetic sensor array. The approximate 3D positions of multiple targets were then obtained based on the normalized source strength (NSS) and magnetic gradient tensor (MGT) inversion. Finally, refined inversion of the position and magnetic moment was performed using a trust region reflective algorithm (TRR). The effectiveness of the proposed method was examined using experimental field data collected from a magnetic sensor array. The experimental results showed that all the targets were successfully captured in multiple trials with three to five targets with an average positioning error of less than 3 mm and an average time of less than 300 ms. Full article
(This article belongs to the Special Issue Multi-Sensor Systems for Object Tracking—2nd Edition)
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18 pages, 3297 KiB  
Article
Investigations of In2O3 Added SiC Semiconductive Thin Films and Manufacture of a Heterojunction Diode
by Chia-Te Liao, Chia-Yang Kao, Zhi-Ting Su, Yu-Shan Lin, Yi-Wen Wang and Cheng-Fu Yang
Nanomaterials 2024, 14(10), 881; https://doi.org/10.3390/nano14100881 (registering DOI) - 19 May 2024
Abstract
This study involved direct doping of In2O3 into silicon carbide (SiC) powder, resulting in 8.0 at% In-doped SiC powder. Subsequently, heating at 500 °C was performed to form a target, followed by the utilization of electron beam (e-beam) technology to [...] Read more.
This study involved direct doping of In2O3 into silicon carbide (SiC) powder, resulting in 8.0 at% In-doped SiC powder. Subsequently, heating at 500 °C was performed to form a target, followed by the utilization of electron beam (e-beam) technology to deposit the In-doped SiC thin films with the thickness of approximately 189.8 nm. The first breakthrough of this research was the successful deposition of using e-beam technology. The second breakthrough involved utilizing various tools to analyze the physical and electrical properties of In-doped SiC thin films. Hall effect measurement was used to measure the resistivity, mobility, and carrier concentration and confirm its n-type semiconductor nature. The uniform dispersion of In ions in SiC was as confirmed by electron microscopy energy-dispersive spectroscopy and secondary ion mass spectrometry analyses. The Tauc Plot method was employed to determine the Eg values of pure SiC and In-doped SiC thin films. Semiconductor parameter analyzer was used to measure the conductivity and the I-V characteristics of devices in In-doped SiC thin films. Furthermore, the third finding demonstrated that In2O3-doped SiC thin films exhibited remarkable current density. X-ray photoelectron spectroscopy and Gaussian-resolved spectra further confirmed a significant relationship between conductivity and oxygen vacancy concentration. Lastly, depositing these In-doped SiC thin films onto p-type silicon substrates etched with buffered oxide etchant resulted in the formation of heterojunction p-n junction. This junction exhibited the rectifying characteristics of a diode, with sample current values in the vicinity of 102 mA, breakdown voltage at approximately −5.23 V, and open-circuit voltage around 1.56 V. This underscores the potential of In-doped SiC thin films for various semiconductor devices. Full article
(This article belongs to the Special Issue Advances in Wide-Bandgap Semiconductor Nanomaterials)
18 pages, 250 KiB  
Article
A New Materialist Analysis of Body Disaffection, Gender and Health and Fitness Social Media: ‘You Shouldn’t Compare Yourself to Anyone... but Everyone Does’
by Emma Rich
Youth 2024, 4(2), 700-717; https://doi.org/10.3390/youth4020047 (registering DOI) - 19 May 2024
Abstract
Recent research has documented the relationship between the promotion of ‘ideal’, ‘fit’ bodies in social media, body image and associated body concerns and conditions. This article expands this scholarship, focusing specifically on gender, body dissatisfaction and social media. Thus far, body disaffection has [...] Read more.
