The 2023 MDPI Annual Report has
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15 pages, 6665 KiB  
Article
The Effect of Apple Vinegar Addition on the Quality and Shelf Life of Cooked Sausage during Chilling Storage
by Anna Okoń, Dorota Zielińska, Piotr Szymański, Anna Łepecka, Urszula Siekierko, Katarzyna Neffe-Skocińska, Monika Trząskowska, Katarzyna Kajak-Siemaszko, Barbara Sionek, Marcelina Karbowiak, Danuta Kołożyn-Krajewska and Zbigniew J. Dolatowski
Appl. Sci. 2024, 14(10), 4027; https://doi.org/10.3390/app14104027 (registering DOI) - 9 May 2024
Abstract
As more and more consumers are becoming conscious of the safety and taste of meat products, the use of natural additives and innovative processing techniques has gained significant attention. Naturally fermented fruit vinegar is rich in organic acids and antioxidant phenolic compounds. In [...] Read more.
As more and more consumers are becoming conscious of the safety and taste of meat products, the use of natural additives and innovative processing techniques has gained significant attention. Naturally fermented fruit vinegar is rich in organic acids and antioxidant phenolic compounds. In addition, it contains amino acids, minerals, vitamins, and provitamin beta-carotene, and the presence of acetic acid bacteria may have a positive effect on consumer health. The study aimed to assess the impact of different concentrations of apple vinegar addition on the quality of cooked sausage, focusing on physicochemical parameters, including fatty acid profile and oxidative stability, as well as microbiological quality and sensory changes after production and during chilling storage. Four variants of sausage were prepared: C—sausage without apple vinegar; V1—sausage with 1% of apple vinegar; V3—sausage with 3% of apple vinegar; and V5—sausage with 5% of apple vinegar. All of the tests were carried out after production, as well as after 7 and 14 days of refrigeration storage. The addition of apple vinegar decreased the pH value and increased the oxidation-reduction potential and lipid oxidation in the samples V1, V3, and V5. The sausage with the 5% addition of apple vinegar (V5) was characterized by significantly more intensive brightness (parameter L* = 54.67) in comparison to the C sample (parameter L* = 52.78). The sausages that were tested showed good microbiological quality concerning the total number of microorganisms, lactic acid bacteria, and the absence of pathogenic bacteria. The addition of apple vinegar contributed to the reduction in the intensity of the cured meat flavor and the fatty flavor. Therefore, according to the results presented in this work, it can be concluded that 3% of vinegar is the optimal addition, which may be used in the next step of investigation, taking into account color formation abilities as well as microbiological quality and lipid oxidation processes. Full article
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11 pages, 1360 KiB  
Article
A Study on the Effect of New Surfactant Proportions on the Recovery Improvement of Carbonate Reservoir
by Pengfei Li and Mingyi Hu
Appl. Sci. 2024, 14(10), 4028; https://doi.org/10.3390/app14104028 (registering DOI) - 9 May 2024
Abstract
The strategy of integrating water injection and chemical additives in combining secondary and tertiary oil recovery techniques has been widely investigated in enhancing oil recovery efficiency. Nevertheless, there is a lack of sufficient evidence on the effectiveness of a mixture of cationic and [...] Read more.
The strategy of integrating water injection and chemical additives in combining secondary and tertiary oil recovery techniques has been widely investigated in enhancing oil recovery efficiency. Nevertheless, there is a lack of sufficient evidence on the effectiveness of a mixture of cationic and nonionic surfactants combined with water injection techniques in enhancing recovery in the application of carbonate reservoirs. Therefore, it is particularly critical to explore the impact of this combination strategy in enhancing recovery in fractured carbonate reservoirs. The recovery enhancement effect can be assessed by conducting phase behavior experiments and determining interfacial tension and contact angle. Further, the effectiveness of specific surfactant ration solutions in enhancing recovery can be verified by performing drive-off experiments. The results show that low mineralization water and surfactants have a significant synergistic effect in enhancing the recovery efficiency of carbonate reservoirs, with the optimal ratio of cationic to non-ionic surfactants being 2.5:1. The optimized surfactant ratio is able to increase the recovery of carbonate reservoirs by 20% compared to the original recovery rate. Full article
(This article belongs to the Section Earth Sciences)
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11 pages, 730 KiB  
Article
Evaluation of Gastroprotective Activity of the Methanolic Extract of Justicia pectoralis Jacq. (Acanthaceae)
by Ismael Aureliano Rosa Júnior, Dionys de Souza Almeida, Hamilton Barbosa Napolitano, Josana de Castro Peixoto, Lucimar Pinheiro Rosseto, Emerith Mayra Hungria Pinto, Lucas Danilo Dias, James Oluwagbamigbe Fajemiroye, Elson Alves Costa, Rodolfo P. Vieira and José Luis Rodrigues Martins
Nutrients 2024, 16(10), 1430; https://doi.org/10.3390/nu16101430 (registering DOI) - 9 May 2024
Abstract
Introduction: Justicia pectoralis Jacq. is traditionally applied in folk medicine in Brazil and in several Latin American countries. The leaves are used in tea form, especially in the treatment of respiratory disorders, acting as an expectorant. It also has activity in gastrointestinal disorders, [...] Read more.
