The 2023 MDPI Annual Report has
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11 pages, 2163 KiB  
Article
Study on Carbon Stock and Sequestration Potential of Typical Grasslands in Northern China: A Case Study of Wuchuan County
by Fan Gao, Zhen Tian, Yanzhe Wang, Zhiheng Yang and Guodong Ding
Sustainability 2024, 16(10), 4053; https://doi.org/10.3390/su16104053 (registering DOI) - 13 May 2024
Abstract
Grasslands in China cover an extensive area and rank second globally. They constitute the second-largest carbon reservoir in China after forests, holding about 8% of the total carbon stock of the world’s grassland ecosystems. This study focuses on the grasslands of Wuchuan County, [...] Read more.
Grasslands in China cover an extensive area and rank second globally. They constitute the second-largest carbon reservoir in China after forests, holding about 8% of the total carbon stock of the world’s grassland ecosystems. This study focuses on the grasslands of Wuchuan County, Inner Mongolia Autonomous Region of Northern China. This study compares the carbon stock and density characteristics across different communities based on plot survey and GIS vector data. It also anticipates the region’s carbon sequestration potential using biomass-to-carbon conversion and extrapolation methods. The findings indicate that (1) the total carbon stock in the study area is 1805.65 × 104 tons with an average carbon density of 77.50 t/ha. The distribution of carbon density and stock follows a pattern: soil layer > herbaceous layer > litter layer; (2) the Stipa krylovii + Leymus chinensis community exhibits the highest carbon stock and density; (3) there is a positive correlation between herbaceous carbon density and NPP (Net Primary Productivity) values in the study area; and (4) the overall carbon stock in the region is projected to increase, with growth rates accelerating annually. These results contribute to our understanding of the formation, turnover, stability maintenance, and regulation mechanisms of grassland soil organic carbon. Furthermore, they hold significant implications for enhancing the carbon sequestration capacity of ecosystems. Full article
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22 pages, 305 KiB  
Article
On the Foundation Period of the Maronite Tradition
by Joseph Azize
Religions 2024, 15(5), 596; https://doi.org/10.3390/rel15050596 (registering DOI) - 13 May 2024
Abstract
The Maronite Church states that it is an Antiochene and Syriac Church. This article traces, in chronological and discursive fashion, the emergence of the Maronite tradition. It explores the life and significance of St Maroun (d. ca AD 418–23), giving consideration to thinkers [...] Read more.
The Maronite Church states that it is an Antiochene and Syriac Church. This article traces, in chronological and discursive fashion, the emergence of the Maronite tradition. It explores the life and significance of St Maroun (d. ca AD 418–23), giving consideration to thinkers who helped to understand his outlook and methods and assessing what we know of the St Maroun monastery (Dayr Mar Maroun) and its vicissitudes down to the sixth century. The piece then treats Maronites in the context of the seventh-century monothelite controversy, following their foundational developments up to the time of their first patriarch Yohanna Maroun (flor. 680s). The paper considers not only the ascetic and monastic currents in the early Maronite community but also touches on the influence of Syriac typology and its gradual displacement by analytic and dogmatic theology. Full article
(This article belongs to the Special Issue Patristics: Essays from Australia)
11 pages, 6055 KiB  
Article
Miniaturized and High Volumetric Energy Density Power Supply Device Based on a Broad-Frequency Vibration Driven Triboelectric Nanogenerator
by Liting Wu, Zewei Ren, Yanjun Wang, Yumin Tang, Zhong Lin Wang and Rusen Yang
Micromachines 2024, 15(5), 645; https://doi.org/10.3390/mi15050645 (registering DOI) - 13 May 2024
Abstract
The widespread vibration is one of the most promising energy sources for IoT and small sensors, and broad-frequency vibration energy harvesting is important. Triboelectric nanogenerators (TENGs) can convert vibration energy into electrical energy through triboelectricity and electrostatic induction, providing an effective solution to [...] Read more.
The widespread vibration is one of the most promising energy sources for IoT and small sensors, and broad-frequency vibration energy harvesting is important. Triboelectric nanogenerators (TENGs) can convert vibration energy into electrical energy through triboelectricity and electrostatic induction, providing an effective solution to the collection of broad-frequency vibration energy. Also, the power supply in constrained and compact spaces has been a long-standing challenge. Here, a miniaturized power supply (MPS) based on a broad-frequency vibration-driven triboelectric nanogenerator (TENG) is developed. The size of the MPS is 38 mm × 26 mm × 20 mm, which can adapt to most space-limited environments. The TENG device is optimized through theoretical mechanical modeling for the external stimuli, it can efficiently harvest vibrational energy in the frequency range of 1–100 Hz and has a high output power density of 134.11 W/cm3. The developed device demonstrates its practical application potential in powering small electronics like LEDs, watches, and timers. Full article
(This article belongs to the Special Issue Emerging Applications of Triboelectric Effects/Materials)
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14 pages, 1548 KiB  
Article
Assessing Sodium Intake in Middle-Aged and Older Adults with Elevated Blood Pressure: Validation of Spot Urine Excretion and Dietary Survey-Derived Estimates
by Yee Chang Soh, Andrea Fairley, Mawada Alawad, Siew Siew Lee, Tin Tin Su, Blossom Christa Maree Stephan, Daniel Reidpath, Louise Robinson, Shajahan Yasin, Mario Siervo and Devi Mohan
Nutrients 2024, 16(10), 1461; https://doi.org/10.3390/nu16101461 (registering DOI) - 13 May 2024
Abstract
This cross-sectional study evaluated the validity of three alternative methods compared to the gold standard 24-h urine collection for estimating dietary sodium intake, a modifiable risk factor for hypertension, among middle-aged and older adults with elevated blood pressure. These included spot urine collection [...] Read more.