Recent research has documented the relationship between the promotion of ‘ideal’, ‘fit’ bodies in social media, body image and associated body concerns and conditions. This article expands this scholarship, focusing specifically on gender, body dissatisfaction and social media. Thus far, body disaffection has mostly been understood through a psychological framing, as a pathology residing within an individual and strongly associated with poor body image because of internalizing media images. In this paper, drawing on feminist new materialism, I offer a framing of body disaffection as a relational phenomenon. The paper draws on a mixed method study in England, with over 1000 young people examining their experiences with a range of digital health technologies. I focus specifically on their engagement with social media, to explore the relationship between ideal images and body concerns. Far from being a simple process of internalization of negative perceptions or image one has of their body, disaffection is formed through the body via a complex process of entanglement with social media and other elements. I outline how disaffection materialises as part of an assemblage of elements, including discourses, humans, bodies, digital objects and platforms. The paper reveals how entanglements with social media can generate powerful affects such as shame, pleasure and belonging along gendered lines, which may have significant implications for young people’s relationships with their bodies. I analyse how social media events focused on the ‘transformation’ of bodies generate powerful affects, which open or limit capacities for what ‘boys’ or ‘girls’ bodies might become in deeply gendered and sometimes harmful ways. Full article
(This article belongs to the Special Issue Body Image: Youth, Gender and Health)
14 pages, 5722 KiB  
Article
Cluster-Assisted Mesoplasma Chemical Vapor Deposition for Fast Epitaxial Growth of SiGe/Si Heterostructures: A Molecular Dynamics Simulation Study
by Wen-bo Wang, Wenfang Li, Ryoshi Ohta and Makoto Kambara
Materials 2024, 17(10), 2448; https://doi.org/10.3390/ma17102448 (registering DOI) - 19 May 2024
Abstract
Co-condensation of mixed SiGe nanoclusters and impingement of SiGe nanoclusters on a Si substrate were applied using molecular dynamics (MD) simulation in this study to mimic the fast epitaxial growth of SiGe/Si heterostructures under mesoplasma chemical vapor deposition (CVD) conditions. The condensation dynamics [...] Read more.
Co-condensation of mixed SiGe nanoclusters and impingement of SiGe nanoclusters on a Si substrate were applied using molecular dynamics (MD) simulation in this study to mimic the fast epitaxial growth of SiGe/Si heterostructures under mesoplasma chemical vapor deposition (CVD) conditions. The condensation dynamics and properties of the SiGe nanoclusters during the simulations were investigated first, and then the impingement of transient SiGe nanoclusters on both Si smooth and trench substrate surfaces under varying conditions was studied theoretically. The results show that the mixed nanoclusters as precursors demonstrate potential for enhancing epitaxial SiGe film growth at a high growth rate, owing to their loosely bound atomic structures and high mobility on the substrate surface. By varying cluster sizes and substrate temperatures, this study also reveals that smaller clusters and higher substrate temperatures contribute to faster structural ordering and smoother surface morphologies. Furthermore, the formed layers display a consistent SiGe composition, closely aligning with nominal values, and the cluster-assisted deposition method achieves the epitaxial bridging of heterostructures during cluster impingement, highlighting its additional distinctive characteristics. The implications of this work make it clear that the mechanism of fast alloyed epitaxial film growth by cluster-assisted mesoplasma CVD is critical for extending it as a versatile platform for synthesizing various epitaxial films. Full article
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3 pages, 155 KiB  
Editorial
The Recognition and Utilization of Natural Genetic Resources for Advances in Plant Biology through Genomics and Biotechnology
by Guofei Tan, Feng Que and Jian Zhang
Agronomy 2024, 14(5), 1076; https://doi.org/10.3390/agronomy14051076 (registering DOI) - 19 May 2024
Abstract
Biological diversity is the most essential gift from nature, and many elite or superior genes that confer favorable traits remain to be discovered and utilized [...] Full article
13 pages, 301 KiB  
Article
Exploring the Relationship of Anxiety and Depressive Symptoms and Impulsiveness with the Quality of Life of Older Patients with Cardiovascular Disease: A Cross-Sectional Study
by Giada Pietrabissa, Gloria Marchesi, Luca Alessandro Gondoni and Gianluca Castelnuovo
Int. J. Environ. Res. Public Health 2024, 21(5), 646; https://doi.org/10.3390/ijerph21050646 (registering DOI) - 19 May 2024
Abstract
Background: This study aimed to evaluate the relationship of selected clinical (i.e., body mass index, BMI) and psychological factors (i.e., anxiety, depression, and impulsiveness) with the quality of life (QoL) of elderly patients with cardiovascular disease (CVD) in a single clinical center in [...] Read more.