Introduction: Justicia pectoralis Jacq. is traditionally applied in folk medicine in Brazil and in several Latin American countries. The leaves are used in tea form, especially in the treatment of respiratory disorders, acting as an expectorant. It also has activity in gastrointestinal disorders, and it is anti-inflammatory, antioxidant, sedative, and estrogenic, among others. Aims: To investigate the gastroprotective activity of the methanol extract of the leaves of Justicia pectoralis Jacq. (MEJP) in different experimental models of gastric ulcers. Materials and methods: The adult leaves of Justicia pectoralis Jacq. were collected and cultivated in beds, with an approximate spacing of 40 × 40 cm, organic fertilization, irrigation with potable water and without shelter from light. The MEJP was prepared from the dried and pulverized leaves and concentrated under reduced pressure in a rotary evaporator. For the experimental model of gastric ulcer, Swiss male albino mice were used. The inputs used in the experiment were MEJP at three different concentrations (250, 500 and 1000 mg/kg p.o.), cimetidine (50 mg/kg p.o.), indomethacin (50 mg/kg s.c.) and vehicle (10 mL/kg p.o.). Results: MEJP (250, 500 and 1000 mg/kg p.o.) demonstrated gastroprotective activity, with levels of protection of 45.65%, 44.80% and 40.22%, respectively, compared to the control (vehicle). Compared with cimetidine (48.29%), MEJP showed similar gastroprotective activity. Conclusions: This study demonstrated the gastroprotective activity of MEJP and contributes to validate the traditional use the species for gastric disorders and provides a pharmacological basis for its clinical potential. Full article
(This article belongs to the Special Issue Dietary Nutrition on Gastrointestinal Health)
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27 pages, 1645 KiB  
Article
Numerical Simulation and Modeling of Mechano–Electro–Thermal Behavior of Electrical Contact Using COMSOL Multiphysics
by Andrei Andras, Florin Dumitru Popescu, Sorin Mihai Radu, Dragos Pasculescu, Ildiko Brinas, Mirela Ancuta Radu and Daniela (Furdui) Peagu
Appl. Sci. 2024, 14(10), 4026; https://doi.org/10.3390/app14104026 (registering DOI) - 9 May 2024
Abstract
Electrical contacts are important circuit components with diverse industrial applications, and their failure can lead to multiple unwanted effects. Hence, the behavior of electrical contacts is a widely studied topic in the scientific literature based on various approaches, tools, and techniques. The present [...] Read more.
Electrical contacts are important circuit components with diverse industrial applications, and their failure can lead to multiple unwanted effects. Hence, the behavior of electrical contacts is a widely studied topic in the scientific literature based on various approaches, tools, and techniques. The present study proposes a new approach to numerical modeling and simulation based on the Holm contact theory, aiming to study the dependence between the electric potential and the temperature within an electrical contact. Structured in five sections, the research was conducted using COMSOL Multiphysics software and its solid-state mechanics, electric current, and heat transfer modules in order to highlight contact behavior from mechanical, electrical and thermal points of view: the von Mises stress, contact force, electric field amplitude, variation of the electrical potential along the current path, temperature gradient, and dependence of temperature along the contact elements edges were obtained by simulation, and are graphically represented. The results show that the temperature increase follows a parabolic curve, and that for values higher than 4 mV of voltage drop, the temperature of the contact increases to 79.25 degrees (and up to 123.81 degrees for 5 mV) over the ambient temperature, thus the integrity of insulation can be compromised. These values are close (10–12%) to the analytically calculated ones, and also in line with research assessed in the literature review. Full article
(This article belongs to the Special Issue Recent Studies on Optimization in Electric Energy Systems)
26 pages, 675 KiB  
Article
A Usable Encryption Solution for File-Based Geospatial Data within a Database File System
by Pankajeshwara Sharma, Michael Govorov and Michael Martin
J. Cybersecur. Priv. 2024, 4(2), 298-323; https://doi.org/10.3390/jcp4020015 (registering DOI) - 9 May 2024
Abstract
Developing a security solution for spatial files within today’s enterprise Geographical Information System (GIS) that is also usable presents a multifaceted challenge. These files exist in “data silos” of different file server types, resulting in limited collaboration and increased vulnerability. While cloud-based data [...] Read more.
Developing a security solution for spatial files within today’s enterprise Geographical Information System (GIS) that is also usable presents a multifaceted challenge. These files exist in “data silos” of different file server types, resulting in limited collaboration and increased vulnerability. While cloud-based data storage offers many benefits, the associated security concerns have limited its uptake in GIS, making it crucial to explore comparable alternative security solutions that can be deployed on-premise and are also usable. This paper introduces a reasonably usable security solution for spatial files within collaborative enterprise GIS. We explore a Database File System (DBFS) as a potential repository to consolidate and manage spatial files based on its enterprise document management capabilities and security features inherited from the underlying legacy DBMS. These files are protected using the Advanced Encryption Standard (AES) algorithm with practical encryption times of 8 MB per second. The final part focuses on an automated encryption solution with schemes for single- and multi-user files that is compatible with various GIS programs and protocol services. Usability testing is carried out to assess the solution’s usability and focuses on effectiveness, efficiency, and user satisfaction, with the results demonstrating its usability based on the minimal changes it makes to how users work in a collaborative enterprise GIS environment. The solution furnishes a viable means for consolidating and protecting spatial files with various formats at the storage layer within enterprise GIS. Full article
(This article belongs to the Special Issue Usable Security)
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25 pages, 6878 KiB  
Article
Improved Mechanical Performance in FDM Cellular Frame Structures through Partial Incorporation of Faces
by Mahan Ghosh and Nandika Anne D’Souza
Polymers 2024, 16(10), 1340; https://doi.org/10.3390/polym16101340 (registering DOI) - 9 May 2024
Abstract
The utilization of lattice-type cellular architectures has seen a significant increase, owing to their predictable shape and the ability to fabricate templated porous materials through low-cost 3D-printing methods. Frames based on atomic lattice structures such as face-centered cubic (FCC), body-centered cubic (BCC), or [...] Read more.