This cross-sectional study evaluated the validity of three alternative methods compared to the gold standard 24-h urine collection for estimating dietary sodium intake, a modifiable risk factor for hypertension, among middle-aged and older adults with elevated blood pressure. These included spot urine collection (using Kawasaki, Tanaka, and INTERSALT equations), 24-h dietary recall, and food frequency questionnaire responses, compared to 24-h urine collection in a subset of 65 participants (aged 50–75 years, 58.5% women, 61.6% hypertensive) from the DePEC-Nutrition trial. The validity of the methods was assessed using bias, the Spearman correlation coefficient (SCC), the intraclass correlation coefficient (ICC), and Bland–Altman analysis. Among the alternative methods, spot urine collection using the Kawasaki equation showed the strongest correlation (SCC 0.238; ICC 0.119, 95% CI −0.079 to 0.323), but it exhibited a significant bias (1414 mg/day, p-value < 0.001) relative to 24-h urine collection. Conversely, dietary surveys had a smaller bias but wider limits of agreement. These findings underscore the complexities of accurately estimating dietary sodium intake using spot urine collection or dietary surveys in this specific population, suggesting that a combination or the refinement of existing methodologies might improve accuracy. Further research with larger samples is necessary to develop more reliable methods for assessing sodium intake in this high-risk group. Full article
(This article belongs to the Section Nutrition Methodology & Assessment)
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17 pages, 3673 KiB  
Article
Technological Analysis of the Production of Nickel-Containing Composite Materials
by Bauyrzhan Kelamanov, Dauren Yessengaliyev, Otegen Sariev, Askhat Akuov, Yerulan Samuratov, Talgat Zhuniskaliyev, Yerbol Kuatbay, Yerbol Mukhambetgaliyev, Olga Kolesnikova, Assel Zhumatova, Zukhra Karaidarova and Assylbek Abdirashit
J. Compos. Sci. 2024, 8(5), 179; https://doi.org/10.3390/jcs8050179 (registering DOI) - 12 May 2024
Abstract
The article presents the results of obtaining a composite material by sintering nickel-containing raw materials mixed with carbon-containing materials, namely using coke and semi-coke. The sintering process was performed at a charge layer height of 240 mm and the temperature of the lower [...] Read more.
The article presents the results of obtaining a composite material by sintering nickel-containing raw materials mixed with carbon-containing materials, namely using coke and semi-coke. The sintering process was performed at a charge layer height of 240 mm and the temperature of the lower layer was T = 1200 °C. The results of the sieve analysis showed (a fraction of 10 mm) that the yield of a suitable composite material using coke was 68.3% and with semi-coke 67.0%. The average nickel and chromium content in the composite materials was 1.42% and 3.07%, accordingly. As a result of determining the strength characteristics of the obtained composite materials with various reducing agents by dropping from a height of 2 m onto a steel pallet, it was found that the obtained composite materials have high mechanical properties in terms of strength of 81% and 89.2%. The results of the elemental composition at the studied points and the thermal analysis of the studied composite material are presented. The mineralogical composition of the composite material is presented in the form of serpentine and nontronite, and the empty rock is made of quartz and talc. The activation energy of thermal analysis by the method of non-isothermal kinetics were calculated. The results of experiments on the production of composite materials from nickel-containing raw materials will be recommended for obtaining the optimal composition of composite materials at the stage of pilot tests and industrial development of the developed technology for processing nickel ores of the Republic of Kazakhstan. For the processing of nickel-poor nickel ores, it is of great importance to obtain optimal technological and technical and economic indicators that ensure low cost of nickel in the resulting product. Full article
(This article belongs to the Special Issue Metal Composites, Volume II)
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20 pages, 1225 KiB  
Article
Towards Multi-Objective Object Push-Grasp Policy Based on Maximum Entropy Deep Reinforcement Learning under Sparse Rewards
by Tengteng Zhang and Hongwei Mo
Entropy 2024, 26(5), 416; https://doi.org/10.3390/e26050416 (registering DOI) - 12 May 2024
Abstract
In unstructured environments, robots need to deal with a wide variety of objects with diverse shapes, and often, the instances of these objects are unknown. Traditional methods rely on training with large-scale labeled data, but in environments with continuous and high-dimensional state spaces, [...] Read more.