Background: This study aimed to evaluate the relationship of selected clinical (i.e., body mass index, BMI) and psychological factors (i.e., anxiety, depression, and impulsiveness) with the quality of life (QoL) of elderly patients with cardiovascular disease (CVD) in a single clinical center in Italy. Methods: A total of 238 patients of older age (≥65 years) with CVD who voluntarily attended a single clinical center for weight loss and cardiac rehabilitation were sequentially recruited and tested upon admission to the hospital based on pre-established inclusion criteria. Results: The findings indicated that anxiety and depressive symptoms were moderately associated with lower QoL. Additionally, there were noteworthy but minor negative connections between impulsivity and QoL. Furthermore, BMI was inversely associated with the perceived QoL of the participants, and when incorporated into the regression analysis, BMI alone significantly accounted for 11.8% of the variability in QoL. This percentage increased to 18.4% with the inclusion of impulsiveness in the model and further to 34.3% with the addition of anxiety and depressive symptoms. However, after introducing anxiety and depression, the association between impulsivity and QoL ceased to be statistically significant. Conclusions: Integrating the routine assessment and treatment of psychological factors into the care of older patients with CVD is important for optimizing their overall health outcomes and improving their QoL. Full article
15 pages, 3798 KiB  
Article
α-Catenin and Piezo1 Mediate Cell Mechanical Communication via Cell Adhesions
by Mingxing Ouyang, Qingyu Zhang, Yiming Zhu, Mingzhi Luo, Bing Bu and Linhong Deng
Biology 2024, 13(5), 357; https://doi.org/10.3390/biology13050357 (registering DOI) - 19 May 2024
Abstract
Cell-to-cell distant mechanical communication has been demonstrated using in vitro and in vivo models. However, the molecular mechanisms underlying long-range cell mechanoresponsive interactions remain to be fully elucidated. This study further examined the roles of α-Catenin and Piezo1 in traction force-induced rapid branch [...] Read more.
Cell-to-cell distant mechanical communication has been demonstrated using in vitro and in vivo models. However, the molecular mechanisms underlying long-range cell mechanoresponsive interactions remain to be fully elucidated. This study further examined the roles of α-Catenin and Piezo1 in traction force-induced rapid branch assembly of airway smooth muscle (ASM) cells on a Matrigel hydrogel containing type I collagen. Our findings demonstrated that siRNA-mediated downregulation of α-Catenin or Piezo1 expression or chemical inhibition of Piezo1 activity significantly reduced both directional cell movement and branch assembly. Regarding the role of N-cadherin in regulating branch assembly but not directional migration, our results further confirmed that siRNA-mediated downregulation of α-Catenin expression caused a marked reduction in focal adhesion formation, as assessed by focal Paxillin and Integrin α5 localization. These observations imply that mechanosensitive α-Catenin is involved in both cell–cell and cell-matrix adhesions. Additionally, Piezo1 partially localized to Paxillin in focal adhesions, which was inhibited by siRNA-mediated downregulation of α-Catenin expression. This result provides insights into the Piezo1-mediated mechanosensing of traction force on a hydrogel. Collectively, our findings highlight the significance of α-Catenin in the regulation of cell-matrix interactions and provide a possible interpretation of Piezo1-mediated mechanosensing activity at focal adhesions during cell–cell distant mechanical communication. Full article
(This article belongs to the Section Cell Biology)
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23 pages, 368 KiB  
Article
Specification of Self-Adaptive Privacy-Related Requirements within Cloud Computing Environments (CCE)
by Angeliki Kitsiou, Maria Sideri, Michail Pantelelis, Stavros Simou, Aikaterini-Georgia Mavroeidi, Katerina Vgena, Eleni Tzortzaki and Christos Kalloniatis
Sensors 2024, 24(10), 3227; https://doi.org/10.3390/s24103227 (registering DOI) - 19 May 2024
Abstract
This paper presents a novel approach to address the challenges of self-adaptive privacy in cloud computing environments (CCE). Under the Cloud-InSPiRe project, the aim is to provide an interdisciplinary framework and a beta-version tool for self-adaptive privacy design, effectively focusing on the integration [...] Read more.