The utilization of lattice-type cellular architectures has seen a significant increase, owing to their predictable shape and the ability to fabricate templated porous materials through low-cost 3D-printing methods. Frames based on atomic lattice structures such as face-centered cubic (FCC), body-centered cubic (BCC), or simple cubic (SC) have been utilized. In FDM, the mechanical performance has been impeded by stress concentration at the nodes and melt-solidification interfaces arising from layer-by-layer deposition. Adding plates to the frames has resulted in improvements with a concurrent increase in weight and hot-pocket-induced dimensional impact in the closed cells formed. In this paper, we explore compressive performance from the partial addition of plates to the frames of a SC-BCC lattice. Compression testing of both single unit cells and 4 × 4 × 4 lattices in all three axial directions is conducted to examine stress transfer to the nearest neighbor and assess scale-up stress transfer. Our findings reveal that hybrid lattice structure unit cells exhibit significantly improved modulus in the range of 125% to 393%, specific modulus in the range of 13% to 120%, and energy absorption in the range of 17% to 395% over the open lattice. The scaled-up lattice modulus increased by 8% to 400%, specific modulus by 2% to 107%, and energy absorption by 37% to 553% over the lattice frame. Parameters that emerged as key to improved lightweighting. Full article
(This article belongs to the Section Polymer Applications)
12 pages, 1044 KiB  
Article
Entomopathogenic Fungi in Forest Habitats of Ixodes ricinus
by Dagmara Dyczko, Kinga Plewa-Tutaj and Dorota Kiewra
Insects 2024, 15(5), 341; https://doi.org/10.3390/insects15050341 (registering DOI) - 9 May 2024
Abstract
(1) Background: In addition to the microclimate, host availability, and tick microbiota, soil environmental microorganisms can affect tick populations. This study aimed to (1) determine the presence and diversity of entomopathogenic fungi (EF) in forests, where ticks are abundant, and (2) estimate the [...] Read more.
(1) Background: In addition to the microclimate, host availability, and tick microbiota, soil environmental microorganisms can affect tick populations. This study aimed to (1) determine the presence and diversity of entomopathogenic fungi (EF) in forests, where ticks are abundant, and (2) estimate the effectiveness of the isolated EF strains against Ixodes ricinus. (2) Methods: EF were isolated using the trap insect method from soil collected from tick sites. A bioassay was used to estimate the effectiveness of EF against ticks. (3) Results: The presence of EF was found in all tested forest habitat types. A total of 53 strains belonging to the genera Metarhizium, Beauveria, and Isaria were isolated. All the six strains subjected to the bioassay showed potential efficacy against both adult and nymphal stages of I. ricinus; however, the strains differed in their effectiveness. The most effective isolate against I. ricinus was the soil environmental strain of Metarhizium anisopliae. (4) Conclusion: The study indicates that tick habitats can be the source of entomopathogenic fungi, which have a lethal effect on ticks, as demonstrated in preliminary laboratory tests with I. ricinus. However, for practical use, extensive field tests and further research on application methods and long-term effects are necessary to develop effective and sustainable tick management strategies. Full article
(This article belongs to the Section Other Arthropods and General Topics)
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16 pages, 3437 KiB  
Article
Clustering of Wind Speed Time Series as a Tool for Wind Farm Diagnosis
by Ana Alexandra Martins, Daniel C. Vaz, Tiago A. N. Silva, Margarida Cardoso and Alda Carvalho
Math. Comput. Appl. 2024, 29(3), 35; https://doi.org/10.3390/mca29030035 (registering DOI) - 9 May 2024
Abstract
In several industrial fields, environmental and operational data are acquired with numerous purposes, potentially generating a huge quantity of data containing valuable information for management actions. This work proposes a methodology for clustering time series based on the K-medoids algorithm using a convex [...] Read more.
In several industrial fields, environmental and operational data are acquired with numerous purposes, potentially generating a huge quantity of data containing valuable information for management actions. This work proposes a methodology for clustering time series based on the K-medoids algorithm using a convex combination of different time series correlation metrics, the COMB distance. The multidimensional scaling procedure is used to enhance the visualization of the clustering results, and a matrix plot display is proposed as an efficient visualization tool to interpret the COMB distance components. This is a general-purpose methodology that is intended to ease time series interpretation; however, due to the relevance of the field, this study explores the clustering of time series judiciously collected from data of a wind farm located on a complex terrain. Using the COMB distance for wind speed time bands, clustering exposes operational similarities and dissimilarities among neighboring turbines which are influenced by the turbines’ relative positions and terrain features and regarding the direction of oncoming wind. In a significant number of cases, clustering does not coincide with the natural geographic grouping of the turbines. A novel representation of the contributing distances—the COMB distance matrix plot—provides a quick way to compare pairs of time bands (turbines) regarding various features. Full article
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23 pages, 3853 KiB  
Review
The Use of Spectroscopic Methods to Study Organic Matter in Virgin and Arable Soils: A Scoping Review
by Evgeny Lodygin and Evgeny Abakumov
Agronomy 2024, 14(5), 1003; https://doi.org/10.3390/agronomy14051003 (registering DOI) - 9 May 2024
Abstract
The use of modern spectroscopic methods of analysis, which provide extensive information on the chemical nature of substances, significantly expands our understanding of the molecular composition and properties of soil organic matter (SOM) and its transformation and stabilization processes in various ecosystems and [...] Read more.