In unstructured environments, robots need to deal with a wide variety of objects with diverse shapes, and often, the instances of these objects are unknown. Traditional methods rely on training with large-scale labeled data, but in environments with continuous and high-dimensional state spaces, the data become sparse, leading to weak generalization ability of the trained models when transferred to real-world applications. To address this challenge, we present an innovative maximum entropy Deep Q-Network (ME-DQN), which leverages an attention mechanism. The framework solves complex and sparse reward tasks through probabilistic reasoning while eliminating the trouble of adjusting hyper-parameters. This approach aims to merge the robust feature extraction capabilities of Fully Convolutional Networks (FCNs) with the efficient feature selection of the attention mechanism across diverse task scenarios. By integrating an advantage function with the reasoning and decision-making of deep reinforcement learning, ME-DQN propels the frontier of robotic grasping and expands the boundaries of intelligent perception and grasping decision-making in unstructured environments. Our simulations demonstrate a remarkable grasping success rate of 91.6%, while maintaining excellent generalization performance in the real world. Full article
34 pages, 1666 KiB  
Article
New Accomplishments on the Equivalence of the First-Order Displacement-Based Zigzag Theories through a Unified Formulation
by Marco Di Sciuva and Matteo Sorrenti
J. Compos. Sci. 2024, 8(5), 181; https://doi.org/10.3390/jcs8050181 (registering DOI) - 12 May 2024
Abstract
The paper presents a critical review and new accomplishments on the equivalence of the first-order displacement-based zigzag theories for laminated composite and sandwich structures. Zigzag theories (ZZTs) have widely spread among researchers over the last few decades thanks to their accuracy in predicting [...] Read more.
The paper presents a critical review and new accomplishments on the equivalence of the first-order displacement-based zigzag theories for laminated composite and sandwich structures. Zigzag theories (ZZTs) have widely spread among researchers over the last few decades thanks to their accuracy in predicting the response of multilayered composite and sandwich structures while retaining the simplicity of their underlying equivalent single-layer (ESL) theory. The displacement field consists of two main contributions: the global one, able to describe the overall structural behaviour, and the local layer-wise one that considers the transverse shear continuity at the layer interfaces that describe the “zigzag” displacement pattern typical of multilayered structures. In the framework of displacement-based linear ZZTs, various assumptions have been made on the local contribution, and different theories have been deduced. This paper aims to provide a unified formulation for first-order ZZTs, highlighting some common aspects and underlying equivalencies with existing formulations. The mathematical demonstrations and the numerical examples prove the equivalence of the approaches to characterising local zigzag enrichment. Finally, it is demonstrated that the kinematic assumptions are the discriminants of the ZZTs’ accuracy. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2024)
17 pages, 1846 KiB  
Article
Experimental Evaluation of a Takagi–Sugeno Fuzzy Controller for an EV3 Ballbot System
by Rodolfo Enemegio, Francisco Jurado and Jonathan Villanueva-Tavira
Appl. Sci. 2024, 14(10), 4103; https://doi.org/10.3390/app14104103 (registering DOI) - 12 May 2024
Abstract
In this paper, experimental results about the performance of a Takagi–Sugeno Fuzzy Controller (TSFC) for an EV3 Ballbot Robotic System (EV3BRS) are reported. The physical configuration of the EV3BRS has the form of an inverted pendulum mounted on a ball. The EV3BRS is [...] Read more.
In this paper, experimental results about the performance of a Takagi–Sugeno Fuzzy Controller (TSFC) for an EV3 Ballbot Robotic System (EV3BRS) are reported. The physical configuration of the EV3BRS has the form of an inverted pendulum mounted on a ball. The EV3BRS is an underactuated robotic system with four outputs and two control torques. In this work, following the Takagi–Sugeno (TS) fuzzy control design methodology, the Parallel Distributed Compensation (PDC) approach is used in the design of the TSFC. The EV3BRS’s TS Fuzzy Model (TSFM) design comes from linearization of the nonlinear model around two operation points near the upright position of EV3BRS’s body. The Linear Matrix Inequality (LMI) approach was used to obtain the feedback gains for every local linear controller, guaranteeing, via a conservative stability condition, the global asymptotic stability of the overall fuzzy control system. The main goal of the control task consists of maintaining the EV3BRS’s body at its upright position. Measurement and control data from and to the EV3BRS are transferred via telecontrol and telemetry. The appropriate performance of the controller design is corroborated via experimentation. Full article
(This article belongs to the Special Issue Advanced Electronics and Digital Signal Processing)
8 pages, 225 KiB  
Article
A Blow-Up Criterion for the Density-Dependent Incompressible Magnetohydrodynamic System with Zero Viscosity
by Kunlong Shi, Jishan Fan and Gen Nakamura
Mathematics 2024, 12(10), 1510; https://doi.org/10.3390/math12101510 (registering DOI) - 12 May 2024
Abstract
In this paper, we provide a blow-up criterion for the density-dependent incompressible magnetohydrodynamic system with zero viscosity. The proof uses the Lp-method and the Kato–Ponce inequalities in the harmonic analysis. The novelty of our work lies in the fact that we [...] Read more.
In this paper, we provide a blow-up criterion for the density-dependent incompressible magnetohydrodynamic system with zero viscosity. The proof uses the Lp-method and the Kato–Ponce inequalities in the harmonic analysis. The novelty of our work lies in the fact that we deal with the case in which the resistivity η is positive. Full article
18 pages, 50280 KiB  
Article
Generation of Virtual Ground Control Points Using a Binocular Camera
by Ariel Vazquez-Dominguez, Andrea Magadán-Salazar, Raúl Pinto-Elías, Jorge Fuentes-Pacheco, Máximo López-Sánchez and Hernán Abaunza-González
Drones 2024, 8(5), 195; https://doi.org/10.3390/drones8050195 (registering DOI) - 12 May 2024
Abstract
This paper presents a methodology for generating virtual ground control points (VGCPs) using a binocular camera mounted on a drone. We compare the measurements of the binocular and monocular cameras between the classical method and the proposed one. This work aims to decrease [...] Read more.