This paper presents a novel approach to address the challenges of self-adaptive privacy in cloud computing environments (CCE). Under the Cloud-InSPiRe project, the aim is to provide an interdisciplinary framework and a beta-version tool for self-adaptive privacy design, effectively focusing on the integration of technical measures with social needs. To address that, a pilot taxonomy that aligns technical, infrastructural, and social requirements is proposed after two supplementary surveys that have been conducted, focusing on users’ privacy needs and developers’ perspectives on self-adaptive privacy. Through the integration of users’ social identity-based practices and developers’ insights, the taxonomy aims to provide clear guidance for developers, ensuring compliance with regulatory standards and fostering a user-centric approach to self-adaptive privacy design tailored to diverse user groups, ultimately enhancing satisfaction and confidence in cloud services. Full article
(This article belongs to the Section Sensor Networks)
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22 pages, 7400 KiB  
Article
Predictive Modeling for Microchannel Flow Boiling Heat Transfer under the Dual Effect of Gravity and Surface Modification
by Haoxian Wu, Shengnan Zhou, Dongwei Wang, Yunbo Yang, Linglin Liu, Huijie Mao and Bifen Shu
Processes 2024, 12(5), 1028; https://doi.org/10.3390/pr12051028 (registering DOI) - 19 May 2024
Abstract
This paper investigates the heat transfer performance of flow boiling in microchannels under the dual effect of gravity and surface modification through both experimental studies and mechanistic analysis. Utilizing a test bench with microchannels featuring surfaces of varying wettability levels and adjustable flow [...] Read more.
This paper investigates the heat transfer performance of flow boiling in microchannels under the dual effect of gravity and surface modification through both experimental studies and mechanistic analysis. Utilizing a test bench with microchannels featuring surfaces of varying wettability levels and adjustable flow directions, multiple experiments on R134-a flow boiling heat transfer under the effects of gravity and surface modification were conducted, resulting in 1220 sets of experimental data. The mass flux ranged from 735 kg/m2s to 1271 kg/m2s, and the heating heat flux density ranged from 9 × 103 W/m2 to 46 × 103 W/m2. The experimental results revealed the differences in the influence of different gravity and surface modification conditions on heat transfer performance. It was found that the heat transfer performance of super-hydrophilic surfaces in horizontal flow is optimal and more stable heat transfer performance is observed when gravity is aligned with the flow direction. And the impact of gravity and surface modification on heat transfer has been explained through mechanistic analysis. Therefore, two new dimensionless numbers, Fa and Conew, were introduced to characterize the dual effects of gravity and surface modification on heat transfer. A new heat transfer model was developed based on these effects, and the prediction error of the heat transfer coefficient was reduced by 12–15% compared to existing models, significantly improving the prediction accuracy and expanding its application scope. The applicability and accuracy of the new model were also validated with other experimental data. Full article
(This article belongs to the Section Energy Systems)
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25 pages, 395 KiB  
Article
Teamwork Conflict Management Training and Conflict Resolution Practice via Large Language Models
by Sakhi Aggrawal and Alejandra J. Magana
Future Internet 2024, 16(5), 177; https://doi.org/10.3390/fi16050177 (registering DOI) - 19 May 2024
Abstract
This study implements a conflict management training approach guided by principles of transformative learning and conflict management practice simulated via an LLM. Transformative learning is more effective when learners are engaged mentally and behaviorally in learning experiences. Correspondingly, the conflict management training approach [...] Read more.