The use of modern spectroscopic methods of analysis, which provide extensive information on the chemical nature of substances, significantly expands our understanding of the molecular composition and properties of soil organic matter (SOM) and its transformation and stabilization processes in various ecosystems and geochemical conditions. The aim of this review is to identify and analyze studies related to the application of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) spectroscopy techniques to study the molecular composition and transformation of organic matter in virgin and arable soils. This article is mainly based on three research questions: (1) Which NMR spectroscopy techniques are used to study SOM, and what are their disadvantages and advantages? (2) How is the NMR spectroscopy technique used to study the molecular structure of different pools of SOM? (3) How is ESR spectroscopy used in SOM chemistry, and what are its advantages and limitations? Relevant studies published between 1996 and 2024 were searched in four databases: eLIBRARY, MDPI, ScienceDirect and Springer. We excluded non-English-language articles, review articles, non-peer-reviewed articles and other non-article publications, as well as publications that were not available according to the search protocols. Exclusion criteria for articles were studies that used NMR and EPR techniques to study non-SOM and where these techniques were not the primary methods. Our scoping review found that both solid-state and solution-state NMR spectroscopy are commonly used to study the structure of soil organic matter (SOM). Solution-phase NMR is particularly useful for studying soluble SOM components of a low molecular weight, whereas solid-phase NMR offers advantages such as higher 13C atom concentration for stronger signals and faster analysis time. However, solution-phase NMR has limitations including sample insolubility, potential signal aggregation and reduced sensitivity and resolution. Solid-state NMR is better at detecting non-protonated carbon atoms and identifying heterogeneous regions within structures. EPR spectroscopy, on the other hand, offers significant advantages in experimental biochemistry due to its high sensitivity and ability to provide detailed information about substances containing free radicals (FRs), aiding in the assessment of their reactivity and transformations. Understanding the FR structure in biopolymers can help to study the formation and transformation of SOM. The integration of two- and three-dimensional NMR spectroscopy with other analytical methods, such as chromatography, mass spectrometry, etc., provides a more comprehensive approach to deciphering the complex composition of SOM than one-dimensional techniques alone. Full article
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26 pages, 1952 KiB  
Review
Prurigo Nodularis: Pathogenesis and the Horizon of Potential Therapeutics
by Hwa Jung Yook and Ji Hyun Lee
Int. J. Mol. Sci. 2024, 25(10), 5164; https://doi.org/10.3390/ijms25105164 (registering DOI) - 9 May 2024
Abstract
Chronic pruritus that lasts for over 6 weeks can present in various forms, like papules, nodules, and plaque types, with prurigo nodularis (PN) being the most prevalent. The pathogenesis of PN involves the dysregulation of immune cell–neural circuits and is associated with peripheral [...] Read more.
Chronic pruritus that lasts for over 6 weeks can present in various forms, like papules, nodules, and plaque types, with prurigo nodularis (PN) being the most prevalent. The pathogenesis of PN involves the dysregulation of immune cell–neural circuits and is associated with peripheral neuropathies, possibly due to chronic scratching. PN is a persistent and challenging condition, involving complex interactions among the skin, immune system, and nervous system. Lesional skin in PN exhibits the infiltration of diverse immune cells like T cells, eosinophils, macrophages, and mast cells, leading to the release of inflammatory cytokines and itch-inducing substances. Activated sensory nerve fibers aggravate pruritus by releasing neurotransmitters, perpetuating a vicious cycle of itching and scratching. Traditional treatments often fail, but recent advancements in understanding the inflammatory and itch transmission mechanisms of PN have paved the way for innovative therapeutic approaches, which are explored in this review. Full article
(This article belongs to the Special Issue Molecular Research Progress of Skin and Skin Diseases)
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16 pages, 7363 KiB  
Article
Sustainable Application of Pyrolytic Oxygen Furnace Slag in Cement-Stabilized Macadam: Volume Stability, Mechanical Properties, and Environmental Impact
by Dezhi Kong, Jiahui Zou, Meizhu Chen, Jun Xie and Xuanwen Gou
Sustainability 2024, 16(10), 3965; https://doi.org/10.3390/su16103965 (registering DOI) - 9 May 2024
Abstract
As an industrial waste, basic oxygen furnace (BOF) slag is an ideal substitute for natural rubble and sand. However, its potential instability of volume restricts the application of the BOF slag in engineering. This study aims at investigating the volume stability and mechanical [...] Read more.
As an industrial waste, basic oxygen furnace (BOF) slag is an ideal substitute for natural rubble and sand. However, its potential instability of volume restricts the application of the BOF slag in engineering. This study aims at investigating the volume stability and mechanical properties of BOF slag and its application as an aggregate in cement-stabilized macadam. As part of this research, the physicochemical properties, especially the volume stability, of two types of BOF slags and andesite were first studied. Then, mechanical properties, volume stability, and an environment analysis are used to evaluate the application of pyrolytic BOF slag in cement-stabilized macadam. The experimental results show that different types of BOF slags have similar thermal expansion coefficients, which are higher than andesite. The free CaO content of pyrolytic BOF slag is much lower than that of ordinary BOF slag and the volume expansion of pyrolytic BOF slag is less than 0.5%. The unconfined compressive strength (UCS) of cement-stabilized macadam using pyrolytic BOF slag is about 30% higher than that of andesite. Although the water loss rate is higher than a natural aggregate, dry shrinkage of pyrolytic BOF slag cement-stabilized macadam is about 30–50% less than that of a natural aggregate. Meanwhile, its shrinking speed is also slower than that of a natural aggregate. The micro-expansion properties of pyrolytic BOF slag could effectively partially offset the shrinkage characteristics of cement-stabilized macadam. Finally, the Toxicity Characteristic Leaching Procedure (TCLP) test results indicated that the metal leaching concentration meets the Chinese environmental standards. This study provides a direction for the large-scale and effective sustainable application of pyrolytic BOF slag. Full article
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13 pages, 6859 KiB  
Article
Effect of Sb Content on the Microstructure and Mechanical Properties of Eutectic SnPb Solder
by Xiuchen Zhao, Jiahui Chang, Xuefeng Wu, Zi-Ting Ye, Weiwei Chen and Xiaochen Xie
Materials 2024, 17(10), 2233; https://doi.org/10.3390/ma17102233 (registering DOI) - 9 May 2024
Abstract
SnPb solder was widely used in electronic packaging for aerospace devices due to its high reliability. However, its creep resistance is poor and can be improved by adding alloying elements. The effects of Sb content on the microstructure, tensile, and creep properties of [...] Read more.