This paper presents a methodology for generating virtual ground control points (VGCPs) using a binocular camera mounted on a drone. We compare the measurements of the binocular and monocular cameras between the classical method and the proposed one. This work aims to decrease human processing times while maintaining a reduced root mean square error (RMSE) for 3D reconstruction. Additionally, we propose utilizing COLMAP to enhance reconstruction accuracy by solely utilizing a sparse point cloud. The results demonstrate that implementing COLMAP for pre-processing reduces the RMSE by up to 16.9% in most cases. We prove that VGCPs further reduce the RMSE by up to 61.08%. Full article
13 pages, 782 KiB  
Article
Liquid–Liquid Equilibrium Behavior of Ternary Systems Comprising Biodiesel + Glycerol and Triglyceride + Methanol: Experimental Data and Modeling
by Lingmei Yang, Shiyou Xing, Xianbin Teng, Rukuan Liu, Zhongming Wang, Baining Lin, Pengmei Lv, Akram Ali Nasser Mansoor Al-Haimi, Fatma Yehia and Wen Luo
Catalysts 2024, 14(5), 320; https://doi.org/10.3390/catal14050320 (registering DOI) - 12 May 2024
Abstract
Having a comprehensive knowledge of phase equilibrium is advantageous for industrial simulation and design of chemical processes. For further acquisition of primary data to facilitate the separation and purification of waste oil biodiesel systems, a liquid–liquid equilibrium (LLE) tank is deployed for the [...] Read more.
Having a comprehensive knowledge of phase equilibrium is advantageous for industrial simulation and design of chemical processes. For further acquisition of primary data to facilitate the separation and purification of waste oil biodiesel systems, a liquid–liquid equilibrium (LLE) tank is deployed for the ternary system of waste oil biodiesel + methanol + glycerin, thereby enhancing the precision and efficiency of the process. The phase equilibrium system was constructed under the influence of atmospheric pressure at precise temperatures of 303.15 K, 313.15 K, and 323.15 K. The equilibrium components of each substance were analyzed by employing high-temperature gas chromatography, a sophisticated analytical method that enables the identification and quantification of individual components of a sample. Moreover, the ternary liquid–liquid equilibrium data were correlated by implementing the NRTL and UNIQUAC activity coefficient models. Subsequently, the binary interaction parameters of the ternary system were derived by conducting regression analysis. The experimental data demonstrated that the presence of lower methanol content in the system resulted in nearly immiscible biodiesel and glycerol phases, which ultimately facilitated the separation of biodiesel and glycerol. Conversely, with the increase in methanol content, the mutual solubility of biodiesel and glycerol was observed to increase gradually. The results showed that the calculated values of the NRTL and UNIQUAC models aligned well with the experimental values. The root-mean-square deviations of the NRTL and UNIQUAC models at 313.15 K were 2.76% and 3.56%, respectively. Full article
(This article belongs to the Section Biomass Catalysis)
19 pages, 363 KiB  
Entry
The Ecumene: A Research Program for Future Knowledge and Governance
by Paulo Castro Seixas and Nadine Lobner
Encyclopedia 2024, 4(2), 799-817; https://doi.org/10.3390/encyclopedia4020051 (registering DOI) - 12 May 2024
Definition
The ecumene defines a beyond-border space of strong cultural encounters, flows, and merging, grounded within the traditions of world-systems, globalization, transnationalism, and cosmopolitanism discourses. Furthermore, the ecumene links directly with international regions as core political platforms in the making. As such, there are [...] Read more.
The ecumene defines a beyond-border space of strong cultural encounters, flows, and merging, grounded within the traditions of world-systems, globalization, transnationalism, and cosmopolitanism discourses. Furthermore, the ecumene links directly with international regions as core political platforms in the making. As such, there are several ecumenes on the forefront, as evidenced by the literature, which can be clustered into ideal types. Epistemologically, it is a relevant concept and tool for a science-of-the-future that focuses on conviviality and transformation for the yet-to-come. Analytically, the ecumene has a descriptive, normative, and critical dimension, and can be empirically accessed through operational concepts such as triggers, hubs, and types of beyond-border conviviality. To apply the ecumene as a research program means to detect convivial common-sense spaces within the global context. Full article
(This article belongs to the Collection Encyclopedia of Social Sciences)
19 pages, 4097 KiB  
Article
Institutional, Ecological, Economic, and Socio-Cultural Sustainability—Evidence from Ponjavica Nature Park
by Vladica Ristić, Igor Trišić, Snežana Štetić, Marija Maksin, Florin Nechita, Adina Nicoleta Candrea, Marko Pavlović and Andreea Hertanu
Land 2024, 13(5), 669; https://doi.org/10.3390/land13050669 (registering DOI) - 12 May 2024
Abstract
The Nature Park Ponjavica (NP) is the habitat of strictly protected plant and animal species, located in AP Vojvodina, in southern Banat (Northern Serbia). The area of the park covers 302,96 ha. Protection zones I, II, and III have been established in the [...] Read more.