This study implements a conflict management training approach guided by principles of transformative learning and conflict management practice simulated via an LLM. Transformative learning is more effective when learners are engaged mentally and behaviorally in learning experiences. Correspondingly, the conflict management training approach involved a three-step procedure consisting of a learning phase, a practice phase enabled by an LLM, and a reflection phase. Fifty-six students enrolled in a systems development course were exposed to the transformative learning approach to conflict management so they would be better prepared to address any potential conflicts within their teams as they approached a semester-long software development project. The study investigated the following: (1) How did the training and practice affect students’ level of confidence in addressing conflict? (2) Which conflict management styles did students use in the simulated practice? (3) Which strategies did students employ when engaging with the simulated conflict? The findings indicate that: (1) 65% of the students significantly increased in confidence in managing conflict by demonstrating collaborative, compromising, and accommodative approaches; (2) 26% of the students slightly increased in confidence by implementing collaborative and accommodative approaches; and (3) 9% of the students did not increase in confidence, as they were already confident in applying collaborative approaches. The three most frequently used strategies for managing conflict were identifying the root cause of the problem, actively listening, and being specific and objective in explaining their concerns. Full article
21 pages, 15320 KiB  
Article
Examining the Impacts of Pre-Fire Forest Conditions on Burn Severity Using Multiple Remote Sensing Platforms
by Kangsan Lee, Willem J. D. van Leeuwen, Jeffrey K. Gillan and Donald A. Falk
Remote Sens. 2024, 16(10), 1803; https://doi.org/10.3390/rs16101803 (registering DOI) - 19 May 2024
Abstract
Pre-fire environmental conditions play a critical role in wildfire severity. This study investigated the impact of pre-fire forest conditions on burn severity as a result of the 2020 Bighorn Fire in the Santa Catalina Mountains in Arizona. Using a stepwise regression model and [...] Read more.
Pre-fire environmental conditions play a critical role in wildfire severity. This study investigated the impact of pre-fire forest conditions on burn severity as a result of the 2020 Bighorn Fire in the Santa Catalina Mountains in Arizona. Using a stepwise regression model and remotely sensed data from Landsat 8 and LiDAR, we analyzed the effects of structural and functional vegetation traits and environmental factors on burn severity. This analysis revealed that the difference normalized burn ratio (dNBR) was a more reliable indicator of burn severity compared to the relative dNBR (RdNBR). Stepwise regression identified pre-fire normalized difference vegetation index (NDVI), canopy cover, and tree density as significant variables across all land cover types that explained burn severity, suggesting that denser areas with higher vegetation greenness experienced more severe burns. Interestingly, residuals between the actual and estimated dNBR were lower in herbaceous zones compared to denser forested areas at similar elevations, suggesting potentially more predictable burn severity in open areas. Spatial analysis using Geary’s C statistics further revealed a strong negative autocorrelation: areas with high burn severity tended to be clustered, with lower severity areas interspersed. Overall, this study demonstrates the potential of readily available remote sensing data to predict potential burn severity values before a fire event, providing valuable information for forest managers to develop strategies for mitigating future wildfire damage. Full article
(This article belongs to the Special Issue Vegetation Mapping through Multiscale Remote Sensing)
23 pages, 3543 KiB  
Article
Tracing the Origin and Magmatic Evolution of the Rejuvenated Volcanism in Santa Clara Island, Juan Fernández Ridge, SE Pacific
by Javier Reyes, Luis E. Lara, Vanessa Sutherland, Nicolás Aguirre, Carlos Orellana, Folkmar Hauff and Kaj Hoernle
Minerals 2024, 14(5), 524; https://doi.org/10.3390/min14050524 (registering DOI) - 19 May 2024
Abstract
Oceanic intraplate volcanoes sometimes experience late-stage eruptive activity known as rejuvenated volcanism, and contrasting interpretations for its petrogenesis depend on the compositional characteristics. In the Juan Fernández Ridge (JFR), a volcanic chain approximately 800 km in length emplaced on the Nazca Plate, some [...] Read more.