SnPb solder was widely used in electronic packaging for aerospace devices due to its high reliability. However, its creep resistance is poor and can be improved by adding alloying elements. The effects of Sb content on the microstructure, tensile, and creep properties of eutectic SnPb solder were investigated. Sb addition effectively improved the mechanical properties of the SnPb solder. When Sb content exceeds 1.7 wt.%, SbSn intermetallic compounds (IMCs) occurred. And increasing the Sb content increased the tensile strength. Furthermore, Sb addition decreased the steady-state creep rate and increased the stress exponent n, suggesting that the creep resistance had been enhanced, which may be attributed to the hindrance of dislocation movement by SbSn IMCs, as well as the reduction in phase boundaries, which consequently reduced grain boundary sliding. Full article
(This article belongs to the Special Issue Physical Metallurgy of Metals and Alloys II)
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16 pages, 873 KiB  
Article
Evaluating the Sustainable Development Performance of China’s International Commercial Ports Based on Environmental, Social and Governance Elements
by Yan Zhang, Zihan Xin and Guoya Gan
Sustainability 2024, 16(10), 3968; https://doi.org/10.3390/su16103968 (registering DOI) - 9 May 2024
Abstract
An environmental, social and governance (ESG) evaluation system can focus on the value of enterprises more comprehensively and better scrutinize the development premise of enterprise. As a novel investment concept, both domestic and foreign investors widely acknowledge the significance of ESG. With the [...] Read more.
An environmental, social and governance (ESG) evaluation system can focus on the value of enterprises more comprehensively and better scrutinize the development premise of enterprise. As a novel investment concept, both domestic and foreign investors widely acknowledge the significance of ESG. With the implementation of “carbon peak”, “carbon neutral” and other national strategies, an increasing number of transportation enterprises in China’s international commercial ports have started to focus on the role of ESG evaluation. This not only facilitates self-examination and correction within enterprises but also helps in adjusting the strategic direction toward sustainable development. This shift toward ESG evaluation is crucial for promoting environmental sustainability and corporate social responsibility within the transportation industry. In this regard, this study aims to evaluate the sustainable development performance of China’s international commercial ports based on ESG elements. A data envelopment analysis (DEA) is considered to be a non-parametric performance evaluation method that can effectively solve for multi-criteria decision-making units, so this study mainly selects the DEA model for the performance evaluation. This study conducted research to select eight benchmarking companies within the industry and found that efficient units excelled in their ability to complete capacity levels with high quality and quantity at ports. In contrast, less efficient units scored lower in the domain of social responsibility. Full article
(This article belongs to the Special Issue Green Shipping and Sustainable Maritime Transport)
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17 pages, 5451 KiB  
Article
Chitin Deacetylase Homologous Gene cda Contributes to Development and Aflatoxin Synthesis in Aspergillus flavus
by Xin Zhang, Meifang Wen, Guoqi Li and Shihua Wang
Toxins 2024, 16(5), 217; https://doi.org/10.3390/toxins16050217 (registering DOI) - 9 May 2024
Abstract
The fungal cell wall serves as the primary interface between fungi and their external environment, providing protection and facilitating interactions with the surroundings. Chitin is a vital structural element in fungal cell wall. Chitin deacetylase (CDA) can transform chitin into chitosan through deacetylation, [...] Read more.
The fungal cell wall serves as the primary interface between fungi and their external environment, providing protection and facilitating interactions with the surroundings. Chitin is a vital structural element in fungal cell wall. Chitin deacetylase (CDA) can transform chitin into chitosan through deacetylation, providing various biological functions across fungal species. Although this modification is widespread in fungi, the biological functions of CDA enzymes in Aspergillus flavus remain largely unexplored. In this study, we aimed to investigate the biofunctions of the CDA family in A. flavus. The A. flavus genome contains six annotated putative chitin deacetylases. We constructed knockout strains targeting each member of the CDA family, including Δcda1, Δcda2, Δcda3, Δcda4, Δcda5, and Δcda6. Functional analyses revealed that the deletion of CDA family members neither significantly affects the chitin content nor exhibits the expected chitin deacetylation function in A. flavus. However, the Δcda6 strain displayed distinct phenotypic characteristics compared to the wild-type (WT), including an increased conidia count, decreased mycelium production, heightened aflatoxin production, and impaired seed colonization. Subcellular localization experiments indicated the cellular localization of CDA6 protein within the cell wall of A. flavus filaments. Moreover, our findings highlight the significance of the CBD1 and CBD2 structural domains in mediating the functional role of the CDA6 protein. Overall, we analyzed the gene functions of CDA family in A. flavus, which contribute to a deeper understanding of the mechanisms underlying aflatoxin contamination and lay the groundwork for potential biocontrol strategies targeting A. flavus. Full article
(This article belongs to the Special Issue Aspergillus flavus and Aflatoxins (Volume III))
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21 pages, 26199 KiB  
Article
Implementation of a Long Short-Term Memory Neural Network-Based Algorithm for Dynamic Obstacle Avoidance
by Esmeralda Mulás-Tejeda, Alfonso Gómez-Espinosa, Jesús Arturo Escobedo Cabello, Jose Antonio Cantoral-Ceballos and Alejandra Molina-Leal
Sensors 2024, 24(10), 3004; https://doi.org/10.3390/s24103004 (registering DOI) - 9 May 2024
Abstract
Autonomous mobile robots are essential to the industry, and human–robot interactions are becoming more common nowadays. These interactions require that the robots navigate scenarios with static and dynamic obstacles in a safely manner, avoiding collisions. This paper presents a physical implementation of a [...] Read more.