The Nature Park Ponjavica (NP) is the habitat of strictly protected plant and animal species, located in AP Vojvodina, in southern Banat (Northern Serbia). The area of the park covers 302,96 ha. Protection zones I, II, and III have been established in the protected area of the NP. The NP includes the middle course of the Ponjavica River, which has preserved characteristics of watercourses of plain areas and coastal remains of wetland habitats. The most valuable area of this park in terms of protection is an island with an area of slightly less than 1 hectare. According to the IUCN (International Union for Conservation of Nature), the NP is classified as the fourth category—Habitat and species management area. The good geographical position of NP is one of its main characteristics. The NP can be a destination where specific forms of tourism can be developed, such as ecotourism, nature-based tourism, birdwatching, scientific and research tourism, etc. Numerous historical sites represent a significant potential for the development of cultural tourism. The research examined the influence of institutional, economic, ecological, and socio-cultural sustainability on the respondents’ satisfaction. The quantitative methodology in this research included a questionnaire as a survey instrument for respondents. A total of 547 residents were surveyed. The results of the research indicate that there is considerable satisfaction among residents with sustainable tourism. The results of the research can help in the development of numerous tourism development strategies in which the wetland is the primary resource. Full article
(This article belongs to the Special Issue Landscape Heritage: Geomorphology, Geoheritage and Geoparks)
17 pages, 4777 KiB  
Article
Design and Experiment of a Passive Vibration Isolator for Small Unmanned Aerial Vehicles
by Chan-Hwi Kang, Hun-Suh Park, Seong-Weon Seo and Dong-Gi Kwag
Appl. Sci. 2024, 14(10), 4113; https://doi.org/10.3390/app14104113 (registering DOI) - 12 May 2024
Abstract
The advancement of sensor, actuator, and flight control technologies has increasingly expanded the possibilities for drone utilization. Among the technologies related to drone applications, the vibration isolator technology for payload has a significant impact on the precision of optical equipment in missions such [...] Read more.
The advancement of sensor, actuator, and flight control technologies has increasingly expanded the possibilities for drone utilization. Among the technologies related to drone applications, the vibration isolator technology for payload has a significant impact on the precision of optical equipment in missions such as detection, reconnaissance, and tracking. However, despite ongoing efforts to develop vibration isolators to mitigate the impact of vibrations transmitted to optical equipment, research on drone-specific natural frequencies and payloads has been lacking. Consequently, there is a need for research on vibration isolators tailored to specific drone types and optical equipment payloads. This study focuses on exploring the correlation between the natural frequencies of drones and the weight of the payload, and proposes methods for developing and testing vibration isolators that consider both factors. To achieve this, the study measured the stiffness of vibration isolator rubbers and conducted cross-validation between random vibration tests and finite element method (FEM) analyses to verify the vibration reduction effects resulting from changes in the dynamic characteristics of vibration isolator rubbers. The rubber with a shore hardness of 70 exhibited relatively high damping and damping performance during random vibration tests. Additionally, it showed relatively high stability with only one resonance point measured within the operational frequency band. Through the findings of this study, a methodology for selecting vibration isolators for drones is proposed, aiming to enhance the stability of optical equipment. Full article
23 pages, 2125 KiB  
Article
An Analysis of Blockchain-Based IoT Sensor Network Distributed Denial of Service Attacks
by Kithmini Godewatte Arachchige, Philip Branch and Jason But
Sensors 2024, 24(10), 3083; https://doi.org/10.3390/s24103083 (registering DOI) - 12 May 2024
Abstract
The Internet of Things (IoT) and blockchain are emerging technologies that have attracted attention in many industries, including healthcare, automotive, and supply chain. IoT networks and devices are typically low-powered and susceptible to cyber intrusions. However, blockchains hold considerable potential for securing low-power [...] Read more.
The Internet of Things (IoT) and blockchain are emerging technologies that have attracted attention in many industries, including healthcare, automotive, and supply chain. IoT networks and devices are typically low-powered and susceptible to cyber intrusions. However, blockchains hold considerable potential for securing low-power IoT networks. Blockchain networks provide security features such as encryption, decentralisation, time stamps, and ledger functions. The integration of blockchain and IoT technologies may address many of the security concerns. However, integrating blockchain with IoT raises several issues, including the security vulnerabilities and anomalies of blockchain-based IoT networks. In this paper, we report on our experiments using our blockchain test bed to demonstrate that blockchains on IoT platforms are vulnerable to DDoS attacks, which can also potentially lead to device hardware failures. We show that a number of anomalies are visible during either a DDoS attack or IoT device failure. In particular, the temperature of IoT hardware devices can exceed 90 °C during a DDoS attack, which could lead to hardware failure and potential fire hazards. We also found that the Block Transaction Rate (BTR) and network block loss percentage can increase due to corrupted hardware, with the BTR dropping to nearly zero blocks/sec and a block loss percentage of over 50 percent for all evaluated blockchains, and as high as 81.3 percent in one case. Our experiments demonstrate that anomalous temperature, latency, bandwidth, BTR, and network block loss percentage can potentially be used to identify DDoS attacks. Full article
(This article belongs to the Special Issue Wireless Sensor Network and IoT Technologies for Smart Cities)
23 pages, 1582 KiB  
Article
Exploring the Association between Anxiety, Depression, and Gut Microbiota during Pregnancy: Findings from a Pregnancy Cohort Study in Shijiazhuang, Hebei Province, China
by Ruixin Chi, Muxia Li, Man Zhang, Na Zhang, Guohua Zhang, Lijun Cui and Guansheng Ma
Nutrients 2024, 16(10), 1460; https://doi.org/10.3390/nu16101460 (registering DOI) - 12 May 2024
Abstract
Negative emotions and gut microbiota during pregnancy both bear significant public health implications. However, the relationship between them has not been fully elucidated. This study, utilizing data from a pregnancy cohort, employed metagenomic sequencing to elucidate the relationship between anxiety, depression, and gut [...] Read more.