Oceanic intraplate volcanoes sometimes experience late-stage eruptive activity known as rejuvenated volcanism, and contrasting interpretations for its petrogenesis depend on the compositional characteristics. In the Juan Fernández Ridge (JFR), a volcanic chain approximately 800 km in length emplaced on the Nazca Plate, some subaerial occurrences of rejuvenated volcanism have been recognized on the Robinson Crusoe and Santa Clara Islands, both part of the same deeply eroded shield volcano complex. This study aims to understand the origin and magmatic evolution of rejuvenated volcanism on Santa Clara Island, emplaced after ~2.15 Ma of quiescence above the shield sequence, mainly via the analysis of unpublished geochemical and isotopic data. Field reconnaissance identified two nearly coeval rejuvenated sequences on Santa Clara Island: Bahía W (BW) and Morro Spartan (MS), both formed by basanitic and picro-basaltic lava flows with brecciated levels and local intercalations of sedimentary and pyroclastic deposits. In comparison to the chemical signature of the preceding shield-building stage (comprised mainly of basalts and picrites), the two rejuvenated sequences exhibit a notable enrichment in incompatible elements, but the Sr, Nd, and Pb isotopes are very similar to the FOZO mantle endmember, with an apparent additional contribution of HIMU and EM1 components. The geochemistry of lavas revealed the involvement of various processes, including contamination by ultramafic xenoliths, high-pressure fractional crystallization of olivine and clinopyroxene, and potential partial assimilation of oceanic lithospheric components. While the oceanic lithosphere has been considered as a potential source, the isotopic data from Santa Clara lies outside of the mixing curve between depleted mantle (DM, here represented by the North Chile Rise and the East Pacific Rise) and the previous shield stage, suggesting that a lithospheric mantle is not the primary source for the rejuvenated stage volcanism. Therefore, we favor an origin of the rejuvenated volcanism from the mantle plume forming the JFR, supported by similarities in isotopic signatures with the shield stage and high values of 208Pb/204Pb (only comparable to San Félix—San Ambrosio in the vicinity of JFR), implying the presence of a regional source with radiogenic 208Pb/204Pb isotope ratios. In addition, isotopic variations are subparallel to the mixing line between HIMU and EM1 components, whose participation in different proportions might explain the observed trends. In conclusion, we propose that the source of the rejuvenated volcanism on Santa Clara Island is a heterogeneous mantle plume, the same one that fed the shield stage. The rejuvenated volcanism is derived from a secondary melting zone away from the main axis of the plume. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
18 pages, 3331 KiB  
Article
Anionic Effect on Electrical Transport Properties of Solid Co2+/3+ Redox Mediators
by Ravindra Kumar Gupta, Ahamad Imran and Aslam Khan
Polymers 2024, 16(10), 1436; https://doi.org/10.3390/polym16101436 (registering DOI) - 19 May 2024
Abstract
In a solid-state dye-sensitized solar cell, a fast-ion conducting (σ25°C > 10−4 S cm−1) solid redox mediator (SRM; electrolyte) helps in fast dye regeneration and back-electron transfer inhibition. In this work, we synthesized solid Co2+/3+ redox mediators using [...] Read more.
In a solid-state dye-sensitized solar cell, a fast-ion conducting (σ25°C > 10−4 S cm−1) solid redox mediator (SRM; electrolyte) helps in fast dye regeneration and back-electron transfer inhibition. In this work, we synthesized solid Co2+/3+ redox mediators using a [(1 − x)succinonitrile: x poly(ethylene oxide)] matrix, LiX, Co(tris-2,2′-bipyridine)3(bis(trifluoromethyl) sulfonylimide)2, and Co(tris-2,2′-bipyridine)3(bis(trifluoromethyl) sulfonylimide)3 via the solution-cast method, and the results were compared with those of their acetonitrile-based liquid counterparts. The notation x is a weight fraction (=0, 0.5, and 1), and X represents an anion. The anion was either bis(trifluoromethyl) sulfonylimide [TFSI; ionic size, 0.79 nm] or trifluoromethanesulfonate [Triflate; ionic size, 0.44 nm]. The delocalized electrons and a low value of lattice energy for the anions made the lithium salts highly dissociable in the matrix. The electrolytes exhibited σ25°C ≈ 2.1 × 10−3(1.5 × 10−3), 7.2 × 10−4(3.1 ×× 10−4), and 9.7 × 10−7 (6.3 × 10−7) S cm−1 for x = 0, 0.5, and 1, respectively, with X = TFSI(Triflate) ions. The log σ–T−1 plot portrayed a linear curve for x = 0 and 1, and a downward curve for x = 0.5. The electrical transport study showed σ(TFSI) > σ(Triflate), with lower activation energy for TFSI ions. The anionic effect increased from x = 0 to 1. This effect was explained using conventional techniques, such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), UV–visible spectroscopy (UV-vis), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Full article
(This article belongs to the Special Issue Advanced Polymers for Solar Cells Applications)

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