Autonomous mobile robots are essential to the industry, and human–robot interactions are becoming more common nowadays. These interactions require that the robots navigate scenarios with static and dynamic obstacles in a safely manner, avoiding collisions. This paper presents a physical implementation of a method for dynamic obstacle avoidance using a long short-term memory (LSTM) neural network that obtains information from the mobile robot’s LiDAR for it to be capable of navigating through scenarios with static and dynamic obstacles while avoiding collisions and reaching its goal. The model is implemented using a TurtleBot3 mobile robot within an OptiTrack motion capture (MoCap) system for obtaining its position at any given time. The user operates the robot through these scenarios, recording its LiDAR readings, target point, position inside the MoCap system, and its linear and angular velocities, all of which serve as the input for the LSTM network. The model is trained on data from multiple user-operated trajectories across five different scenarios, outputting the linear and angular velocities for the mobile robot. Physical experiments prove that the model is successful in allowing the mobile robot to reach the target point in each scenario while avoiding the dynamic obstacle, with a validation accuracy of 98.02%. Full article
(This article belongs to the Section Navigation and Positioning)
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26 pages, 4287 KiB  
Systematic Review
Strength and Durability Properties of High-Volume Fly Ash (HVFA) Binders: A Systematic Review
by Desire Runganga, Felix Okonta and Innocent Musonda
CivilEng 2024, 5(2), 435-460; https://doi.org/10.3390/civileng5020022 (registering DOI) - 9 May 2024
Abstract
South Africa is endowed with a wealth of coal-fired power stations that can produce extremely high volumes of fly ash per year exceeding 34 million tonnes. The use of high-volume fly ash (HVFA) binders in the construction sector has the capacity to significantly [...] Read more.
South Africa is endowed with a wealth of coal-fired power stations that can produce extremely high volumes of fly ash per year exceeding 34 million tonnes. The use of high-volume fly ash (HVFA) binders in the construction sector has the capacity to significantly reduce greenhouse gas emissions associated with traditional cement production and offset the carbon footprint of Eskom. The excessive production of fly ash by Eskom warrants the need for developing ultra-high-volume fly ash binders (UHVFA, fly ash/binder > 60 wt%). Nonetheless, fly ash (FA) replacement of cement is still largely limited to 35% regardless of more ambitious research indicating the potential to surpass 60%. In view of the urgent need for South Africa to offset and reduce its carbon footprint, this work reviews and summarises the literature on the performance of HVFA binders with a focus on two specific areas: (i) strength and (ii) durability. On HVFA binder strength, the focus is drawn on work that analysed the compressive strength, flexural strength, and split tensile strength. This review focuses on the extant literature analysing the durability of HVFA binders using various tests, including sorptivity, resistivity, permeability, tortuosity, rapid chloride penetration tests, resistance to sulphate attack, and microstructural analysis. As the FA content increases towards optima, i.e., 50–80%, the most indicative composite characteristics of the strength and durability properties are UCS (30–90 MPa) and permeability (low). This review reveals the leading methodologies, instrumentation, findings, challenges, and contradictions. Full article
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15 pages, 6401 KiB  
Article
Effects of Organic Fertilizer on Photosynthesis, Yield, and Quality of Pakchoi under Different Irrigation Conditions
by Shudong Lin, Kai Wei, Quanjiu Wang, Yan Sun, Mingjiang Deng and Wanghai Tao
Plants 2024, 13(10), 1308; https://doi.org/10.3390/plants13101308 (registering DOI) - 9 May 2024
Abstract
Water scarcity and the overuse of chemical fertilizers present significant challenges to modern agriculture, critically affecting crop photosynthesis, yield, quality, and productivity sustainability. This research assesses the impact of organic fertilizer on the photosynthetic attributes, yield, and quality of pakchoi under varying irrigation [...] Read more.
Water scarcity and the overuse of chemical fertilizers present significant challenges to modern agriculture, critically affecting crop photosynthesis, yield, quality, and productivity sustainability. This research assesses the impact of organic fertilizer on the photosynthetic attributes, yield, and quality of pakchoi under varying irrigation water conditions, including fresh water and brackish water. Findings reveal that the modified rectangular hyperbolic model most accurately captures the photosynthetic reaction to organic fertilization, outperforming other evaluated models. The maximum net photosynthesis rate (Pnmax), yield, soluble sugar (SS), and soluble protein content (SP) all exhibited a downward-opening quadratic parabolic trend with increasing amounts of organic fertilizer application. Specifically, under fresh-water irrigation, the optimal Pnmax, yield, SS, and SP were obtained at organic fertilizer rates of 65.77, 74.63, 45.33, and 40.79 kg/ha, respectively, achieving peak values of 20.71 µmol/(m2·s), 50,832 kg/ha, 35.63 g/kg, and 6.25 g/kg. This investigation provides a foundational basis for further research into the intricate relationship between water salinity stress and nutrient management, with the goal of crafting more sophisticated and sustainable farming methodologies. The insights gained could significantly influence organic fertilizer practices, promoting not only higher yields but also superior quality in agricultural outputs. Full article
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13 pages, 13204 KiB  
Article
Explorative Study on Volatile Organic Compounds of Cinnamon Based on GC-IMS
by Yu Pan, Liya Qiao, Shanshuo Liu, Ye He, Danna Huang, Wuwei Wu, Yingying Liu, Lu Chen and Dan Huang
Metabolites 2024, 14(5), 274; https://doi.org/10.3390/metabo14050274 (registering DOI) - 9 May 2024
Abstract
Cinnamon is one of the most popular spices worldwide, and volatile organic compounds (VOCs) are its main metabolic products. The misuse or mixing of cinnamon on the market is quite serious. This study used gas chromatography-ion migration spectroscopy (GC-IMS) technology to analyze the [...] Read more.