Negative emotions and gut microbiota during pregnancy both bear significant public health implications. However, the relationship between them has not been fully elucidated. This study, utilizing data from a pregnancy cohort, employed metagenomic sequencing to elucidate the relationship between anxiety, depression, and gut microbiota’s diversity, composition, species, and functional pathways. Data from 87 subjects, spanning 225 time points across early, mid, and late pregnancy, were analyzed. The results revealed that higher anxiety and depression scores significantly corresponded to lower alpha diversity (including the Shannon entropy and the Simpson index). Anxiety and depression scores, along with categorical distinctions of anxiety/non-anxiety and depression/non-depression, were found to account for 0.723%, 0.731%, 0.651%, and 0.810% of the variance in gut-microbiota composition (p = 0.001), respectively. Increased anxiety was significantly positively associated with the abundance of Oscillibacter sp. KLE 1745, Oscillibacter sp. PEA192, Oscillibacter sp. KLE 1728, Oscillospiraceae bacterium VE202 24, and Treponema socranskii. A similar association was significantly noted for Oscillibacter sp. KLE 1745 with elevated depression scores. While EC.3.5.3.1: arginase appeared to be lower in the anxious group than in the non-anxious group, vitamin B12-related enzymes appeared to be lower in the depression group than in the non-depression group. The changes were found to be not statistically significant after post-multiple comparison adjustment. Full article
(This article belongs to the Section Nutrition in Women)
16 pages, 2827 KiB  
Article
Co-Assembled Supramolecular Organohydrogels of Amphiphilic Zwitterion and Polyoxometalate with Controlled Microstructures
by Peilin Wei, Yu Duan, Chen Wang, Panpan Sun and Na Sun
Molecules 2024, 29(10), 2286; https://doi.org/10.3390/molecules29102286 (registering DOI) - 12 May 2024
Abstract
The organization of modifiable and functional building components into various superstructures is of great interest due to their broad applications. Supramolecular self-assembly, based on rationally designed building blocks and appropriately utilized driving forces, is a promising and widely used strategy for constructing superstructures [...] Read more.
The organization of modifiable and functional building components into various superstructures is of great interest due to their broad applications. Supramolecular self-assembly, based on rationally designed building blocks and appropriately utilized driving forces, is a promising and widely used strategy for constructing superstructures with well-defined nanostructures and diverse morphologies across multiple length scales. In this study, two homogeneous organohydrogels with distinct appearances were constructed by simply mixing polyoxometalate (phosphomolybdic acid, HPMo) and a double-tailed zwitterionic quaternary ammonium amphiphile in a binary solvent of water and dimethyl sulfoxide (DMSO). The delicate balance between electrostatic attraction and repulsion of anionic HPMo clusters and zwitterionic structures drove them to co-assemble into homogeneous organohydrogels with diverse microstructures. Notably, the morphologies of the organohydrogels, including unilamellar vesicles, onion-like vesicles, and spherical aggregates, can be controlled by adjusting the ionic interactions between the zwitterionic amphiphiles and phosphomolybdic acid clusters. Furthermore, we observed an organohydrogel fabricated with densely stacked onion-like structures (multilamellar vesicles) consisting of more than a dozen layers at certain proportions. Additionally, the relationships between the self-assembled architectures and the intermolecular interactions among the polyoxometalate, zwitterionic amphiphile, and solvent molecules were elucidated. This study offers valuable insights into the mechanisms of polyoxometalate-zwitterionic amphiphile co-assembly, which are essential for the development of materials with specific structures and emerging functionalities. Full article
(This article belongs to the Special Issue Amphiphilic Molecules, Interfaces and Colloids)
17 pages, 5824 KiB  
Article
Synthesis of Gold Nanoparticles over CoAl Mixed Oxide for Ethanol Oxidation Reaction
by Guillaume Rochard, Eric Genty, Jean-Marc Giraudon, Christophe Poupin, Jean-François Lamonier, Stéphane Siffert, Valeria La Parola, Leonarda Francesca Liotta and Renaud Cousin
Molecules 2024, 29(10), 2285; https://doi.org/10.3390/molecules29102285 (registering DOI) - 12 May 2024
Abstract
Catalytic total oxidation is an effective technique for the treatment of industrial VOCs principally resulting from industrial processes using solvents and usually containing mono-aromatics (BTEX) and oxygenated compounds (acetone, ethanol, butanone). The aim of this work is to deposit gold nanoparticles on CoAl [...] Read more.
Catalytic total oxidation is an effective technique for the treatment of industrial VOCs principally resulting from industrial processes using solvents and usually containing mono-aromatics (BTEX) and oxygenated compounds (acetone, ethanol, butanone). The aim of this work is to deposit gold nanoparticles on CoAl mixed oxide issued from layered double hydroxide (LDH) precursor by using the deposition precipitation (DP) method, which is applied with two modifications, labeled method (A) and method (B), in order to enhance the interaction of the HAuCl4 precursor with the support. Method (A) involves the hydrolysis of the HAuCl4 precursor after addition of the support, while in method (B), the gold precursor is hydrolyzed before adding the support. The two methods were applied using as support the CoAl mixed oxide and the LDH precursor. Samples were characterized by several physical chemical techniques and evaluated for ethanol total oxidation. Method (B) allowed the ethanol oxidation activity to be enhanced for the resulting Au/CoAlOx catalysts thanks to the high surface concentration of Co2+ and improved reducibility at low temperature. The presence of gold permits to minimize the formation of by-products, notably, methanol, allowed for a total oxidation of ethanol at lower temperature than the corresponding support. Full article
(This article belongs to the Special Issue Design, Synthesis and Application of Heterogeneous Catalysts)
16 pages, 17175 KiB  
Article
Detailed Radiomorphometric Analysis of the Surgical Corridor for the Suprageniculate Approach
by Tomasz Wojciechowski, Nicola Bisi, Kazimierz Szopiński and Daniele Marchioni
J. Pers. Med. 2024, 14(5), 516; https://doi.org/10.3390/jpm14050516 (registering DOI) - 12 May 2024
Abstract
Background: The suprageniculate fossa (SGF) is located between the geniculate ganglion, the middle cranial fossa (MCF) and the anterior semicircular canal (ASCC). An endoscopic transcanal approach has been recently proposed to treat the different lesions in this area. The aim of the study [...] Read more.
Background: The suprageniculate fossa (SGF) is located between the geniculate ganglion, the middle cranial fossa (MCF) and the anterior semicircular canal (ASCC). An endoscopic transcanal approach has been recently proposed to treat the different lesions in this area. The aim of the study is to describe the anatomical pathway of this approach by measuring the dimensions of its boundaries while checking their correlation with the pneumatization of the SGF area. Methods: This is a retrospective anatomical analysis of Cone Beam CT scans of 80 patients, for a total of 160 temporal bones analyzed. Two checkpoints were measured for the SGF route, as an internal and an external window. These are triangles between the MCF dura, the geniculate ganglion and the ASCC on parasagittal and axial planes. The pneumatization of the SGF was also assessed, classified and correlated with the measured dimensions. Results: The depth of the SGF was 7.5 ± 1.8 mm. The width of the external window was 7.5 ± 1.9, 5.6 ± 2.4 and 1.6 ± 1.6 mm for the posterior, middle and anterior points of measurement, respectively. The height of the internal window was 7.6 ± 1.2, 4.5 ± 1.5 and 1.7 ± 1.7 mm for the posterior, middle and anterior points of measurement, respectively. Type A pneumatization was found in 87 cases, type B in 34 and type C in 39. The degree of pneumatization directly correlated to the depth and height of the fossa. Conclusions: The suprageniculate approach route is defined by the internal and external windows which should be evaluated during a pre-surgery imaging assessment. The detailed anatomy of the approach and the novel classification of the pneumatization of the SGF are here described which may be useful to plan a safer procedure with minimal complications. Full article
32 pages, 3274 KiB  
Review
A Review of Real-Time Implementable Cooperative Aerial Manipulation Systems
by Stamatina C. Barakou, Costas S. Tzafestas and Kimon P. Valavanis
Drones 2024, 8(5), 196; https://doi.org/10.3390/drones8050196 (registering DOI) - 12 May 2024
Abstract
This review paper focuses on quadrotor- and multirotor-based cooperative aerial manipulation. Emphasis is first given to comparing and evaluating prototype systems that have been implemented and tested in real-time in diverse application environments. The underlying modeling and control approaches are also discussed and [...] Read more.
This review paper focuses on quadrotor- and multirotor-based cooperative aerial manipulation. Emphasis is first given to comparing and evaluating prototype systems that have been implemented and tested in real-time in diverse application environments. The underlying modeling and control approaches are also discussed and compared. The outcome of this review allows for understanding the motivation and rationale to develop such systems, their applicability and implementability in diverse applications and also challenges that need to be addressed and overcome. Moreover, this paper provides a guide to develop the next generation of prototype systems based on preferred characteristics, functionality, operability, and application domain. Full article
19 pages, 3325 KiB  
Article
Identification of Critical Immune Regulators and Potential Interactions of IL-26 in Riemerella anatipestifer-Infected Ducks by Transcriptome Analysis and Profiling
by Paula Leona T. Cammayo-Fletcher, Rochelle A. Flores, Binh T. Nguyen, Bujinlkham Altanzul, Cherry P. Fernandez-Colorado, Woo H. Kim, Rajkumari Mandakini Devi, Suk Kim and Wongi Min
Microorganisms 2024, 12(5), 973; https://doi.org/10.3390/microorganisms12050973 (registering DOI) - 12 May 2024
Abstract
Riemerella anatipestifer (RA) is an economically important pathogen in the duck industry worldwide that causes high mortality and morbidity in infected birds. We previously found that upregulated IL-17A expression in ducks infected with RA participates in the pathogenesis of the disease, but this [...] Read more.