Cinnamon is one of the most popular spices worldwide, and volatile organic compounds (VOCs) are its main metabolic products. The misuse or mixing of cinnamon on the market is quite serious. This study used gas chromatography-ion migration spectroscopy (GC-IMS) technology to analyze the VOCs of cinnamon samples. The measurement results showed that 66 VOCs were detected in cinnamon, with terpenes being the main component accounting for 45.45%, followed by aldehydes accounting for 21.21%. The content of esters and aldehydes was higher in RG-01, RG-02, and RG-04; the content of alcohols was higher in RG-01; and the content of ketones was higher in RG-02. Principal component analysis, cluster analysis, and partial least squares regression analysis can be performed on the obtained data to clearly distinguish cinnamon. According to the VIP results of PLS-DA, 1-Hexanol, 2-heptanone, ethanol, and other substances are the main volatile substances that distinguish cinnamon. This study combined GC-IMS technology with chemometrics to accurately identify cinnamon samples, providing scientific guidance for the efficient utilization of cinnamon. At the same time, this study is of great significance for improving the relevant quality standards of spices and guiding the safe use of spices. Full article
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15 pages, 1772 KiB  
Article
Level of Agreement in Subjective Selection of Gingival Colour
by Cristina Gómez-Polo, Javier Montero, Norberto Quispe, Javier Flores-Fraile, Maria Portillo Muñoz and Ana María Martín Casado
Appl. Sci. 2024, 14(10), 4025; https://doi.org/10.3390/app14104025 (registering DOI) - 9 May 2024
Abstract
Background and Objectives: Primary outcome: To assess the level of agreement between the objective and subjective methods for recording gingival colour in each area of the gingiva. Secondary outcome: To compare performance of the subjective visual method of gingival colour selection by [...] Read more.
Background and Objectives: Primary outcome: To assess the level of agreement between the objective and subjective methods for recording gingival colour in each area of the gingiva. Secondary outcome: To compare performance of the subjective visual method of gingival colour selection by a male observer and a female observer. Materials and Methods: A chromatic study was conducted on a total of 101 participants, in five gingival zones, from the free gingival margin to the mucogingival line, using a SpectroShade Micro spectrophotometer for the objective method and 21 ad hoc ceramic gingival shade tabs for the subjective method. A man and a woman of the same age, with the same amount of clinical experience in dentistry, selected the tab that most resembled the colour of participants’ gingiva. The “chromatic error” was then assessed by calculating the colour difference (using the Euclidean and CIEDE2000 formulae) between the CIELAB coordinates of the shade tab selected and the objective coordinates of the gingiva. The unweighted Kappa coefficient was used to calculate the level of agreement between observers. Results: For the male observer, the mean chromatic errors varied between ΔEab* 10.3 and 13.1 units, while for the female observer, the mean errors varied between ΔEab* 11.1 and 12.8: these differences were not statistically significant. Similarly, no statistically significant differences were found between the mean chromatic errors for the five gingival zones in either the male operator (p = 0.100) or the female operator (p = 0.093). The minimum level of agreement (unweighted Kappa) between the observers ranged from 0.1 to 0.4. Conclusions: Subjective selection of gingival colour was very inaccurate, by both the male observer and the female observer, for any area of the gingiva, with no differences identified between them. The level of agreement between the observers was low. These findings suggest that gingival colour should not be determined using solely subjective methods, given that the chromatic errors significantly exceeded the clinical acceptability threshold for gingiva (4.1 units for ΔEab* and 2.9 units for ΔE00). Both observers showed a tendency to select gingival shade tabs that were redder and bluer than the objective colours. Full article
(This article belongs to the Section Applied Dentistry and Oral Sciences)
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16 pages, 3005 KiB  
Article
Synthesis of New Ruthenium Complexes and Their Exploratory Study as Polymer Hybrid Composites in Organic Electronics
by Ricardo Ballinas-Indilí, María Elena Sánchez Vergara, Saulo C. Rosales-Amezcua, Joaquín André Hernández Méndez, Byron López-Mayorga, René Miranda-Ruvalcaba and Cecilio Álvarez-Toledano
Polymers 2024, 16(10), 1338; https://doi.org/10.3390/polym16101338 (registering DOI) - 9 May 2024
Abstract
Polymeric hybrid films, for their application in organic electronics, were produced from new ruthenium indanones in poly(methyl methacrylate) (PMMA) by the drop-casting procedure. Initially, the synthesis and structural characterization of the ruthenium complexes were performed, and subsequently, their properties as a potential semiconductor [...] Read more.