Riemerella anatipestifer (RA) is an economically important pathogen in the duck industry worldwide that causes high mortality and morbidity in infected birds. We previously found that upregulated IL-17A expression in ducks infected with RA participates in the pathogenesis of the disease, but this mechanism is not linked to IL-23, which primarily promotes Th17 cell differentiation and proliferation. RNA sequencing analysis was used in this study to investigate other mechanisms of IL-17A upregulation in RA infection. A possible interaction of IL-26 and IL-17 was discovered, highlighting the potential of IL-26 as a novel upstream cytokine that can regulate IL-17A during RA infection. Additionally, this process identified several important pathways and genes related to the complex networks and potential regulation of the host immune response in RA-infected ducks. Collectively, these findings not only serve as a roadmap for our understanding of RA infection and the development of new immunotherapeutic approaches for this disease, but they also provide an opportunity to understand the immune system of ducks. Full article
(This article belongs to the Section Veterinary Microbiology)
11 pages, 1484 KiB  
Article
Study on Phenol–Formaldehyde Resin–Montmorillonite Impregnation and Compression Modification of Chinese Fir
by Lei He, Qian Zhang, Bengang Zhang, Hongyun Qiu, Jie Guo, Fengwen Sun, Zengfu Jiang and Weidong Zhou
Polymers 2024, 16(10), 1385; https://doi.org/10.3390/polym16101385 (registering DOI) - 12 May 2024
Abstract
In this study, a phenol–formaldehyde resin–montmorillonite intercalation composite solution was used as a modifier to treat Chinese fir via impregnation and compression. The basic characteristics and wettability of the PF (phenol–formaldehyde)–montmorillonite impregnation solution were analyzed. The effects of the solid content of PF, [...] Read more.
In this study, a phenol–formaldehyde resin–montmorillonite intercalation composite solution was used as a modifier to treat Chinese fir via impregnation and compression. The basic characteristics and wettability of the PF (phenol–formaldehyde)–montmorillonite impregnation solution were analyzed. The effects of the solid content of PF, the quantity of montmorillonite, and the impregnation time on the impregnation weight gain of Chinese fir were studied through orthogonal experiments. The results showed that when the amount of montmorillonite was 1%, the wettability of the PF–montmorillonite impregnation solution performed the best, the curing time was short, and the curing strength was high. The optimal impregnation process consists of a PF solid content of 25%, an impregnation time of 120 min, and a montmorillonite ratio of 1%. Under these conditions, the modified Chinese fir was prepared via hot pressing. The effects of the addition of montmorillonite and different levels of compressibility on the physical and mechanical properties of modified wood were studied. The physical and mechanical properties were found to be better when the compression ratio was 33%: the density increased from 0.33 g/cm3 to 0.58 g/cm3; the surface hardness increased from 33.6 HD to 70.9 HD; the static bending strength increased from 60.4 MPa to 98.7 MPa; and the elastic modulus increased from 6 390 MPa to 11 498 MPa. After 30 days of release, the compression rebound rate was 3.97%. Meanwhile, the micromorphology and heat resistance of the impregnated compressed Chinese fir showed that the PF–montmorillonite impregnation solution entered into the cell cavity and intercellular space of the Chinese fir and formed a good composite, thus improving the water resistance, heat resistance, and physical and mechanical properties. Full article
(This article belongs to the Section Biomacromolecules, Biobased and Biodegradable Polymers)
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17 pages, 9132 KiB  
Article
Aluminum Removal from Rare Earth Chloride Solution through Regulated Hydrolysis via Electrochemical Method
by Yaoyao Zhu, Jian Li, Dongyue Xie, Hui Zhang, Man Li, Binfeng Xu, Xuxia Zhang, Yangyang Xie and Tao Qi
Separations 2024, 11(5), 149; https://doi.org/10.3390/separations11050149 (registering DOI) - 12 May 2024
Abstract
Due to the coexistence of Al3+ and RE3+ and their similar properties, the separation of aluminum from rare earths is difficult. In this study, selective precipitation was used to separate aluminum from rare earth chloride solution via electrochemical regulated hydrolysis. By [...] Read more.
Due to the coexistence of Al3+ and RE3+ and their similar properties, the separation of aluminum from rare earths is difficult. In this study, selective precipitation was used to separate aluminum from rare earth chloride solution via electrochemical regulated hydrolysis. By controlling the current density and electrolytic time, the rate of hydroxyl ion production was regulated, and the selective separation of rare earth and aluminum was realized according to the different precipitation sequences. By altering the temperature, current density, pH value, and other parameters, the separation performance of aluminum from rare earth in mixed rare earth chloride systems was systematically investigated. The removal rate of aluminum reached 88.35%, and the loss rate of rare earth was only 5.99% under optimized conditions. Compared with traditional neutralization hydrolysis, the new process showed higher efficiency and lower rare earth loss rate. Furthermore, a kinetic analysis of aluminum precipitation revealed that the reaction adhered to pseudo-first order kinetics. Additionally, the precipitate obtained via separation and filtration was amorphous alumina hydroxide with a small amount of rare earth attached. No reagent was consumed for the new process, which was more efficient and cleaner, providing a new idea for removing aluminum impurities from rare earth solutions. Full article
(This article belongs to the Section Purification Technology)
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