Polymeric hybrid films, for their application in organic electronics, were produced from new ruthenium indanones in poly(methyl methacrylate) (PMMA) by the drop-casting procedure. Initially, the synthesis and structural characterization of the ruthenium complexes were performed, and subsequently, their properties as a potential semiconductor material were explored. Hence hybrid films in ruthenium complexes were deposited using PMMA as a polymeric matrix. The hybrid films were characterized by infrared spectrophotometry and atomic force microscopy. The obtained results confirmed that the presence of the ruthenium complexes enhanced the mechanical properties in addition to increasing the transmittance, favoring the determination of their optical parameters. Both hybrid films exhibited a maximum stress around 10.5 MPa and a Knoop hardness between 2.1 and 18.4. Regarding the optical parameters, the maximum transparency was obtained at wavelengths greater than 590 nm, the optical band gap was in the range of 1.73–2.24 eV, while the Tauc band gap was in the range of 1.68–2.17 eV, and the Urbach energy was between 0.29 and 0.50 eV. Consequently, the above comments are indicative of an adequate semiconductor behavior; hence, the target polymeric hybrid films must be welcomed as convenient candidates as active layers or transparent electrodes in organic electronics. Full article
(This article belongs to the Special Issue Polymer-Based Hybrid Composites II)
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8 pages, 809 KiB  
Communication
Chlorate and Trichloromethane Residues in Bulk Tank Milk Produced in the Republic of Ireland before and after Chlorine was Prohibited as a Cleaning Agent on Farms
by Lorna Twomey, Ambrose Furey, Bernadette O’Brien, Tom Beresford, Paula Reid, Martin Danaher and David Gleeson
Dairy 2024, 5(2), 287-294; https://doi.org/10.3390/dairy5020023 (registering DOI) - 9 May 2024
Abstract
In an effort to reduce the occurrence of chlorine derived residues such as chlorate and trichloromethane (TCM) in milk and ultimately in dairy products, ‘chlorine-free’ cleaning of milking equipment became compulsory in the Republic of Ireland (ROI) from January 2021. While data exists [...] Read more.
In an effort to reduce the occurrence of chlorine derived residues such as chlorate and trichloromethane (TCM) in milk and ultimately in dairy products, ‘chlorine-free’ cleaning of milking equipment became compulsory in the Republic of Ireland (ROI) from January 2021. While data exists on TCM levels in bulk tank milk, little is known about the prominence and typical levels (mg/kg) of chlorate residue in bulk tank milk. To address this, 3625 bulk milk samples were collected from six milk processors and were analysed for chlorate and TCM residues across 2020 and 2021, with 2020 representing a period before chlorine-free cleaning was introduced and 2021 being the period after chlorine removal. In 2020, 15% of the samples analysed had detectable levels of chlorate (0.0020–1.6 mg/kg), but this reduced to 8% in 2021 (0.0020–3.9 mg/kg), following the introduction of ‘chlorine-free’ cleaning. Chlorate and TCM residues have not been totally eliminated because sources of residue other than cleaning chemicals exist, i.e., chlorinated water. Full article
(This article belongs to the Section Dairy Microbiota)
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17 pages, 5460 KiB  
Article
Transient Temperature at Tool–Chip Interface during Initial Period of Chip Formation in Orthogonal Cutting of Inconel 718
by Youssef Alammari, Jian Weng, Jannis Saelzer and Dirk Biermann
Materials 2024, 17(10), 2232; https://doi.org/10.3390/ma17102232 (registering DOI) - 9 May 2024
Abstract
Machining nickel-based super alloys such as Inconel 718 generates a high thermal load induced via friction and plastic deformation, causing these alloys to be among most difficult-to-cut materials. Localized heat generation occurring in machining induces high temperature gradients. Experimental techniques for determining cutting [...] Read more.
Machining nickel-based super alloys such as Inconel 718 generates a high thermal load induced via friction and plastic deformation, causing these alloys to be among most difficult-to-cut materials. Localized heat generation occurring in machining induces high temperature gradients. Experimental techniques for determining cutting tool temperature are challenging due to the small dimensions of the heat source and the chips produced, making it difficult to observe the tool–chip interface. Therefore, theoretical analysis of cutting temperatures is crucial for understanding heat generation and temperature distribution during cutting operations. Periodic heating and cooling occurring during cutting and interruption, respectively, are modeled using a hybrid analytical and finite element (FE) transient thermal model. In addition to identifying a transition distance associated with initial period of chip formation (IPCF) from apparent coefficient of friction results using a sigmoid function, the transition temperature is also identified using the thermal model. The model is validated experimentally by measuring the tool–chip interface temperature using a two-color pyrometer at a specific cutting distance. Due to the cyclic behavior in interrupted cutting, where a steady-state condition may or may not be achieved, transient thermal modeling is required in this case. Input parameters required to identify the heat flux for the transient thermal model are obtained experimentally and the definitions of heat-flux-reducing factors along the cutting path are associated with interruptions and the repeating IPCF. The thermal model consists of two main parts: one is related to identifying the heat flux, and the other part involves the determination of the temperature field within the tool using a partial differential equation (PDE) solved numerically via a 2D finite element method. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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16 pages, 861 KiB  
Article
The Impact of Sugarcane By-Product Exports on Income Inequality: How Sustainable Is This Relationship?
by Thiago Vizine Da Cruz and Ricardo Luiz Machado
Sustainability 2024, 16(10), 3966; https://doi.org/10.3390/su16103966 (registering DOI) - 9 May 2024
Abstract
The reduction in income inequality and its convergence between localities is one of the aims of the United Nations Sustainable Development Goals. This work aims to contribute to the theme, researching the relationship among international trade, the export of sugarcane by-products, and income [...] Read more.
The reduction in income inequality and its convergence between localities is one of the aims of the United Nations Sustainable Development Goals. This work aims to contribute to the theme, researching the relationship among international trade, the export of sugarcane by-products, and income inequality. A panel data regression was performed for a group of 98 cities from the state of Goiás-Brazil. Results indicate that international trade has a minimal, though positive effect, reducing income inequality. Nevertheless, the export of sugarcane by-product results indicates a harmful effect on workers’ income in the poorest cities who work in the agricultural sector. The results indicate that international trade contributes to sustainable development by generating wealth, contributing to UN SDG number 1, and reducing income inequality, helping to achieve UN SDG number 10. Full article
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